Journal
CERAMICS INTERNATIONAL
Volume 47, Issue 18, Pages 25398-25407Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.05.262
Keywords
Solid-state electrolyte; Silica based ionogel; Ionic liquid; Co-gelation approach; Ambient pressure drying
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Funding
- Scientific and Technological Research Council of Turkey (TUB.ITAK) [119M898]
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In this study, Li-doped silica ionogels were successfully synthesized using a two-step sol-gel method. The hybrid ionogels were characterized by FTIR, SEM, BET, and TGA analysis, with specific surface areas ranging from 685 to 725 m(2)/g. The ion conductivity of the ionogel prepared with a 2 M Li+ ion solution was determined to be 4.06 x 10(-4) S/cm, showing good electrochemical stability at 3.3V.
Having excellent safety and potentially high energy density, solid-state electrolytes can be used in large-scale energy storage applications instead of flammable and volatile organic solvent-based electrolytes. Aerogels are notable candidates for solid-state electrolytes due to their low density, high porosity, high specific surface area, stable thermal behavior, and ultralow dielectric constant. In this work, Li-doped silica ionogels were synthesized by the two-step sol-gel method by using trifunctional organosilane Methyltrimethoxysilane (MTMS), as silica coprecursor along with conventional precursor TEOS. In addition, 1,3-Butylmethylimidazolium bis(trifluorosulfonyl)imide (BMIMTFSI) was selected as an ionic liquid to provide ion mobility throughout the solid skeleton. The synthesized hybrid ionogels were characterized by FTIR, SEM, BET, and TGA analyzes. It was observed that the specific surface areas of the obtained ionogels varied between 685 and 725 m(2)/g. To examine the effect of Li+ ion concentration on ion conductivity, electrolyte solutions have prepared in different concentrations (0.5 similar to 2 M). The Li+ ion conductivity of the ionogel prepared with 2 M of Li+ ion solution (M-IGE-2) was determined as 4.06 x 10(-4) S/cm by Potentiostatic EIS measurement and it possessed 3.3V of electrochemical stability.
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