4.8 Article

Wafer-Scale Functional Metasurfaces for Mid-Infrared Photonics and Biosensing

Journal

ADVANCED MATERIALS
Volume 33, Issue 43, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202102232

Keywords

biosensing; CMOS compatibility; deep ultraviolet lithography; free-standing membranes; high-throughput fabrication; metasurfaces; wavefront and polarization control

Funding

  1. European Research Council (ERC) [682167]
  2. European Union Horizon 2020 Framework Program for Research and Innovation [665667, 777714]
  3. Australian Research Council [DP210101292]
  4. US Army International Office [FA520921P0034]
  5. European Research Council (ERC) [682167] Funding Source: European Research Council (ERC)

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Metasurfaces have emerged as a breakthrough platform for manipulating light at the nanoscale, with the ability to enable various optical functionalities. By realizing functional metasurfaces on almost completely transparent free-standing metal-oxide membranes, the constraints of material choice have been overcome, allowing for highly efficient and wafer-scale manufacturing techniques for mid-infrared metasurfaces.
Metasurfaces have emerged as a breakthrough platform for manipulating light at the nanoscale and enabling on-demand optical functionalities for next-generation biosensing, imaging, and light-generating photonic devices. However, translating this technology to practical applications requires low-cost and high-throughput fabrication methods. Due to the limited choice of materials with suitable optical properties, it is particularly challenging to produce metasurfaces for the technologically relevant mid-infrared spectral range. These constraints are overcome by realizing functional metasurfaces on almost completely transparent free-standing metal-oxide membranes. A versatile nanofabrication process is developed and implemented for highly efficient dielectric and plasmonic mid-infrared metasurfaces with wafer-scale and complementary metal-oxide-semiconductor (CMOS)-compatible manufacturing techniques. The advantages of this method are revealed by demonstrating highly uniform and functional metasurfaces, including high-Q structures enabling fine spectral selectivity, large-area metalenses with diffraction-limited focusing capabilities, and birefringent metasurfaces providing polarization control at record-high conversion efficiencies. Aluminum plasmonic devices and their integration into microfluidics for real-time and label-free mid-infrared biosensing of proteins and lipid vesicles are further demonstrated. The versatility of this approach and its compatibility with mass-production processes bring infrared metasurfaces markedly closer to commercial applications, such as thermal imaging, spectroscopy, and biosensing.

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