4.7 Review

Mechanistic aspects of poly(ethylene terephthalate) recycling-toward enabling high quality sustainability decisions in waste management

Journal

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 28, Issue 32, Pages 43074-43101

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-021-14925-z

Keywords

Chemical Mechanism; Plastic wastes; Plastic recycling; Biodegradable plastics; Monomer; Oligomer

Funding

  1. Research Affairs Division of the Amir Kabir University of Technology (AUT)

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The recycling of PET can reduce consumption of crude oil-based materials and decrease greenhouse gas emissions, particularly CO2. Understanding the reaction mechanism of PET recycling helps protect the environment and produce new materials for various applications.
Since plastic waste pollution is a severe environmental concern in modern life, the demand for recycling poly(ethylene terephthalate) (PET) has increased due to its versatile applications. Taking advantage of plastic recycling methods creates the chances of minimizing overall crude oil-based materials consumption, and as a result, greenhouse gasses, specifically CO2, will be decreased. Although many review articles have been published on plastic recycling methods from different aspects, a few review articles exist to investigate the organic reaction mechanism in plastic recycling. This review aims to describe other processes for recycling bottle waste of PET, considering the reaction mechanism. Understanding the reaction mechanism offers practical solutions toward protecting the environment against disadvantageous outgrowths rising from PET wastes. PET recycling aims to transform into a monomer/oligomer to produce new materials from plastic wastes. It is an application in various fields, including the food and beverage industry, packaging, and textile applications, to protect the environment from contamination and introduce a green demand for the near future. In this review, the chemical glycolysis process as an outstanding recycling technique for PET is also discussed, emphasizing the catalysts' performance, reaction conditions and methods, degradation agents, the kinetics of reactions, and reprocessing products. In general, a correct understanding of the PET recycling reaction mechanism leads to making the right decisions in waste management.

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