Review
Chemistry, Multidisciplinary
Niklas W. Kinzel, Christophe Werle, Walter Leitner
Summary: The electrocatalytic transformation of carbon dioxide has long been a topic of interest, with recent focus on it as an alternative strategy for CO2 reduction. Studies have increasingly looked at direct electron transfer and molecular transition metal complexes as catalysts. This can lead to the production of C-1 compounds as well as more complex transformations.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Electrochemistry
M. Bellini, E. Berretti, M. Innocenti, G. Magherini, M. V. Pagliaro, L. Poggini, H. A. Miller, A. Lavacchi, F. Vizza
Summary: This paper demonstrates a convenient strategy to reduce the PGM loading in electrolysis by using ultra-low Pd loaded electrocatalysts supported on 3D architectures of titania nanotubes. The comprehensive analysis of TiO2 support synthesis, Pd catalyst deposition methods, and functional characterization of obtained materials for hydrogen and oxygen evolution, as well as the development of a new strategy to obtain short low aspect ratio 3D titania nanotubes arrays, are key aspects covered in this manuscript. The study shows that an extremely low quantity of Pd (81 mu g cm(-2)) is sufficient to significantly improve activity in an Anion Exchange Membrane (AEM) water electrolyser.
ELECTROCHIMICA ACTA
(2021)
Review
Chemistry, Physical
Yadong Du, Xiangtong Meng, Zhen Wang, Xin Zhao, Jieshan Qiu
Summary: This article reviews recent progress in graphene-based electrocatalysts for electrocatalytic CO2 reduction (ECR). The fundamentals and evaluation parameters of ECR, as well as the methods for making graphene-based catalysts for ECR, are introduced and discussed. The relationships between graphene structures, surface functional groups, heteroatom doping configurations, metal single-atom species, surface/interface properties, and catalytic performance are highlighted. Finally, the opportunities and perspectives of graphene-based catalysts for ECR are outlined.
ACTA PHYSICO-CHIMICA SINICA
(2022)
Article
Chemistry, Multidisciplinary
Yanling Qiu, Wenbin Xu, Pengfei Yao, Qiong Zheng, Huamin Zhang, Xianfeng Li
Summary: This study focuses on the electrochemical reduction of CO2 to valuable chemicals using Cu electrodes derived from Cu2O with predominant (111) facets. The optimized electrode shows high faradaic efficiency for HCOOH production, surpassing most reported Cu electrodes. The catalytic activity of unit active sites on Cu2O-derived Cu electrodes is found to be higher than that on blank Cu electrodes, with OCHO* production being favored in the presence of cetyltrimethylammonium bromide.
Article
Chemistry, Multidisciplinary
Weiwei Guo, Shoujie Liu, Xingxing Tan, Ruizhi Wu, Xupeng Yan, Chunjun Chen, Qinggong Zhu, Lirong Zheng, Jingyuan Ma, Jing Zhang, Yuying Huang, Xiaofu Sun, Buxing Han
Summary: This study reports a new catalyst design with atomically dispersed Sn sites anchored on defective CuO catalysts for CO2 electroreduction to methanol, demonstrating high efficiency and stability in H-cells.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Mirtha A. O. Lourenco, Juqin Zeng, Pravin Jagdale, Micaela Castellino, Adriano Sacco, M. Amin Farkhondehfal, Candido F. Pirri
Summary: Novel electrocatalysts based on zinc oxide and biochars were prepared through a simple and scalable route for the electrocatalytic reduction of CO2. The study found that pyrolyzed chitosan with pyridinic- and pyridone-N species outperformed pyrolyzed brewed waste coffee in terms of CO selectivity and current density. The composite with 40.6 wt % of biochar showed the best performance, with high CO selectivity and electrode activity retention during long-term CO2 electrolysis.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Chemistry, Physical
Juqin Zeng, Michele Re Fiorentin, Marco Fontana, Micaela Castellino, Francesca Risplendi, Adriano Sacco, Giancarlo Cicero, M. Amin Farkhondehfal, Filippo Drago, Candido F. Pirri
Summary: In this study, a SbCu2O material was synthesized via one-pot microwave-assisted solvothermal route and its catalytic performance in electrochemical reduction of CO2 was investigated. The Sb-Cu2O bimetallic catalyst exhibited high CO selectivity and good stability.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Applied
Xinyan Liu, Bo-Quan Li, Bing Ni, Lei Wang, Hong-Jie Peng
