Homogeneous oxidative transformations mediated by copper catalyst systems

Guanidines strike back: Exceptional Substrate Diversity in Oxygenation Reactions Catalyzed by a Bis(µ‐oxo) Copper Complex

(2020) Sonja Herres-Pawlis et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Advances in Copper Catalyzed Alcohol Oxidation in Homogeneous Medium

(2020) Telma F. S. Silva et al.   MOLECULES

Copper–Oxygen Dynamics in the Tyrosinase Mechanism

(2020) Nobutaka Fujieda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Benzene Hydroxylation by Bioinspired Copper(II) Complexes: Coordination Geometry versus Reactivity

(2020) Sethuraman Muthuramalingam et al.   INORGANIC CHEMISTRY

Recent Advances on Copper-Catalyzed C–C Bond Formation via C–H Functionalization

(2020) Esteban Mejía et al.   SYNTHESIS-STUTTGART

The development of a Cu(I)/pyrazolylpyridineamine catalyst system for the hydroxylation of aryl halides

(2020) Lindie Marais et al.   Molecular Catalysis

Metalloglycosidase Mimics: Oxidative Cleavage of Saccharides Promoted by Multinuclear Copper Complexes under Physiological Conditions

(2020) Zhen Yu et al.   INORGANIC CHEMISTRY

Catch It If You Can: Copper-Catalyzed (Transfer) Hydrogenation Reactions and Coupling Reactions by Intercepting Reactive Intermediates Thereof

(2020) Johannes F. Teichert et al.   SYNTHESIS-STUTTGART

Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides

(2019) Alena Kulakova et al.   Catalysts

Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties

(2019) Alena N. Kulakova et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations

(2019) Rachel Trammell et al.   CHEMICAL REVIEWS

Employing Linear Tridentate Ligands with Pyrazole End Groups in Catalytic Tyrosinase Model Chemistry: Does Hemilability Matter?

(2019) Benjamin Herzigkeit et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis, characterization and catalytic properties of dinuclear complexes of copper(II) and nickel(II): Oxidation of cyclohexane, toluene and cyclopentane

(2019) Aradhita Bhattacharjee et al.   INORGANICA CHIMICA ACTA

Regioselective oxidative carbon-oxygen bond cleavage catalysed by copper(II) complexes: A relevant model study for lytic polysaccharides monooxygenases activity

(2019) Sethuraman Muthuramalingam et al.   JOURNAL OF CATALYSIS

Particulate methane monooxygenase contains only mononuclear copper centers

(2019) Matthew O. Ross et al.   SCIENCE

Biomimetic Cu/Nitroxyl Catalyst Systems for Selective Alcohol Oxidation

(2019) Lindie Marais et al.   Catalysts

Native top-down mass spectrometry provides insights into the copper centers of membrane-bound methane monooxygenase

(2019) Soo Y. Ro et al.   Nature Communications

Oxidative Cleavage of Cellobiose by Lytic Polysaccharide Monooxygenase (LPMO)-Inspired Copper Complexes

(2019) Andrea. C. Neira et al.   ACS Omega

Pyrimidine-2,4,6-trione copper(II) complexes and their catalytic activities in the peroxidative oxidation of cyclohexane

(2019) Erkan Fırıncı   JOURNAL OF MOLECULAR STRUCTURE

Copper-Catalyzed Oxidative Carbon–Carbon and/or Carbon–Heteroatom Bond Formation with O2 or Internal Oxidants

(2018) Xiaodong Tang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tyrosinase Model Systems Supported by Pyrazolylmethylpyridine Ligands: Electronic and Steric Factors Influencing the Catalytic Activity and Impact of Complex Equilibria in Solution

(2018) Benjamin Herzigkeit et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic oxidation of benzyl alcohols by new Cu(II) complexes of 1,3-oxazolidine based ligand obtained from a solvent free reaction

(2018) Rahman Bikas et al.   INORGANICA CHIMICA ACTA

Crystal structure of an alkoxide bridged dinuclear copper(II) complex: mild and selective oxidation of primary and secondary alcohols in water

(2018) Hakan Ünver   TRANSITION METAL CHEMISTRY

On the nature of the active intermediates in iron-catalyzed oxidation of cycloalkanes with hydrogen peroxide and peracids

(2018) Alexandra M. Zima et al.   Molecular Catalysis

Click. Coordinate. Catalyze. Using CuAAC Click Ligands in Small‐Molecule Model Chemistry of Tyrosinase

(2018) Benjamin Herzigkeit et al.   ChemCatChem

Three Generations of Cobalt Porphyrins as Catalysts in the Oxidation of Cycloalkanes

(2018) Katarzyna Pamin et al.   ChemSusChem

Selective catalytic oxidation of aromatic substrates employing mononuclear copper(II) catalyst with H2O2

