Compared catalytic properties of OMS-2-based nanocomposites for the degradation of organic pollutants

In this study, Mn catalysts have been designed based on manganese oxide octahedral molecular sieve (OMS-2) supports to optimize the catalytic activity in the degradation of organic pollutants. Herein, two different synthetic strategies: Pre-incorporation vs. wet-impregnation have been employed to synthesize [PW]-OMS-2 and [PW]/OMS-2. For [PW]-OMS-2, energy dispersive X-ray spectroscopy (EDX) confirmed that dispersed granular phosphotungstic acid attached and located at the surface of OMS-2, meanwhile some W atoms have been doped into frameworks of OMS-2. However, for [PW]/OMS-2, the W atoms cannot enter the OMS-2 frameworks. A correlation has been established between the different synthetic strategies and catalytic activities. The [PW]-OMS-2 is the most highly effective and stable over than [PW]/OMS-2 and OMS-2 itself for the organic pollutants removal. This may be caused not only by the synergetic effect of [PW] and OMS-2, but also by doping W into frameworks of OMS-2. Therefore, this work provides a new environmentally-friendly and heterogeneous PMS activator and it may be put into practice to degrade organic pollutants. (c) 2021 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

Automated summary

In this study, Mn catalysts were designed based on manganese oxide octahedral molecular sieve (OMS-2) supports to optimize catalytic activity for organic pollutant degradation. The results showed that the [PW]-OMS-2 exhibited the highest efficiency and stability in organic pollutant removal compared to [PW]/OMS-2 and OMS-2 itself.