Summary: This article discusses the importance of producing methanol through electrochemical CO2 reduction, the application of metallomacrocyclic catalysts in CO2 reduction, and recent research progress on catalyzing CO2 to methanol using cobalt phthalocyanine-based catalysts.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Charles E. Creissen, Jose Guillermo Rivera de la Cruz, Dilan Karapinar, Dario Taverna, Moritz W. Schreiber, Marc Fontecave
Summary: This study demonstrates that surface-immobilised molecular species can act as inhibitors to finely control selectivity, offering a rational approach to modify heterogeneous catalysts in electrochemical CO2 reduction.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Yibo Guo, Sai Yao, Yuanyuan Xue, Xu Hu, Huijuan Cui, Zhen Zhou
Summary: The nitrogen-doped carbon supported Ni single-atom catalysts (Ni-SAC@NCs) show high CO selectivity and faradaic efficiency, making them promising electrocatalysts for the conversion of CO2 to CO.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Review
Electrochemistry
Yunkun Dai, Fanrong Kong, Xuehan Tai, Yunlong Zhang, Bing Liu, Jiajun Cai, Xiaofei Gong, Yunfei Xia, Pan Guo, Bo Liu, Jian Zhang, Lin Li, Lei Zhao, Xulei Sui, Zhenbo Wang
Summary: Heterogeneous single-atom catalysts (SACs) have attracted significant attention in electrochemical applications due to their high metal utilization, well-defined active sites, tunable selectivity, and excellent activity. Graphene, with its high surface area, excellent conductivity, and unique electronic properties, has been widely used as a substrate for SACs. This review provides an overview of the synthetic methods for graphene-supported single-atom catalysts (G-SACs), discusses advanced characterization techniques, summarizes recent progress in G-SACs for various electrochemical applications, and presents challenges and outlook for the development of G-SACs with outstanding catalytic activity, stability, and selectivity.
ELECTROCHEMICAL ENERGY REVIEWS
(2022)
Review
Energy & Fuels
Feng Cheng, Xinxin Zhang, Kaiwen Mu, Xin Ma, Mingyang Jiao, Zhiheng Wang, Paphada Limpachanangkul, Benjapon Chalermsinsuwan, Ying Gao, Yunhui Li, Zhipeng Chen, Licheng Liu
Summary: This paper discusses the importance of using renewable electric power to drive CO2 electrochemical reduction for producing high-value-added chemical fuels and summarizes the application and development of tin-based catalysts in CO2RR research. The study points out that tin-based catalysts may be widely used due to their low cost, environmental friendliness, and high selectivity towards formic acid, showing great potential for practical applications.
Article
Chemistry, Physical
Christopher Ehlert, Anna Piras, Juliette Schleicher, Ganna Gryn'ova
Summary: In this study, density functional theory is used to investigate the chemisorption step of the oxygen reduction reaction (ORR) pathway for a set of molecules with experimentally determined catalytic activities. Weak chemisorption is found for only negatively charged catalysts, and a strong correlation is observed between computed electron affinities and experimental catalytic activities for a range of B- and B,N-doped polyaromatic hydrocarbons. The electron affinity is proposed as a simple activity descriptor for charged (activated) catalysts on an electrode.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Energy & Fuels
Dharmendra Kumar Yadav, Fatin Saiha Omar, Mamta Yadav, Xian Liang Ho, Malcolm E. Tessensohn, K. Ramesh, S. Ramesh, Richard D. Webster, Vellaichamy Ganesan
Summary: In the field of renewable energy research, MWCNTs-ZrO2-Co3O4 has been successfully employed as a catalyst and supercapacitor material, demonstrating efficient and stable performance.
JOURNAL OF ENERGY STORAGE
(2021)
Article
Chemistry, Physical
Minmin Wang, Min Li, Yunqi Liu, Chao Zhang, Yuan Pan
Summary: This article systematically summarizes the current research status of metal single-atomic site catalysts (SASCs) for the efficient catalysis of CO2RR, discusses various methods for enhancing the activity and selectivity of SASCs, and reviews the application of in-situ characterization technologies in SASC-catalyzed CO2RR. The article also discusses the unresolved challenges in this field and proposes future research directions for the design and application of SASCs for CO2RR.
