Construction of chemoenzymatic cascade reactions for bridging chemocatalysis and Biocatalysis: Principles, strategies and prospective

Enantiocomplementary C-H Bond Hydroxylation Combining Photo-Catalysis and Whole-Cell Biocatalysis in a One-Pot Cascade Process

(2020) Yongzhen Peng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Design and synthesis of a versatile cooperative catalytic aerobic oxidation system with co-immobilization of palladium nanoparticles and laccase into the cavities of MCF

(2020) Sirvan Moradi et al.   JOURNAL OF CATALYSIS

Integrating biocatalysis with chemocatalysis for selective transformations

(2020) Xiaoqiang Huang et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Microbial Electrosynthesis – An Inventory on Technology Readiness Level and Performance of Different Process Variants

(2020) Hanna M. Fruehauf et al.   Biotechnology Journal

From CO 2 to Bioplastic – Coupling the Electrochemical CO 2 Reduction with a Microbial Product Generation by Drop‐in Electrolysis

(2020) Markus Stöckl et al.   ChemSusChem

Catalysts Encapsulated in Biopolymer Hydrogels for Chemoenzymatic One-Pot Processes in Aqueous Media

(2019) Jan Pauly et al.   ChemCatChem

Enzymes Immobilized on Carbon Nitride (C 3 N 4 ) Cooperating with Metal Nanoparticles for Cascade Catalysis

(2019) Yangxin Wang et al.   Advanced Materials Interfaces

Enantioselective One-Pot Synthesis of Biaryl-Substituted Amines by Combining Palladium and Enzyme Catalysis in Deep Eutectic Solvents

(2019) Juraj Paris et al.   ACS Sustainable Chemistry & Engineering

Approaching Bulk Chemical Nitriles from Alkenes: A Hydrogen Cyanide-Free Approach through Combination of Hydroformylation and Biocatalysis

(2019) Carmen Plass et al.   ACS Catalysis

Stabilization of Formate Dehydrogenase in a Metal-Organic Frame-work for Bioelectrocatalytic Reduction of CO₂

(2019) Yijing Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoenzymatic Cascade Synthesis of Optically Pure Alkanoic Acids by Using Engineered Arylmalonate Decarboxylase Variants

(2019) Junichi Enoki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient NADH Regeneration by a Redox Polymer-Immobilized Enzymatic System

(2019) Mengwei Yuan et al.   ACS Catalysis

Photo-Biocatalysis: Biotransformations in the Presence of Light

(2019) Luca Schmermund et al.   ACS Catalysis

Continuous Flow Chemo-Enzymatic Baeyer–Villiger Oxidation with Superactive and Extra-Stable Enzyme/Carbon Nanotube Catalyst: An Efficient Upgrade from Batch to Flow

(2019) Anna Szelwicka et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Bridging the gap between transition metal- and bio-catalysis via aqueous micellar catalysis

(2019) Margery Cortes-Clerget et al.   Nature Communications

Chemo-Enzymatic Metathesis/Aromatization Cascades for the Synthesis of Furans: Disclosing the Aromatizing Activity of Laccase/TEMPO in Oxygen-Containing Heterocycles

(2019) Caterina Risi et al.   ACS Catalysis

Developing Multicompartment Biopolymer Hydrogel Beads for Tandem Chemoenzymatic One-Pot Process

(2019) Jan Pauly et al.   Catalysts

Highly active enzyme–metal nanohybrids synthesized in protein–polymer conjugates

(2019) Xiaoyang Li et al.   Nature Catalysis

Chemoenzymatic Synthesis of an Odanacatib Precursor through a Suzuki‐Miyaura Cross‐Coupling and Bioreduction Sequence

(2019) Daniel González‐Martínez et al.   ChemCatChem

H2O2 production at low over‐potentials for electro‐enzymatic halogenation reactions

(2019) Dirk Holtmann et al.   ChemSusChem

Combining Pd nanoparticles on MOFs with cross-linked enzyme aggregates of lipase as powerful chemoenzymatic platform for one-pot dynamic kinetic resolution of amines