(2018) Chengcheng Wu et al.   POLYHEDRON

Homogeneous oxidation reactions catalysed by in situ-generated triazolylidene copper(I) complexes

(2018) Siyabonga G. Mncube et al.   TRANSITION METAL CHEMISTRY

Catalytic Performance of a Dicopper–Oxo Complex for Methane Hydroxylation

(2017) Yuta Hori et al.   INORGANIC CHEMISTRY

Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations

(2017) Alena N. Kulakova et al.   INORGANIC CHEMISTRY

Copper Complexes as Bioinspired Models for Lytic Polysaccharide Monooxygenases

(2017) Alda Lisa Concia et al.   INORGANIC CHEMISTRY

Catalytic Mechanism of Fungal Lytic Polysaccharide Monooxygenases Investigated by First-Principles Calculations

(2017) Luca Bertini et al.   INORGANIC CHEMISTRY

Targeting the reactive intermediate in polysaccharide monooxygenases

(2017) Erik D. Hedegård et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Synthesis, crystal structures and catalytic activity of Cu(II) and Mn(III) Schiff base complexes: Influence of additives on the oxidation catalysis of cyclohexane and 1-phenylehanol

(2017) Oksana V. Nesterova et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp3 C–H Bonds

(2017) Rachel Trammell et al.   JOURNAL OF ORGANIC CHEMISTRY

Formally Copper(III)–Alkylperoxo Complexes as Models of Possible Intermediates in Monooxygenase Enzymes

(2017) Benjamin D. Neisen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative cleavage of polysaccharides by monocopper enzymes depends on H2O2

(2017) Bastien Bissaro et al.   Nature Chemical Biology

Chemoselective hydrogen peroxide oxidation of primary alcohols to aldehydes by a water-soluble and reusable iron(iii) catalyst in pure water at room temperature

(2017) Qi Yan et al.   NEW JOURNAL OF CHEMISTRY

A bis(pyridyl)-N-alkylamine/Cu(i) catalyst system for aerobic alcohol oxidation

(2017) Lindie Marais et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Homogeneous oxidation of alcohols in water catalyzed with Cu(II)-triphenyl acetate/bipyridyl complex

(2017) Hakan Ünver et al.   POLYHEDRON

Copper-Catalyzed Oxidation of Alkanes under Mild Conditions

(2017) Isaac Garcia-Bosch   SYNLETT

A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies

(2017) Laia Vilella et al.   Chemical Science

Copper-Catalyzed Oxidation of Alkanes with H2 O2 under a Fenton-like Regime

(2016) Isaac Garcia-Bosch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular control of monooxygenase reactivity in a copper(ii) cryptate

(2016) L. Chaloner et al.   DALTON TRANSACTIONS

Tyrosinase and catechol oxidase activity of copper(I) complexes supported by imidazole-based ligands: structure–reactivity correlations

(2016) Franziska Wendt et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

New copper(II) tetramer with arylhydrazone of barbituric acid and its catalytic activity in the oxidation of cyclic C 5 –C 8 alkanes

(2016) Manas Sutradhar et al.   POLYHEDRON

One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina

(2016) Mihoko Yamada et al.   Chemical Science

Bioinspired aerobic oxidation of alcohols with a bifunctional ligand based on bipyridine and TEMPO

(2016) Lianyue Wang et al.   RSC Advances

New Trends in Oxidative Functionalization of Carbon–Hydrogen Bonds: A Review

(2016) Georgiy Shul’pin   Catalysts

[CuO]+ and [CuOH]2+ Complexes: Intermediates in Oxidation Catalysis?

(2015) Nicole Gagnon et al.   ACCOUNTS OF CHEMICAL RESEARCH

Bioinspired Nonheme Iron Catalysts for C–H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants

(2015) Williamson N. Oloo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Developing Mononuclear Copper–Active-Oxygen Complexes Relevant to Reactive Intermediates of Biological Oxidation Reactions

(2015) Shinobu Itoh   ACCOUNTS OF CHEMICAL RESEARCH

A TEMPO-Free Copper-Catalyzed Aerobic Oxidation of Alcohols

(2015) Boran Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cellulose Degradation by Polysaccharide Monooxygenases

(2015) William T. Beeson et al.   Annual Review of Biochemistry

Efficient Biomimetic Hydroxylation Catalysis with a Bis(pyrazolyl)imidazolylmethane Copper Peroxide Complex

(2015) Claudia Wilfer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and characterization of copper(ii) complexes with multidentate ligands as catalysts for the direct hydroxylation of benzene to phenol

(2015) Li Wu et al.   DALTON TRANSACTIONS

Catalytic Models of Tyrosinase: Reactivity Differences between Systems Based on Mono- and Binucleating Ligands

(2015) Julia Schottenheim et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Copper-catalyzed hydroxylation of aryl halides: efficient synthesis of phenols, alkyl aryl ethers and benzofuran derivatives in neat water

(2015) Yangxin Wang et al.   GREEN CHEMISTRY

New Tetracopper(II) Cubane Cores Driven by a Diamino Alcohol: Self-assembly Synthesis, Structural and Topological Features, and Magnetic and Catalytic Oxidation Properties

(2015) Sara S. P. Dias et al.   INORGANIC CHEMISTRY

Hydrogen Atom Abstraction from Hydrocarbons by a Copper(III)-Hydroxide Complex

(2015) Debanjan Dhar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lytic Polysaccharide Monooxygenases in Biomass Conversion

(2015) Glyn R. Hemsworth et al.   TRENDS IN BIOTECHNOLOGY

Highly Chemoselective Aerobic Oxidation of Amino Alcohols into Amino Carbonyl Compounds

(2014) Yusuke Sasano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New catalytic model systems of tyrosinase: fine tuning of the reactivity with pyrazole-based N-donor ligands

(2014) Jessica Nadine Hamann et al.   CHEMICAL COMMUNICATIONS

Aerobic oxidation catalysis with stable radicals

(2014) Qun Cao et al.   CHEMICAL COMMUNICATIONS

Copper Active Sites in Biology

(2014) Edward I. Solomon et al.   CHEMICAL REVIEWS

Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development

(2014) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Biomimetic Hydroxylation Catalysis Through Self-Assembly of a Bis(pyrazolyl)methane Copper-Peroxo Complex

(2014) Claudia Wilfer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis, characterization and catalytic activity of new Cr(III) complex in oxidation of primary alcohols to aldehydes

(2014) Nader Noshiranzadeh et al.   INORGANICA CHIMICA ACTA

Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals

(2014) Bradford L. Ryland et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling the Catalytic Aerobic Oxidation of Phenols

(2014) Kenneth Virgel N. Esguerra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spectroscopic and computational insight into the activation of O2 by the mononuclear Cu center in polysaccharide monooxygenases

(2014) C. H. Kjaergaard et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Vanadium-catalyzed green oxidation of benzylic alcohols in water under air atmosphere

(2014) Kuniaki Marui et al.   TETRAHEDRON

An efficient and reusable vanadium based catalytic system for room temperature oxidation of alcohols to aldehydes and ketones

(2014) Gayatri Sarmah et al.   TETRAHEDRON LETTERS

Determination of tyrosinase substrate-binding modes reveals mechanistic differences between type-3 copper proteins

(2014) Mor Goldfeder et al.   Nature Communications

Mn(ii) acetate: an efficient and versatile oxidation catalyst for alcohols

(2014) Minna T. Räisänen et al.   Catalysis Science & Technology

Synthesis of two copper clusters and their catalysis towards the oxidation of benzene into phenol

(2014) XiuLi You et al.   RSC Advances

Catalytic Phenol Hydroxylation with Dioxygen: Extension of the Tyrosinase Mechanism beyond the Protein Matrix

(2013) Alexander Hoffmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic Copper-Catalyzed Organic Reactions

(2013) Scott E. Allen et al.   CHEMICAL REVIEWS

Recent insights into copper-containing lytic polysaccharide mono-oxygenases

(2013) Glyn R Hemsworth et al.   CURRENT OPINION IN STRUCTURAL BIOLOGY

A C4-oxidizing Lytic Polysaccharide Monooxygenase Cleaving Both Cellulose and Cello-oligosaccharides

(2013) Trine Isaksen et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation

(2013) Jessica M. Hoover et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

(2013) Janelle E. Steves et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quantum mechanical calculations suggest that lytic polysaccharide monooxygenases use a copper-oxyl, oxygen-rebound mechanism

(2013) S. Kim et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Selective catalytic oxidation of benzyl alcohol to benzaldehyde by a mononuclear oxovanadium(V) complex of a bis(phenolate) ligand containing bulky tert-butyl substituents

(2013) Nader Noshiranzadeh et al.   TRANSITION METAL CHEMISTRY

Catalytic Conversion of Monophenols toOrtho-Quinones in a Tyrosinase-Like Fashion: Towards More Biomimetic and More Efficient Model Systems

(2013) Julia Schottenheim et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems

(2013) Jessica M. Hoover et al.   ACS Catalysis

A novel CuCl2/BIL catalyst for direct oxidation of alcohol to acid at ambient temperature

(2012) Parasuraman Karthikeyan et al.   CATALYSIS COMMUNICATIONS

Multicopper complexes and coordination polymers for mild oxidative functionalization of alkanes

(2012) Alexander M. Kirillov et al.   COORDINATION CHEMISTRY REVIEWS

Pyrazinecarboxylic acid and analogs: Highly efficient co-catalysts in the metal-complex-catalyzed oxidation of organic compounds

(2012) Alexander M. Kirillov et al.   COORDINATION CHEMISTRY REVIEWS

Catalytic activity of some new copper(II) azo-complexes

(2012) Abdel Ghany F. Shoair   JOURNAL OF COORDINATION CHEMISTRY

Genome analyses highlight the different biological roles of cellulases

(2012) Felix Mba Medie et al.   NATURE REVIEWS MICROBIOLOGY

On the key role of hydroxyl groups in platinum-catalysed alcohol oxidation in aqueous medium

(2012) Siwar Chibani et al.   Catalysis Science & Technology

Biomass Converting Enzymes as Industrial Biocatalysts for Fuels and Chemicals: Recent Developments

(2012) Matt D. Sweeney et al.   Catalysts

Copper catalyzed oxidation of benzylic alcohols in water with H2O2

(2011) Jahir Uddin Ahmad et al.   APPLIED CATALYSIS A-GENERAL

Direct, copper-catalyzed oxidation of aromatic C–H bonds with hydrogen peroxide under acid-free conditions

(2011) Ana Conde et al.   CHEMICAL COMMUNICATIONS

Micellar system in copper-catalysed hydroxylation of arylboronic acids: facile access to phenols

(2011) Kiyofumi Inamoto et al.   CHEMICAL COMMUNICATIONS

Copper–O2 reactivity of tyrosinase models towards external monophenolic substrates: molecular mechanism and comparison with the enzyme

(2011) Malte Rolff et al.   CHEMICAL SOCIETY REVIEWS

Monodentate coordination of N-[di(phenyl/ethyl)carbamothioyl]benzamide ligands: synthesis, crystal structure and catalytic oxidation property of Cu(i) complexes

(2011) Nanjappan Gunasekaran et al.   DALTON TRANSACTIONS

Cu(bipy)2+/TEMPO-Catalyzed Oxidation of Alcohols: Radical or Nonradical Mechanism?

(2011) Paola Belanzoni et al.   INORGANIC CHEMISTRY

Ortho-Hydroxyphenylhydrazo-β-Diketones: Tautomery, Coordination Ability, and Catalytic Activity of Their Copper(II) Complexes toward Oxidation of Cyclohexane and Benzylic Alcohols

(2011) Maximilian N. Kopylovich et al.   INORGANIC CHEMISTRY

Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols

(2011) Jessica M. Hoover et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insights into the oxidative degradation of cellulose by a copper metalloenzyme that exploits biomass components

(2011) R. J. Quinlan et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The First Catalytic Tyrosinase Model System Based on a Mononuclear Copper(I) Complex: Kinetics and Mechanism

(2010) Malte Rolff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidation of benzyl alcohol and styrene using H2O2 catalyzed by tetraazamacrocycle complexes of Cu(II) and Ni(II) encapsulated in zeolite-Y

(2010) Vipin Kumar Bansal et al.   APPLIED CATALYSIS A-GENERAL

Stimulation of Lignocellulosic Biomass Hydrolysis by Proteins of Glycoside Hydrolase Family 61: Structure and Function of a Large, Enigmatic Family

(2010) Paul V. Harris et al.   BIOCHEMISTRY

Highly Efficient Synthesis of Phenols by Copper-Catalyzed Oxidative Hydroxylation of Arylboronic Acids at Room Temperature in Water

(2010) Jimin Xu et al.   ORGANIC LETTERS

An Oxidative Enzyme Boosting the Enzymatic Conversion of Recalcitrant Polysaccharides

(2010) Gustav Vaaje-Kolstad et al.   SCIENCE

Catalytic Activity Dependency on Catalyst Components in Aerobic Copper-TEMPO Oxidation

(2009) Esa T. T. Kumpulainen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trinuclear Triangular Copper(II) Clusters - Synthesis, Electrochemical Studies and Catalytic Peroxidative Oxidation of Cycloalkanes

(2009) Corrado Di Nicola et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Remarkably fast oxidation of alkanes by hydrogen peroxide catalyzed by a tetracopper(II) triethanolaminate complex: Promoting effects of acid co-catalysts and water, kinetic and mechanistic features

(2009) Marina V. Kirillova et al.   JOURNAL OF CATALYSIS

Practical Imidazole-Based Phosphine Ligands for Selective Palladium-Catalyzed Hydroxylation of Aryl Halides

(2008) Thomas Schulz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Self‐Assembled Two‐Dimensional Water‐Soluble Dipicolinate Cu/Na Coordination Polymer: Structural Features and Catalytic Activity for the Mild Peroxidative Oxidation of Cycloalkanes in Acid‐Free Medium

(2008) Marina V. Kirillova et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Reactions of a Copper(II) Superoxo Complex Lead to CH and OH Substrate Oxygenation: Modeling Copper-Monooxygenase CH Hydroxylation

(2007) Debabrata Maiti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION