Article
Chemistry, Physical
Huibing He, Hongyu Qin, Jia Wu, Xingfa Chen, Renshu Huang, Fang Shen, Zhenrui Wu, Guoning Chen, Shibin Yin, Jian Liu
Summary: This article discusses the electrochemistry of zinc, the degradation mechanism of zinc anodes, and the surface engineering strategies to address zinc dendrite issues. It summarizes the mechanisms of different coating materials, and proposes a design principle for an ideal interface layer on the zinc metal.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Titi Li, Sanlue Hu, Chenggang Wang, Dun Wang, Minwei Xu, Caiyun Chang, Xijin Xu, Cuiping Han
Summary: By introducing a fluorine-rich double protective layer strategy and establishing a ZnF2-rich solid electrode/electrolyte interface layer, high reversibility and excellent cycling life of AZIBs have been achieved.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Shan Guo, Liping Qin, Tengsheng Zhang, Miao Zhou, Jiang Zhou, Guozhao Fang, Shuquan Liang
Summary: Electrolyte additive is a key technology in energy storage, especially for aqueous zinc-ion batteries, but there is a lack of systematic research on its features and mechanisms. A comprehensive review on commonly used zinc-ion electrolyte additives is essential for further improvements in this field.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Physical
Ao Yu, Wei Zhang, Nimanyu Joshi, Yang Yang
Summary: This review provides a comprehensive overview of research progress in ZIB anodes, including protective coating layers on zinc surfaces and intercalated anode materials. By designing protective coating layers and selecting appropriate intercalated anode materials, the inherent limitations of zinc metal anode can be overcome, leading to improved reliability and performance of ZIBs.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Kuo Wang, Tong Qiu, Lu Lin, Xiao-Xia Liu, Xiaoqi Sun
Summary: This study introduces a novel interface stabilizer, 2,3,4,5-tetrahydrothiophene-1,1-dioxide (TD), in the 3 m ZnSO4 electrolyte for zinc batteries. The adsorption of TD molecules on Zn surface inhibits the spontaneous chemical corrosions and ensures a homogeneous electrode surface. The stable solid-electrolyte interface (SEI) induced by the adsorbed TD further suppresses parasitic reactions and leads to uniform Zn deposition.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Physical
Yang Chen, Wenlong Wang, WenBin Zhao, Jinting Xu, PengHui Shi, YuLin Min
Summary: The study recommends applying a coating of nano-semiconductor material graphitic carbon nitride (g-C3N4) to the surface of zinc metal to prevent dendrite growth. The coating evenly disperses the electric field and inhibits the development of the tip effect. As a result, the zinc symmetrical battery exhibits exceptional long-term cycle stability and can be cycled at high current densities for extended periods.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Gaurav M. Thorat, Van-Chuong Ho, Junyoung Mun
Summary: Due to its low cost and high safety, metallic zinc has attracted attention as an anode material for zinc aqueous batteries (ZIBs). However, the instability of Zn metal limits the implementation of ZIBs. This study proposes a stable electrolyte based on zinc chloride/ethylene glycol deep eutectic solvent (DES) that allows safe and reversible Zn plating/stripping, resulting in a two-fold increase in cycling life compared to conventional aqueous electrolytes.
FRONTIERS IN CHEMISTRY
(2022)
Article
Engineering, Environmental
Xuena Xu, Ming Song, Min Li, Yan Xu, Limei Sun, Liluo Shi, Yaqiong Su, Chao Lai, Chao Wang
Summary: A novel bifunctional electrolyte, zinc gluconate, is used as a zinc salt for zinc-ion batteries. This electrolyte acts as a nontoxic Zn salt and provides gluconate anions for constructing a dendrite-free Zn deposition interface. Theoretical simulations and experimental observations reveal that the gluconate anions preferentially adsorb on metallic Zn to fill concaves and shield protuberances, leading to an efficient and dendrite-free Zn anode.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Nanoscience & Nanotechnology
Xiangyang Zhou, Penghui Cao, Anran Wei, Aiting Zou, Han Ye, Weiping Liu, Jingjing Tang, Juan Yang
Summary: Coating mesoporous TiO2 on Zn foil can reduce interface resistance and improve performance of aqueous zinc-ion batteries (ZIBs), enabling faster ion transfer and longer cycling stability. The analysis of ion-transfer kinetics at the interface provides valuable insights for the study of metal anodes.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Kexian Huang, Zhenguo Yao, Ke Sun, Keyi Chen, Jiulin Hu, Dongguang Yin, Chilin Li
Summary: The study proposes the use of 1,4,5,8-naphthalene diimide (NDI) layered molecules as cathode candidate for ZBs, characterized by sufficient interconnection of nano-particles for continuous electron transport and porous network for facilitated ion filtration. This enables reversible redox of carbonyl function groups with a stable gravimetric capacity around 200 mAh g(-1). Superior cycling and rate performance, benefiting from electrolyte formulation, is achieved with at least 5000 cycles under 3 A g(-1).