Article
Chemistry, Multidisciplinary
Zhen Li, Changlai Wang, Fangxin Ling, Lifeng Wang, Ruilin Bai, Yu Shao, Qianwang Chen, Hua Yuan, Yan Yu, Yeqiang Tan
Summary: This study proposes guiding principles for catalyst selection to improve the electrochemical performance of room-temperature sodium-sulfur batteries. MoN catalyst is introduced into carbon nanofibers as a dual-functioning host, which effectively anchors and accelerates the conversion reaction of polysulfides. Additionally, the MoN@CNFs induce uniform deposition of sodium and inhibit dendrite growth.
ADVANCED MATERIALS
(2022)
Article
Electrochemistry
Gaohui Ding, Zhiqiang Li, Lingzhi Wei, Ge Yao, Helin Niu, Changlai Wang, Fangcai Zheng, Qianwang Chen
Summary: This study used a S-doping strategy to expand the interlayer distance of carbon materials and optimize doping sites, resulting in a sample NSCRs with high reversible capacity and ultra-long cycling stability. Theoretical simulation and full-cell performance confirmed the potential of NSCRs in sodium ion batteries.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Multidisciplinary
Hong Zhang, Bin Song, Weiwei Zhang, Bowen An, Lin Fu, Songtao Lu, Yingwen Cheng, Qianwang Chen, Ke Lu
Summary: In this study, core-shell structured composite matrixes were used to achieve nearly fully reversible cycling of sulfur cathodes for Na-S batteries. The bidirectional tandem electrocatalysis enabled successive reversible conversion of both long- and short-chain polysulfides, while Fe2O3 and redox-active Fe(CN)(6)(4-)-doped polypyrrole shell facilitated specific conversions. The electrochemically reactive Na2S could be readily charged back to sulfur, and stable cycling of a Na-S pouch cell with high reversible capacity was demonstrated.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Jie Yang, Ge Yao, Zhiqiang Li, Yuhang Zhang, Lingzhi Wei, Helin Niu, Qianwang Chen, Fangcai Zheng
Summary: This study addresses the challenges of structural stability and electronic conductivity in aqueous zinc-ion batteries (AZIBs) by generating ultrathin δ-MnO2 with enlarged interlayer spacing on a flexible carbon membrane. The enlarged interlayer spacing allows for reversible intercalation/deintercalation of H+/Zn2+ ions, resulting in improved charge storage and cycle performance.
Article
Chemistry, Multidisciplinary
Hao Huang, Shi Chen, Peng Jiang, Yang Yang, Changlai Wang, Wei Zheng, Zhiyu Cheng, Minxue Huang, Lin Hu, Qianwang Chen
Summary: Theoretical calculations demonstrate that lithium embedded in N, O-doped graphene is an effective electrocatalytic active center for CO2 reduction and oxygen reduction reactions. This is due to the s-p orbital hybridization between the empty 2p orbital of lithium and the orbitals of coordinated atoms. Experimental results show that a carbon-based catalyst with well-anchored lithium atoms coordinated to N, O substituents exhibits exceptional performance in CO2 reduction and oxygen reduction reactions in acidic media.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ge Yao, Zhiqiang Li, Yuhang Zhang, Yue Xiao, Lingzhi Wei, Helin Niu, Qianwang Chen, Yang Yang, Fangcai Zheng
Summary: In this study, a flexible carbon film implanted with single-atomic Zn-N-2 moiety was constructed as an efficient sulfur host material to improve the redox kinetics and electrical conductivity of sulfur cathode in room-temperature sodium-sulfur batteries.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Dongdong Wang, Lei Zhang, Changlai Wang, Zhiyu Cheng, Wei Zheng, Pengping Xu, Qianwang Chen, Yanli Zhao
Summary: Researchers develop a facile missing-linker-confined coordination strategy to fabricate two self-assembled nanozymes: conventional nanozyme (NE) and single-atomic nanozyme (SAE). They consist of Pt nanoparticles and single Pt atoms as active catalytic sites anchored in metal-organic frameworks (MOFs) with encapsulated photosensitizers for catalase-mimicking enhanced photodynamic therapy. Compared to a Pt nanoparticle-based conventional nanozyme, a Pt single-atomic nanozyme shows enhanced catalase-mimicking activity in generating oxygen for overcoming tumor hypoxia, exhibiting more efficient reactive oxygen species generation and higher tumor inhibition rate.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Jinwei Tu, Huigang Tong, Peichen Wang, Dongdong Wang, Yang Yang, Xiangfu Meng, Lin Hu, Hui Wang, Qianwang Chen
Summary: Due to the deficiency and uneven distribution of lithium resources, potassium-ion batteries have attracted more attention as viable alternatives to lithium-ion batteries. This study shows that the unique anti-spinel structure of magnetite can serve as K+ storage sites, and carbon-coated Fe3O4@C nanoparticles exhibit high reversible capacity and hyper stable cycling performance in potassium-ion batteries.
