Photoelectrocatalytic degradation of glyphosate on titanium dioxide synthesized by sol-gel/spin-coating on boron doped diamond (TiO2/BDD) as a photoanode

The construction of a photoanode with several layers of titanium oxysulfate as a precursor to form titanium dioxide-TiO2 on boron doped diamond-BDD (TiO2/BDD), and its application for the photoelectro-degradation of glyphosate in aqueous medium are presented. The study was divided into three stages: i) optimization of the number of layers of the TiO2 precursor to modify BDD using a novel method combining Sol-gel/Spin-Coating; ii) characterization of the TiO2/BDD electrodes, by scanning electron microscopy-SEM, dispersive energy spectroscopy-EDX, Ray diffraction-XRD, contact angle, and electrochemical response by cyclic voltammetry using [Fe(CN)(6)](3-/4-) system; iii) degradation of glyphosate (50 mg L-1) by electrochemical oxidation on BDD and photoelectrocatalysis on TiO2/BDD in dark and UV-light conditions, at different current densities, for 5 h. The glyphosate degradation and mineralization were evaluated by High-Performance Liquid Chromatography, Total Organic Carbon, Chemical Oxygen Demand and inorganic-ions concentration (NO3-, PO43-, and NH4+). Also, the aminomethylphosphonic acid-AMPA was quantified by HPLC, as a degradation intermediate. Using five layers of the TiO2 precursor, in the construction of TiO2/BDD photoanode, and a lower contact angle, greater photoelectrocatalysis against the [Fe(CN)(6)](3-/4-) redox system and better degradation of glyphosate compared to BDD without modification were achieved. The formation of TiO2 nanoparticles (14.79 +/- 3.43 nm) in anatase phase on BDD was verified by SEM and XRD. Additionally, glyphosate degradation and mineralization were 2.3 times faster by photoelectrocatalysis on TiO2/BDD, relative to BDD, at 3 mA cm(-2) and UV-light. Thus, the presence of TiO2 on BDD increases the rate and efficiency of glyphosate degradation with respect to electrochemical oxidation on BDD. (C) 2021 Elsevier Ltd. All rights reserved.

Automated summary

The study presented the construction of a TiO2/BDD photoanode for the degradation of glyphosate in aqueous medium, showing enhanced degradation efficiency and photocatalytic activity compared to unmodified BDD. The optimized construction of the photoanode played a crucial role in improving the degradation efficiency of glyphosate.