JOURNAL OF POWER SOURCES
(2021)
Review
Chemistry, Physical
Jianhang Huang, Xuan Qiu, Nan Wang, Yonggang Wang
Summary: The development of zinc batteries is booming due to the increasing demand for large-scale energy storage systems to integrate renewable energy into the power grid. However, commercialization of aqueous zinc batteries still faces challenges such as parasitic reactions, zinc dendrite formation, and cathode material dissolution. Understanding the Zn2+ storage mechanism and challenges of electrode materials and aqueous electrolytes, as well as actively discussing solutions for commercialization, are the key points of current research.
CURRENT OPINION IN ELECTROCHEMISTRY
(2021)
Article
Chemistry, Physical
Jianping Chen, Wanyu Zhao, Jiangmin Jiang, Xiaoli Zhao, Songhe Zheng, Zhenghui Pan, Xiaowei Yang
Summary: Rechargeable aqueous Zn-ion batteries (ZIBs) are considered as one of the most promising candidates for next-generation energy storage systems due to their high safety, low cost, environmental friendliness, and satisfactory energy density. However, issues with Zn anode including dendrite growth, hydrogen evolution reaction (HER), and side reactions hinder their large-scale practical applications by shortening lifespan and raising safety risks.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Fan Liu, Shuhong Xu, Wenbin Gong, Kaitian Zhao, Zhimin Wang, Jie Luo, Chunsheng Li, Yan Sun, Pan Xue, Chunlei Wang, Lei Wei, Qingwen Li, Qichong Zhang
Summary: By introducing fluorescent carbon dots with abundant zincophilic functional groups as bifunctional electrolyte additives, fluorescent fiber-shaped aqueous zinc-ion batteries (FFAZIBs) have been developed, achieving high energy density and long-term cyclability. The one-dimensional structure of FFAZIBs ensures the same luminance in all directions, enabling the form of multicolor display-in-battery textiles.
Article
Chemistry, Physical
Yan Wang, Haiji Huang, Dongmei Xie, Hao Wang, Jiachang Zhao, Xiaohui Zeng, Jianfeng Mao
Summary: The addition of 1 vol% sulfolane in the ZnSO4 electrolyte can adjust the solvation structure of Zn2+, reduce water activity, and regulate Zn deposition, effectively suppressing side reactions and improving the performance of AZIBs.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Editorial Material
Chemistry, Multidisciplinary
Wei Zhang, Guanjie He
Summary: Aqueous zinc metal batteries (AZMBs) are a promising electrochemical energy storage technology due to their high safety, low cost, and high energy density. However, they suffer from side reactions such as dendrite formation and hydrogen evolution. Researchers at the University of Adelaide have developed a novel electrolyte using dimethyl methylphosphonate (DMMP) as a solvent to create a stable and uniform phosphate-based solid electrolyte interface (SEI) layer on the zinc surface. This results in improved Coulombic efficiencies and capacity retentions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Nian Ran, Bo Sun, Wujie Qiu, Erhong Song, Tingwei Chen, Jianjun Liu
Summary: Through systematic high-throughput calculation screening, a series of two-dimensional TMD materials have been identified as efficient electrocatalysts for hydrogen evolution reaction, showing catalytic activity comparable to Pt(111). Furthermore, electronic structural analysis indicates that active electrons induced by defects are typically delocalized in the nearest-neighbor and next-nearest neighbor range, rather than at single-atom active sites.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Jun Mei, Tiantian Wang, Dongchen Qi, Jianjun Liu, Ting Liao, Yusuke Yamauchi, Ziqi Sun
Summary: This study proposes a novel concept of enhancing the electrochemical performance by opening three-dimensional fast ion transport channels within the NTO frameworks, achieved through a combination of oxygen vacancy generation and cation substitution strategies. The oxygen-deficient and bismuth-substituted HBNTO exhibits significant enhancements in reversible capacity, rate capability, and cycling stability, attributed to the successful opening of 3D internal ion transport channels.
Article
Chemistry, Multidisciplinary
Zhongli Hu, Xiaolin Zhao, Zhenzhu Li, Sha Li, Pengfei Sun, Gulian Wang, Qiaobao Zhang, Jianjun Liu, Li Zhang
Summary: This study demonstrates high-rate Li+ intercalation pseudocapacitance in organic molecular crystals through weak secondary bonding channels, with the heterocyclic organic molecule BPDCA showing exceptional electrochemical performance. This opens a new avenue for developing organic intercalation pseudocapacitive materials via secondary bonding structure design.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Wujie Qiu, Youwei Wang, Jianjun Liu
Summary: In this article, the correlation between the electrochemical activity of LIB materials and the response of energy to variable parameters was revealed. Multiscale computational methods and machine learning were discussed as powerful tools for accelerating the development of new LIB materials and providing method-selection reference in LIB material design.
WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Yang Gan, Yining Li, Haoxin Li, Wujie Qiu, Jianjun Liu
Summary: Layered transition metal oxides have been extensively studied as cathode materials for sodium-ion batteries. However, the underlying mechanism of multiple voltage plateaus caused by local structure transformations is not fully understood. This study reveals that charge localization is an intrinsic feature of multiple voltage plateaus in P2-NaCrO2 and emphasizes the importance of disordering design of active sites to avoid charge localization.
MATERIALS HORIZONS
(2022)
Article
Engineering, Biomedical
Jianmin Xue, Hongshi Ma, Erhong Song, Fei Han, Tian Li, Meng Zhang, Yufang Zhu, Jianjun Liu, Chengtie Wu
Summary: Mineralized calcium phosphate/bamboo composite scaffolds with high strength and excellent transport performance are successfully prepared using biotemplated approach and biomimetic mineralization. The mineralized biomaterials have high mechanical strength and low modulus, and exhibit good liquid and cell transport capacity.
ADVANCED HEALTHCARE MATERIALS
(2022)
Article
Multidisciplinary Sciences
Xiaowei Guo, Erhong Song, Wei Zhao, Shumao Xu, Wenli Zhao, Yongjiu Lei, Yuqiang Fang, Jianjun Liu, Fuqiang Huang
Summary: This study reveals the charge self-regulation effect mediated by tuning Mo-Mo bonds and S vacancies, leading to the generation of active electronic states in 1T'''-MoS2 structure, thus enhancing the activity of the hydrogen evolution reaction. The optimal 1T'''-MoS2 sample exhibits excellent electrocatalytic performance in acidic conditions, surpassing the performance of 2H-MoS2.
NATURE COMMUNICATIONS
(2022)
Article
Nanoscience & Nanotechnology
Yaning Wang, Xiaolin Zhao, Youwei Wang, Wujie Qiu, Erhong Song, Sufan Wang, Jianjun Liu
Summary: Through the design of compound structures and functional groups, it is possible to develop organic cathode materials with high discharge voltage and capacity. We propose the use of trinitroaromatic salt as a chemical raw material and demonstrate its potential for high-capacity electrode materials through electrochemical reactions and electronic structure analysis.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Haoxin Li, Yining Li, Xiaolin Zhao, Yang Gan, Wujie Qiu, Jianjun Liu
Summary: By studying the Li1.7Mn1.6O3.7F0.3 and Li2MnO3 model systems, it was found that tetrahedral oxygen exhibits higher stability than octahedral oxygen, effectively preventing the aggregation of oxidized anions. This is due to the deeper 2p lone-pair states in tetrahedral oxygen compared to octahedral oxygen. The Li-O-TM bond angle in a polyhedron was identified as a characteristic parameter that correlates with anionic redox stability.
MATERIALS HORIZONS
(2023)
Article
Chemistry, Multidisciplinary
Nian Ran, Erhong Song, Youwei Wang, Yao Zhou, Jianjun Liu
Summary: This study presents a strategy for designing 3d transition metal-oxygen complex single-atom catalytic sites to achieve high catalytic activity for the oxygen evolution reaction (OER). Through a dynamic coordination transformation, the active sites and adsorption-responsive orbitals are exposed, favoring the adsorption of oxidative intermediates and improving the OER catalytic activity.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Ling Chang, Hui Huang, Wei Feng, Hao Fu, Fenggang Qi, Jianjun Liu, Yu Chen
Summary: This study reports a multilayered nanostructure with rapid glutathione response characteristics, which can enhance the efficiency of chemodynamic therapy and comprehensively inhibit tumor metabolic activity through exchanging with glutathione in tumor cells.
Article
Chemistry, Physical
Hui Jiang, Yang Gan, Jie Liu, Xunlu Wang, Ruguang Ma, Jianjun Liu, Jiacheng Wang
Summary: This study developed Mg-doped SnS2/CNF composite materials to enhance the reaction kinetics and lithium storage of lithium-ion batteries. Mg doping effectively promoted Li-ion diffusion and improved cycling stability by inhibiting pulverization. Density functional theory calculations revealed that Mg doping induced internal electric fields, accelerating ion and electron transport kinetics.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Multidisciplinary
Xiaolin Zhao, Zhongli Hu, Yining Li, Youwei Wang, Erhong Song, Li Zhang, Jianjun Liu
Summary: Assembling inorganic-organic building blocks into local composite metal-organic materials synergistically activates transition metal ions and carbon conjugate rings, leading to high specific capacity and excellent cycling stability in electrochemical energy storage devices.
MATERIALS HORIZONS
(2021)
Article
Chemistry, Physical
Haoxin Li, Xiaolin Zhao, Yining Li, Yang Gan, Wujie Qiu, Jifen Wang, Jianjun Liu
Summary: This study presents a new strategy to enhance both cation and anion redox activity in Li2MnO3 by substituting light metals for lithium, resulting in improved reversible capacity. The findings open up possibilities for improving the energy density of rechargeable batteries by low-cost element substitution.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)