Article
Multidisciplinary Sciences
Dongdong Wang, Jiawei Liu, Changlai Wang, Weiyun Zhang, Guangbao Yang, Yun Chen, Xiaodong Zhang, Yinglong Wu, Long Gu, Hongzhong Chen, Wei Yuan, Xiaokai Chen, Guofeng Liu, Bin Gao, Qianwang Chen, Yanli Zhao
Summary: Cancer immunotherapy is revolutionizing oncology and the combination of nanotechnology and immunotherapy provides an opportunity to enhance antitumor immune response. This study presents a mitochondria-targeting nanoplatform, MiBaMc, which consists of Prussian blue nanoparticles derived from bacteria and shows enhanced tumor inhibition in mouse models. The findings demonstrate the potential of targeted nanoparticles in boosting antitumor immunity.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Peichen Wang, Yafei Qu, Xiangfu Meng, Jinwei Tu, Wei Zheng, Lin Hu, Qianwang Chen
Summary: As an external field, a magnetic field can influence the electrocatalytic activity of catalysts through various effects, such as electron spin polarization. In this study, we investigate the sensitive response behavior of Cu2O nanocubes to an in situ magnetic field. The results show that a strong magnetic field increases the transferred electron quantity and current density, while decreasing the onset potential. Additionally, the magnetic field alters the product selectivity, with an increase in the Faraday efficiency of C-1.
Article
Chemistry, Multidisciplinary
Dong Wang, Shuo Shi, Yanyun Mao, Leqi Lei, Shaohai Fu, Jinlian Hu
Summary: A novel dual-network design strategy is proposed to prepare a high-performance cellulosic composite bioplastic metafilm with exceptional mechanical toughness, flame retardance, and solvent resistance. The metafilm exhibits a higher maximum usage temperature, lower thermal expansion coefficient, good biocompatibility, and natural biodegradation, making it a competitive substitute for plastics.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Yafei Qu, Wei Zheng, Peichen Wang, Hao Huang, Minxue Huang, Lin Hu, Hui Wang, Qianwang Chen
Summary: Electrochemical carbon dioxide reduction reaction (CO2RR) is an effective method to capture and convert CO2 into valuable chemicals and fuels, reducing CO2 emissions. Copper-based catalysts have shown excellent performance in converting CO2 into multi-carbon compounds and hydrocarbons. However, their selectivity towards coupling products is poor.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Xiaojuan Zhang, Zhiqiang Li, Xinpeng Sun, Lingzhi Wei, Helin Niu, Shan Chen, Qianwang Chen, Changlai Wang, Fangcai Zheng
Summary: This study introduces ruthenium to regulate the surface electronic structure of nickel and optimize its electrocatalytic performance in hydrogen oxidation reactions. By constructing an interfacial-oxygen configuration, the adsorption energy for surface hydroxyl species is optimized. The experimental results show that electron transfer from nickel to ruthenium weakens the hydrogen binding energy and hydroxyl binding energy, leading to enhanced performance in hydrogen oxidation reactions. Additionally, the catalyst exhibits good tolerance towards CO, making it a promising electrocatalyst for hydrogen fuel cells.
ACS MATERIALS LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Hong Zhang, Bin Song, Weiwei Zhang, Yingwen Cheng, Qianwang Chen, Ke Lu
Summary: This study demonstrates the activation of MoS2 catalyst in molten sodium for electrochemical nitrogen fixation at ambient conditions. The activated catalyst shows high electrocatalytic performance, converting N2 to NH3 with improved faradaic efficiency. The interfacial heterojunctions with sulfur vacancies synergistically enhance electron localization for nitrogen fixation and suppress proton recombination. This work provides new insights into manipulating catalyst properties by controlling chalcogenide vacancies and phase junctions.
Article
Chemistry, Physical
Hong Zhang, Zhoutai Shang, Siyuan Gao, Bin Song, Wenli Zhang, Ruiguo Cao, Shuhong Jiao, Yingwen Cheng, Qianwang Chen, Ke Lu
Summary: This study presents a superior polyiodide-free Na-I-2 battery, utilizing a unique catalyst to achieve fast and reversible iodine conversion, resulting in improved cycling stability and rate capability.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)