Research progress of electrochemical CO2 reduction for copper-based catalysts to multicarbon products

Recent Progress in Electrocatalytic Methanation of CO 2 at Ambient Conditions

(2021) Runbo Zhao et al.   ADVANCED FUNCTIONAL MATERIALS

Potential Link between Cu Surface and Selective CO 2 Electroreduction: Perspective on Future Electrocatalyst Designs

(2020) Gracita M. Tomboc et al.   ADVANCED MATERIALS

Production of C2/C3 Oxygenates from Planar Copper Nitride-Derived Mesoporous Copper via Electrochemical Reduction of CO2

(2020) Mohamed Ebaid et al.   CHEMISTRY OF MATERIALS

Fast Cooling Induced Grain-Boundary-Rich Copper Oxide for Electrocatalytic Carbon Dioxide Reduction to Ethanol

(2020) Chao Yang et al.   JOURNAL OF COLLOID AND INTERFACE SCIENCE

Controlling the Oxidation State of the Cu Electrode and Reaction Intermediates for Electrochemical CO2 Reduction to Ethylene

(2020) Tsu-Chin Chou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Exceptionally Mild and Scalable Solution-Phase Synthesis of Molybdenum Carbide Nanoparticles for Thermocatalytic CO2 Hydrogenation

(2020) Frederick G. Baddour et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigating the Origin of Enhanced C2+ Selectivity in Oxide-/Hydroxide-Derived Copper Electrodes during CO2 Electroreduction

(2020) Qiong Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular enhancement of heterogeneous CO2 reduction

(2020) Dae-Hyun Nam et al.   NATURE MATERIALS

Biocatalytic synthesis of planar chiral macrocycles

(2020) Christina Gagnon et al.   SCIENCE

Highly Selective Reduction of CO2 to C2+ Hydrocarbons at Cu/Polyaniline Interfaces

(2020) Xing Wei et al.   ACS Catalysis

A Disquisition on the Active Sites of Heterogeneous Catalysts for Electrochemical Reduction of CO 2 to Value‐Added Chemicals and Fuel

(2020) Rahman Daiyan et al.   Advanced Energy Materials

Atomic‐Scale Spacing between Copper Facets for the Electrochemical Reduction of Carbon Dioxide

(2020) Hyung Mo Jeong et al.   Advanced Energy Materials

Cu 2 O Nanoparticles with Both {100} and {111} Facets for Enhancing the Selectivity and Activity of CO 2 Electroreduction to Ethylene

(2020) Yugang Gao et al.   Advanced Science

Strategies in catalysts and electrolyzer design for electrochemical CO2 reduction toward C2+ products

(2020) Lei Fan et al.   Science Advances

Stability and degradation mechanisms of copper-based catalysts for electrochemical CO2 reduction

(2020) Stefan Popović et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Layered Tungsten Disulfide as Electrocatalyst for Water Splitting

(2020) Zhiyuan Ni et al.   ChemCatChem

Protecting Copper Oxidation State via Intermediate Confinement for Selective CO2 Electroreduction to C2+ Fuels

(2020) Peng-Peng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Grain-Boundary-Rich Copper for Efficient Solar-Driven Electrochemical CO2 Reduction to Ethylene and Ethanol

(2020) Zhiqiang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Accelerated discovery of CO2 electrocatalysts using active machine learning

(2020) Miao Zhong et al.   NATURE

Electrochemically scrambled nanocrystals are catalytically active for CO2-to-multicarbons

(2020) Yifan Li et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Facet-Dependent Selectivity of Cu Catalysts in Electrochemical CO2 Reduction at Commercially Viable Current Densities

(2020) Gian Luca De Gregorio et al.   ACS Catalysis

Effects of Surface Roughness on the Electrochemical Reduction of CO2 over Cu

(2020) Kun Jiang et al.   ACS Energy Letters

Efficient electrically powered CO2-to-ethanol via suppression of deoxygenation

(2020) Xue Wang et al.   Nature Energy

Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C–C coupling over fluorine-modified copper

(2020) Wenchao Ma et al.   Nature Catalysis

Highly Efficient Electroreduction of CO 2 to C2+ Alcohols on Heterogeneous Dual Active Sites

(2020) Chunjun Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hierarchically porous Cu/Zn bimetallic catalysts for highly selective CO2 electroreduction to liquid C2 products

(2020) Xingsong Su et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Atypical Oxygen-Bearing Copper Boosts Ethylene Selectivity toward Electrocatalytic CO2 Reduction

(2020) Wei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Electrocatalytic Ethylene Production from CO2 on Nanodefective Cu Nanosheets

(2020) Bingxing Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlled Synthesis of EDTA-Modified Porous Hollow Copper Microspheres for High-Efficiency Conversion of CO2 to Multicarbon Products

(2020) Juan Liu et al.   NANO LETTERS

Electron‐Deficient Cu Sites on Cu 3 Ag 1 Catalyst Promoting CO 2 Electroreduction to Alcohols

(2020) Ximeng Lv et al.   Advanced Energy Materials

Highly active and stable stepped Cu surface for enhanced electrochemical CO2 reduction to C2H4

(2020) Chungseok Choi et al.   Nature Catalysis

Silver/Copper Interface for Relay Electroreduction of Carbon Dioxide to Ethylene

(2019) Jiaqi Wang et al.   ACS Applied Materials & Interfaces

Structural Sensitivities in Bimetallic Catalysts for Electrochemical CO2 Reduction Revealed by Ag-Cu Nanodimers

(2019) Jianfeng Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Fragmentation of Cu2O Nanoparticles Enhancing Selective C–C Coupling from CO2 Reduction Reaction

(2019) Hyejin Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Suppressing Manganese Dissolution in Potassium Manganate with Rich Oxygen Defects Engaged High-Energy-Density and Durable Aqueous Zinc-Ion Battery

(2019) Guozhao Fang et al.   ADVANCED FUNCTIONAL MATERIALS

Cubic Cu2O on nitrogen-doped carbon shells for electrocatalytic CO2 reduction to C2H4

(2019) Hui Ning et al.   CARBON

Branched Copper Oxide Nanoparticles Induce Highly Selective Ethylene Production by Electrochemical Carbon Dioxide Reduction

(2019) Jinmo Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Catalysts

(2019) Yao Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Binding Site Diversity Promotes CO2 Electroreduction to Ethanol

(2019) Yuguang C. Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid and Scalable Synthesis of Cuprous Halide-Derived Copper Nano-Architectures for Selective Electrochemical Reduction of Carbon Dioxide

(2019) Huan Wang et al.   NANO LETTERS

Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

(2019) Stephanie Nitopi et al.   CHEMICAL REVIEWS

Designing materials for electrochemical carbon dioxide recycling

(2019) Michael B. Ross et al.   Nature Catalysis

Selective carbon dioxide electroreduction to ethylene and ethanol by core-shell copper/cuprous oxide

(2019) Longmei Shang et al.   JOURNAL OF COLLOID AND INTERFACE SCIENCE

Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

(2019) Yuvraj Y. Birdja et al.   Nature Energy

Electrode Materials Engineering in Electrocatalytic CO 2 Reduction: Energy Input and Conversion Efficiency

(2019) Rong‐Bin Song et al.   ADVANCED MATERIALS

Surface and Interface Control in Nanoparticle Catalysis

(2019) Chenlu Xie et al.   CHEMICAL REVIEWS

Selective C–C Coupling in Carbon Dioxide Electroreduction via Efficient Spillover of Intermediates As Supported by Operando Raman Spectroscopy

(2019) Jing Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Operando Insight into the Correlation between the Structure and Composition of CuZn Nanoparticles and Their Selectivity for the Electrochemical CO2 Reduction

(2019) Hyo Sang Jeon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper Nanocubes for CO2 Reduction in Gas Diffusion Electrodes

(2019) Yuxuan Wang et al.   NANO LETTERS

Cu3N Nanocubes for Selective Electrochemical Reduction of CO2 to Ethylene

(2019) Zhouyang Yin et al.   NANO LETTERS

Cover Picture: Chameleon Metals: Autonomous Nano-Texturing and Composition Inversion on Liquid Metals Surfaces (Angew. Chem. Int. Ed. 1/2020)

(2019) Andrew Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Changing the Product Selectivity for Electrocatalysis of CO 2 Reduction Reaction on Plated Cu Electrodes

(2019) Hong Li et al.   ChemCatChem

Mechanistic Understanding of CO2 Reduction Reaction (CO2RR) Toward Multicarbon Products by Heterogeneous Copper-Based Catalysts

(2019) Tanya K. Todorova et al.   ACS Catalysis

Promises of Main Group Metal–Based Nanostructured Materials for Electrochemical CO 2 Reduction to Formate

(2019) Na Han et al.   Advanced Energy Materials

Activation of bimetallic AgCu foam electrocatalysts for ethanol formation from CO2 by selective Cu oxidation/reduction

(2019) Abhijit Dutta et al.   Nano Energy

Cooperative CO2-to-ethanol conversion via enriched intermediates at molecule–metal catalyst interfaces

(2019) Fengwang Li et al.   Nature Catalysis

Self-growing Cu/Sn bimetallic electrocatalysts on nitrogen-doped porous carbon cloth with 3D-hierarchical honeycomb structure for highly active carbon dioxide reduction

(2019) Luwei Peng et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

High Selectivity Toward C2H4 Production over Cu Particles Supported by Butterfly-Wing-Derived Carbon Frameworks

(2018) Yajiao Huo et al.   ACS Applied Materials & Interfaces

Iron Vacancies Induced Bifunctionality in Ultrathin Feroxyhyte Nanosheets for Overall Water Splitting

(2018) Bin Liu et al.   ADVANCED MATERIALS

Promoting Ethylene Selectivity from CO2 Electroreduction on CuO Supported onto CO2 Capture Materials

(2018) Hui-Juan Yang et al.   ChemSusChem

Sequential catalysis controls selectivity in electrochemical CO2 reduction on Cu

(2018) Yanwei Lum et al.   Energy & Environmental Science

Nanoporous Copper–Silver Alloys by Additive-Controlled Electrodeposition for the Selective Electroreduction of CO2 to Ethylene and Ethanol

(2018) Thao T. H. Hoang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical CO Reduction Builds Solvent Water into Oxygenate Products

(2018) Yanwei Lum et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-based nanocatalysts for electrochemical reduction of CO 2

(2018) Huan Xie et al.   Nano Today

Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons

(2018) Yansong Zhou et al.   Nature Chemistry

CO2electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface

(2018) Cao-Thang Dinh et al.   SCIENCE

Poly-Amide Modified Copper Foam Electrodes for Enhanced Electrochemical Reduction of Carbon Dioxide

(2018) Sunyhik Ahn et al.   ACS Catalysis

Mechanism of CO2 Reduction at Copper Surfaces: Pathways to C2 Products

(2018) Alejandro J. Garza et al.   ACS Catalysis

A metal-vacancy-solid-solution NiAlP nanowall array bifunctional electrocatalyst for exceptional all-pH overall water splitting

(2018) Weiren Cheng et al.   Journal of Materials Chemistry A

Heterostructures for Electrochemical Hydrogen Evolution Reaction: A Review

(2018) Guoqiang Zhao et al.   ADVANCED FUNCTIONAL MATERIALS

Electrocatalytic reduction of CO2 to produce higher alcohols

(2018) Shamsa Munir et al.   Sustainable Energy & Fuels

A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction

(2018) Jing-Jing Lv et al.   ADVANCED MATERIALS

Double-slit photoelectron interference in strong-field ionization of the neon dimer

(2018) Maksim Kunitski et al.   Nature Communications

Design of a Cu(i)/C-doped boron nitride electrocatalyst for efficient conversion of CO2 into acetic acid

(2017) Xiaofu Sun et al.   GREEN CHEMISTRY

Nature and Distribution of Stable Subsurface Oxygen in Copper Electrodes During Electrochemical CO2 Reduction

(2017) Filippo Cavalca et al.   Journal of Physical Chemistry C

Current Status and Bioinspired Perspective of Electrochemical Conversion of CO2 to a Long-Chain Hydrocarbon

(2017) Ki Dong Yang et al.   Journal of Physical Chemistry Letters

Metal and Metal Oxide Interactions and Their Catalytic Consequences for Oxygen Reduction Reaction

(2017) Qingying Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhancing CO2 Electroreduction with the Metal–Oxide Interface

(2017) Dunfeng Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Activation of CO2 through Atomic Ordering Transformations of AuCu Nanoparticles

(2017) Dohyung Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical CO2 Reduction over Compressively Strained CuAg Surface Alloys with Enhanced Multi-Carbon Oxygenate Selectivity

(2017) Ezra L. Clark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Janus dendrimersomes coassembled from fluorinated, hydrogenated, and hybrid Janus dendrimers as models for cell fusion and fission

(2017) Qi Xiao et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Engineering Cu surfaces for the electrocatalytic conversion of CO2: Controlling selectivity toward oxygenates and hydrocarbons

(2017) Christopher Hahn et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Copper nanoparticle ensembles for selective electroreduction of CO2to C2–C3products

(2017) Dohyung Kim et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K

(2017) Tao Cheng et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Selective increase in CO2electroreduction activity at grain-boundary surface terminations

(2017) Ruperto G. Mariano et al.   SCIENCE

Morphological and Compositional Design of Pd-Cu Bimetallic Nanocatalysts with Controllable Product Selectivity toward CO2 Electroreduction

(2017) Wenjin Zhu et al.   Small

Tuning of CO2 Reduction Selectivity on Metal Electrocatalysts

(2017) Yuhang Wang et al.   Small

Low-Overpotential Electroreduction of Carbon Monoxide Using Copper Nanowires

(2017) David Raciti et al.   ACS Catalysis

Electrochemical Reduction of CO2 Using Copper Single-Crystal Surfaces: Effects of CO* Coverage on the Selective Formation of Ethylene

(2017) Yun Huang et al.   ACS Catalysis

Importance of Ag–Cu Biphasic Boundaries for Selective Electrochemical Reduction of CO2 to Ethanol

(2017) Seunghwa Lee et al.   ACS Catalysis

Selective Electroreduction of CO2 toward Ethylene on Nano Dendritic Copper Catalysts at High Current Density

(2017) Christian Reller et al.   Advanced Energy Materials

CO2 Reduction: From the Electrochemical to Photochemical Approach

(2017) Jinghua Wu et al.   Advanced Science

Fundamentals and Challenges of Electrochemical CO 2 Reduction Using Two-Dimensional Materials

(2017) Zhenyu Sun et al.   Chem

Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide

(2016) Dong Dong Zhu et al.   ADVANCED MATERIALS

Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction

(2016) Anna Loiudice et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amino acid modified copper electrodes for the enhanced selective electroreduction of carbon dioxide towards hydrocarbons

(2016) Ming Shi Xie et al.   Energy & Environmental Science

CO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts

(2016) Xiaoxia Chang et al.   Energy & Environmental Science

Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction

(2016) André Eilert et al.   Journal of Physical Chemistry Letters

Formation of Copper Catalysts for CO2 Reduction with High Ethylene/Methane Product Ratio Investigated with In Situ X-ray Absorption Spectroscopy

(2016) André Eilert et al.   Journal of Physical Chemistry Letters

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO2: New Theoretical Insights from an Improved Electrochemical Model

(2016) Jason D. Goodpaster et al.   Journal of Physical Chemistry Letters

Mechanistic Explanation of the pH Dependence and Onset Potentials for Hydrocarbon Products from Electrochemical Reduction of CO on Cu (111)

(2016) Hai Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electroreduction of Carbon Dioxide to Hydrocarbons Using Bimetallic Cu–Pd Catalysts with Different Mixing Patterns

(2016) Sichao Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning Catalytic Selectivity at the Mesoscale via Interparticle Interactions

(2016) Hemma Mistry et al.   ACS Catalysis

Tuning the Selectivity of Carbon Dioxide Electroreduction toward Ethanol on Oxide-Derived CuxZn Catalysts

(2016) Dan Ren et al.   ACS Catalysis

Recent Advances in Breaking Scaling Relations for Effective Electrochemical Conversion of CO2

(2016) Yawei Li et al.   Advanced Energy Materials

Controlled assembly of Cu nanoparticles on pyridinic-N rich graphene for electrochemical reduction of CO 2 to ethylene

(2016) Qing Li et al.   Nano Energy

A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles

(2016) Xiaofeng Feng et al.   ACS Central Science

Theoretical Insights into a CO Dimerization Mechanism in CO2 Electroreduction

(2015) Joseph H. Montoya et al.   Journal of Physical Chemistry Letters

Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide

(2015) Ruud Kortlever et al.   Journal of Physical Chemistry Letters

Mechanistic Insights into the Enhanced Activity and Stability of Agglomerated Cu Nanocrystals for the Electrochemical Reduction of Carbon Dioxide to n-Propanol

(2015) Dan Ren et al.   Journal of Physical Chemistry Letters

Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts

(2015) Arnau Verdaguer-Casadevall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide

(2015) Meenesh R. Singh et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Facet Dependence of CO2 Reduction Paths on Cu Electrodes

(2015) Wenjia Luo et al.   ACS Catalysis

Understanding nano effects in catalysis

(2015) Fan Yang et al.   National Science Review

Particle Size Effects in the Catalytic Electroreduction of CO2 on Cu Nanoparticles

(2014) Rulle Reske et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper

(2014) Christina W. Li et al.   NATURE

Theoretical Considerations on the Electroreduction of CO to C2Species on Cu(100) Electrodes

(2013) Federico Calle-Vallejo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selectivity of CO2Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps

(2013) Xiaowa Nie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insights into CC Coupling in CO2Electroreduction on Copper Electrodes

(2013) Joseph H. Montoya et al.   ChemCatChem

Adsorption of CO2 on Cu2O (111) oxygen-vacancy surface: First-principles study

(2013) Huanwen Wu et al.   CHEMICAL PHYSICS LETTERS

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

(2013) Jinli Qiao et al.   CHEMICAL SOCIETY REVIEWS

Controlling Catalytic Selectivities during CO2 Electroreduction on Thin Cu Metal Overlayers

(2013) Rulle Reske et al.   Journal of Physical Chemistry Letters

Structure Sensitivity of the Electrochemical Reduction of Carbon Monoxide on Copper Single Crystals

(2013) Klaas Jan P. Schouten et al.   ACS Catalysis

Electrochemical conversion of CO2 to useful chemicals: current status, remaining challenges, and future opportunities

(2013) Huei-Ru “Molly” Jhong et al.   Current Opinion in Chemical Engineering

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces

(2012) Kendra P. Kuhl et al.   Energy & Environmental Science

Investigation of Catalytic Finite-Size-Effects of Platinum Metal Clusters

(2012) Lin Li et al.   Journal of Physical Chemistry Letters

CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films

(2012) Christina W. Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes

(2012) Klaas Jan P. Schouten et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding the Metal-Carbon Interface in FePt Catalyzed Carbon Nanotubes

(2011) D. Pohl et al.   PHYSICAL REVIEW LETTERS

Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts

(2010) Peter Strasser et al.   Nature Chemistry

Future CO2 Emissions and Climate Change from Existing Energy Infrastructure

(2010) Steven J. Davis et al.   SCIENCE