(2019) Meng Wang et al.   JOURNAL OF CATALYSIS

Chemo-enzymatic cascades to produce cycloalkenes from bio-based resources

(2019) Shuke Wu et al.   Nature Communications

Highly Mesoporous Metal-Organic Frameworks as Synergistic Multimodal Catalytic Platforms for Divergent Cascade Reactions

(2019) Soumen Dutta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mesoporous Core–Shell Nanostructures Bridging Metal and Biocatalyst for Highly Efficient Cascade Reactions

(2019) Shiqi Gao et al.   ACS Catalysis

Photobiocatalysis: Activating Redox Enzymes by Direct or Indirect Transfer of Photoinduced Electrons

(2018) Sahng Ha Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photo-biocatalytic One-Pot Cascades for the Enantioselective Synthesis of 1,3-Mercaptoalkanol Volatile Sulfur Compounds

(2018) Kate Lauder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoenzymatic Deracemization of Chiral Sulfoxides

(2018) Vladimír Nosek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of tandem catalyst by co-immobilization of metal and enzyme on mesoporous foam for cascaded synthesis of ( R )-phenyl ethyl acetate

(2018) Deepali B. Magadum et al.   BIOCHEMICAL ENGINEERING JOURNAL

Bioinspired construction of multi-enzyme catalytic systems

(2018) Jiafu Shi et al.   CHEMICAL SOCIETY REVIEWS

The Hydrophobic Effect Applied to Organic Synthesis: Recent Synthetic Chemistry “in Water”

(2018) Bruce H. Lipshutz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spatiotemporal compartmentalization of hepatic NADH and NADPH metabolism

(2018) Russell P. Goodman et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Enantioselective synthesis of amines by combining photoredox and enzymatic catalysis in a cyclic reaction network

(2018) Xingwei Guo et al.   Chemical Science

Enzymatic Cascade Reactions in Biosynthesis

(2018) Christopher T. Walsh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Strengthening the Combination between Enzymes and Metals in Aqueous Medium: Concurrent Ruthenium-Catalyzed Nitrile Hydration - Asymmetric Ketone Bioreduction

(2018) Elisa Liardo et al.   ChemCatChem

Combination of the Suzuki-Miyaura-cross coupling reaction with engineered transaminases

(2018) Ayad W.H. Dawood et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heterogeneous Metal-Organic-Framework-Based Biohybrid Catalysts for Cascade Reactions in Organic Solvent

(2018) Yangxin Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemoenzymatic Dynamic Kinetic Resolution of Amines in Fully Continuous-Flow Mode

(2018) Emese Farkas et al.   ORGANIC LETTERS

Amine Transaminase from Exophiala Xenobiotica—Crystal Structure and Engineering of a Fold IV Transaminase that Naturally Converts Biaryl Ketones

(2018) Aline Telzerow et al.   ACS Catalysis

An alternative approach towards poly-ε-caprolactone through a chemoenzymatic synthesis: combined hydrogenation, bio-oxidations and polymerization without the isolation of intermediates

(2017) Severin Wedde et al.   GREEN CHEMISTRY

Combining Rh-Catalyzed Diazocoupling and Enzymatic Reduction To Efficiently Synthesize Enantioenriched 2-Substituted Succinate Derivatives

(2017) Yajie Wang et al.   ACS Catalysis

Combination of Metal-Catalyzed Cycloisomerizations and Biocatalysis in Aqueous Media: Asymmetric Construction of Chiral Alcohols, Lactones, and γ-Hydroxy-Carbonyl Compounds

(2017) María J. Rodríguez-Álvarez et al.   ACS Catalysis

Unveiling the Biocatalytic Aromatizing Activity of Monoamine Oxidases MAO-N and 6-HDNO: Development of Chemoenzymatic Cascades for the Synthesis of Pyrroles

(2017) Nicoló Scalacci et al.   ACS Catalysis

Design of a Pd(0)-CalB CLEA Biohybrid Catalyst and Its Application in a One-Pot Cascade Reaction

(2017) Tamás Görbe et al.   ACS Catalysis

Chemoenzymatic one-pot reaction of noncompatible catalysts: combining enzymatic ester hydrolysis with Cu(i)/bipyridine catalyzed oxidation in aqueous medium

(2017) Henning Sand et al.   RSC Advances

A Continuous-Flow Cascade Reactor System for Subtilisin A- Catalyzed Dynamic Kinetic Resolution ofN-tert-Butyloxycarbonylphenylalanine Ethyl Thioester with Benzylamine

(2016) Péter Falus et al.   ADVANCED SYNTHESIS & CATALYSIS

From a Sequential to a Concurrent Reaction in Aqueous Medium: Ruthenium-Catalyzed Allylic Alcohol Isomerization and Asymmetric Bioreduction

(2016) Nicolás Ríos-Lombardía et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A One-Pot Cascade Reaction Combining an Encapsulated Decarboxylase with a Metathesis Catalyst for the Synthesis of Bio-Based Antioxidants

(2016) Álvaro Gómez Baraibar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Surfactant technology applied toward an active pharmaceutical ingredient: more than a simple green chemistry advance

(2016) Fabrice Gallou et al.   GREEN CHEMISTRY

An NAD(P)H-Dependent Artificial Transfer Hydrogenase for Multienzymatic Cascades

(2016) Yasunori Okamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Integrated catalysis opens new arylation pathways via regiodivergent enzymatic C–H activation

(2016) Jonathan Latham et al.   Nature Communications

Integrated Heterogeneous Metal/Enzymatic Multiple Relay Catalysis for Eco-Friendly and Asymmetric Synthesis

(2016) Carlos Palo-Nieto et al.   ACS Catalysis

Efficient In Situ Regeneration of NADH Mimics by an Artificial Metalloenzyme

(2016) Yasunori Okamoto et al.   ACS Catalysis

Light-driven biocatalytic reduction of α,β-unsaturated compounds by ene reductases employing transition metal complexes as photosensitizers

(2016) Martyn K. Peers et al.   Catalysis Science & Technology

Tandem Reactions Combining Biocatalysts and Chemical Catalysts for Asymmetric Synthesis

(2016) Yajie Wang et al.   Catalysts

Asymmetric Catalytic Cascade Reactions for Constructing Diverse Scaffolds and Complex Molecules

(2015) Yao Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Interfacing Microbial Styrene Production with a Biocompatible Cyclopropanation Reaction

(2015) Stephen Wallace et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis of Noncompatible Catalysts through Compartmentalization: Wacker Oxidation and Enzymatic Reduction in a One-Pot Process in Aqueous Media

(2015) Hirofumi Sato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoenzymatic Dynamic Kinetic Resolution: A Powerful Tool for the Preparation of Enantiomerically Pure Alcohols and Amines

(2015) Oscar Verho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoenzymatic flow cascade for the synthesis of protected mandelonitrile derivatives

(2015) Mariëlle M. E. Delville et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Chemoenzymatic Synthesis of Optically Pure l- and d-Biarylalanines through Biocatalytic Asymmetric Amination and Palladium-Catalyzed Arylation

(2015) Syed T. Ahmed et al.   ACS Catalysis

Bipyridine-functionalized amphiphilic block copolymers as support materials for the aerobic oxidation of primary alcohols in aqueous media

(2015) Henning Sand et al.   RSC Advances

A Biocompatible Alkene Hydrogenation Merges Organic Synthesis with Microbial Metabolism

(2014) Gopal Sirasani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Integrated, Cascading Enzyme-/Chemocatalytic Cellulose Conversion using Catalysts based on Mesoporous Silica Nanoparticles

(2014) Yi-Chun Lee et al.   ChemSusChem

Chemoenzymatic Dynamic Kinetic Resolution of Primary Amines Using a Recyclable Palladium Nanoparticle Catalyst Together with Lipases

(2014) Karl P. J. Gustafson et al.   JOURNAL OF ORGANIC CHEMISTRY

Tandem Catalytic Conversion of Glucose to 5-Hydroxymethylfurfural with an Immobilized Enzyme and a Solid Acid

(2014) Hua Huang et al.   ACS Catalysis

Combination of Asymmetric Organo- and Biocatalytic Reactions in Organic Media Using Immobilized Catalysts in Different Compartments

(2014) Marcel Heidlindemann et al.   ACS Catalysis

Introduction to ACS Catalysis Virtual Special Issue on Cascade Catalysis

(2014) Wolfgang Kroutil et al.   ACS Catalysis

Rescuing Auxotrophic Microorganisms with Nonenzymatic Chemistry

(2013) Yunmi Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Co-immobilization of an Enzyme and a Metal into the Compartments of Mesoporous Silica for Cooperative Tandem Catalysis: An Artificial Metalloenzyme

(2013) Karin Engström et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Tandem Catalysis by an Organometallic Complex and a Metalloenzyme

(2013) Carl A. Denard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Mesoporous-Silica-Immobilized Oxovanadium Cocatalyst for the Lipase-Catalyzed Dynamic Kinetic Resolution of Racemic Alcohols

(2013) Masahiro Egi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single Operation Stereoselective Synthesis ofAerangisLactones: Combining Continuous Flow Hydrogenation and Biocatalysts in a Chemoenzymatic Sequence

(2013) Michael J. Fink et al.   ChemCatChem

Synthesis of heterogeneous enzyme–metal nanoparticle biohybrids in aqueous media and their applications in C–C bond formation and tandem catalysis

(2013) Marco Filice et al.   CHEMICAL COMMUNICATIONS

A supramolecular approach to combining enzymatic and transition metal catalysis

(2013) Z. Jane Wang et al.   Nature Chemistry

Combination of a Suzuki cross-coupling reaction using a water-soluble palladium catalyst with an asymmetric enzymatic reduction towards a one-pot process in aqueous medium at room temperature

(2012) Sonja Borchert et al.   JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC

Synthetic cascades are enabled by combining biocatalysts with artificial metalloenzymes

(2012) V. Köhler et al.   Nature Chemistry

Development of a multifunctional catalyst for a “relay” reaction

(2012) Anal Kr. Ganai et al.   RSC Advances

Formal Asymmetric Hydration of Non-Activated Alkenes in Aqueous Medium through a “Chemoenzymatic Catalytic System”

(2011) Ingo Schnapperelle et al.   CHEMISTRY-A EUROPEAN JOURNAL

Engineering a Biometallic Whole Cell Catalyst for Enantioselective Deracemization Reactions

(2011) Joanne M. Foulkes et al.   ACS Catalysis

The Heck Reaction of Allylic Alcohols Catalyzed by Palladium Nanoparticles in Water: Chemoenzymatic Synthesis of (R)-(−)-Rhododendrol

(2010) Alberto Boffi et al.   ChemCatChem

Simultaneous iridium catalysed oxidation and enzymatic reduction employing orthogonal reagents

(2010) Francesco G. Mutti et al.   CHEMICAL COMMUNICATIONS

Highly Recyclable Chemo-/Biocatalyzed Cascade Reactions with Ionic Liquids: One-Pot Synthesis of Chiral Biaryl Alcohols

(2010) Vincent Gauchot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Suzuki-Miyaura cross-coupling catalyzed by protein-stabilized palladium nanoparticles under aerobic conditions in water: application to a one-pot chemoenzymatic enantioselective synthesis of chiral biaryl alcohols

(2009) A. Prastaro et al.   GREEN CHEMISTRY

Modular Chemoenzymatic One-Pot Syntheses in Aqueous Media: Combination of a Palladium-Catalyzed Cross-Coupling with an Asymmetric Biotransformation

(2008) Edyta Burda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dynamic Kinetic Resolution of Racemic β-Haloalcohols: Direct Access to Enantioenriched Epoxides

(2008) Robert M. Haak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY