Article
Chemistry, Multidisciplinary
Liang Yin, Bob Jin Kwon, Yunyeong Choi, Christopher J. Bartel, Mengxi Yang, Chen Liao, Baris Key, Gerbrand Ceder, Saul H. Lapidus
Summary: The study successfully synthesized a promising high-voltage spinel oxide cathode material MgCrMnO4 with 18% Mg/Mn inversion, and designed a new custom operando battery device to investigate cation migration mechanisms. The research showed both reversible and partially reversible Mg2+ insertion in the cathode, with inverted Mn believed to be involved in cation migrations causing irreversible structural evolution. The operando techniques developed in this work could play a significant role in optimizing spinel oxide cathodes for multivalent ion batteries.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Energy & Fuels
Jethro J. Pryke, Rhiannon M. Kennard, Serena A. Cussen
Summary: Magnesium batteries offer advantages in terms of lower cost and better performance compared to lithium batteries, but they still face challenges such as the high charge density of magnesium ions limiting their intercalation in and out of the cathode, and strict requirements for magnesium ion coordination. This article provides an overview of key challenges and high-performance strategies, with a focus on cathode materials.
Review
Chemistry, Multidisciplinary
Fei Li, Renbin Liu, Jie Liu, Hongsen Li
Summary: The pursuit of high energy density rechargeable batteries has led to significant research efforts in developing cathode materials for lithium/sodium-ion batteries. Transition metal oxide materials with remarkable electrochemical performance are particularly promising as next-generation battery cathodes. However, challenges remain in terms of cost, lifespan, energy density and safety. This review examines the voltage hysteresis phenomenon in intercalation electrodes and presents strategies to mitigate its negative effects. Various characterization techniques related to voltage hysteresis are discussed, along with potential design trends to eliminate this phenomenon in cathode materials.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Panya Thanwisai, Panawan Vanaphuti, Zeyi Yao, Jiahui Hou, Zifei Meng, Xiaotu Ma, Hua Guo, Guanhui Gao, Zhenzhen Yang, Yan Wang
Summary: This study successfully enhanced the electrochemical stability of the cathode in sodium-ion batteries by introducing magnesium, improving structural integrity and electrochemical performance. The optimized sample showed a high capacity retention rate after cycling, indicating its potential importance in the development of next-generation sodium-ion batteries.
Article
Chemistry, Physical
Changlian Du, Zhanli Han, Hui Peng, Jiachen Tian, Xinyu Yang, Tianyu Xia, Xilan Ma, Youqi Zhu, Chuanbao Cao
Summary: Anion substitution and crystal facet regulation can optimize electrochemical reaction kinetics and enhance magnesium storage performance of CuS cathodes. Se-substituted CuS nanotube cathodes exhibit excellent storage capacity, remarkable cycling stability, and good rate capability.
JOURNAL OF POWER SOURCES
(2022)
Review
Chemistry, Physical
Lingjun Kong, Ming Liu, Hui Huang, Yunhua Xu, Xian-He Bu
Summary: Metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) are emerging families of functional materials with immense potential for high-performance electrode materials for metal-ion batteries. Despite their advantages, MOFs/COFs and their derivatives face challenges as cathode materials.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Haowei Tang, Liping Duan, Jiaying Liao, Xinru Sheng, Jianzhi Xu, Xiaosi Zhou
Summary: With the development of electrical energy storage technology, the need for new generation rechargeable batteries with low cost, high capacity, and long cycle life is crucial. Alkali-metal ion batteries (AIBs) have gained attention due to their high capacity and impressive performance. Transition metal (TM) layered oxides, as a typical AIB cathode material, have been widely studied; however, they have limitations in capacity retention and structural stability. This review summarizes the effect of magnesium ion doping on the structure and performance of AIBs, discussing the various modification strategies and future development trends for advanced AIBs.
ENERGY STORAGE MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Zhuangzhuang Zhang, Liping Duan, An Li, Jianzhi Xu, Jian Shen, Xiaosi Zhou
Summary: This review summarizes the latest advancements in layered oxide cathodes for potassium-ion batteries (PIBs) and discusses various crystal regulation strategies to improve their electrochemical performance. The relationship between the structural evolution and electrochemical properties of the modified cathodes is also investigated, providing constructive insights for future applications of PIBs.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Multidisciplinary Sciences
Venkat Pamidi, Shivam Trivedi, Santosh Behara, Maximilian Fichtner, M. Anji Reddy
Summary: Confining particle-electrolyte interactions to the surface of electrode materials is crucial for developing sustainable and safe batteries. Research reveals the potential of micron-sized single-crystal particles in sodium-ion batteries, showing high cycling and voltage stability, enhanced thermal stability, and relative stability in water and ambient atmosphere.
Review
Chemistry, Physical
Xuanpeng Wang, Zhitong Xiao, Kang Han, Xiao Zhang, Ziang Liu, Chen Yang, Jiashen Meng, Ming Li, Meng Huang, Xiujuan Wei, Liqiang Mai
Summary: This article summarizes the current research status and prospects of layered transition-metal oxide cathodes, with a focus on engineering the fine structure optimization and energy storage mechanism. Additionally, advanced characterization techniques for potassium-ion batteries are introduced, and the main research directions and hot spots of new-type transition-metal layered oxide cathodes are predicted.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Panawan Vanaphuti, Laisuo Su, Arumugam Manthiram
Summary: This study investigates the impact of electrochemical pre-lithiation on layered oxide cathodes LiNiO2 and LiCoO2 in anode-free lithium-metal batteries (AFLMBs). The research finds that LiCoO2 shows better cycle performance than LiNiO2 under an optimal amount of excess Li, and proposes a promising approach for developing tailor-made layered oxide cathodes for AFLMBs.
Article
Nanoscience & Nanotechnology
Changfeng Li, Ang Li, Mengjie Li, Peixun Xiong, Yuansheng Liu, Mingren Cheng, Dongling Geng, Yunhua Xu
Summary: This paper presents an ultrafast preparation method of layered transition-metal oxides through minute calcination of metal-organic frameworks (MOFs), allowing homogeneous distribution of atoms and fast phase transition. The method successfully obtained layered sodium manganese oxide with excellent electrochemical performance.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Engineering, Environmental
Liangmin Yu, Yusuke Yamauchi, Jie Wang, Zhibin Pang, Bing Ding, Yanjian Wang, Li Xu, Long Zhou, Xiaohui Jiang, Xuefeng Yan, Jonathan P. Hill
Summary: The current energy and environmental crises have led to an increasing demand for efficient and reliable energy storage devices. Aqueous zinc-ion batteries (ZIBs) are considered promising candidates due to their safety and low cost. However, the lack of cost-effective cathode materials with high capacities and stability hinders the practical application of ZIBs. This study introduces a unique class of layered materials as cathode materials for ZIBs, which show excellent performance and can be easily scaled up for large-scale production.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Chemistry, Physical
Emmanuel Karapidakis, Dimitra Vernardou
Summary: This mini review focuses on vanadium pentoxide as a promising cathode material, discussing general strategies for improving cathode performance and the impact of nanostructural morphologies, structure, and composites on vanadium pentoxide performance in the past five years.
Article
Materials Science, Multidisciplinary
Chunyang Wang, Lili Han, Rui Zhang, Hao Cheng, Linqin Mu, Kim Kisslinger, Peichao Zou, Yang Ren, Penghui Cao, Feng Lin, Huolin L. Xin
Summary: This study combines in situ electron microscopy and first-principles calculations to elucidate the atomic-level chemomechanical degradation pathway of LiNiO2-derived cathodes. The research reveals that the O1 phase formed at high voltages acts as a preferential site for rock-salt transformation and identifies a mechanism for planar cracks propagating simultaneously from particle interior and surface.
Article
Chemistry, Physical
Jun Jeffri B. Lidasan, Julie Anne D. del Rosario, Joey D. Ocon
Article
Nanoscience & Nanotechnology
Kristin B. Labasan, Hong-Jhen Lin, Febri Baskoro, Jazer Jose H. Togonon, Hui Qi Wong, Cha-Wen Chang, Susan D. Arco, Hung-Ju Yen
Summary: Recent studies have investigated aromatic polyimide (PI) derivatives as redox-active electrode materials for Li-ion batteries due to their high thermal stability, excellent solvent resistance, and good electrical properties. Two PI derivatives, TPA-NTCPI and TPA-PMPI, synthesized from a newly developed DiCN-TPA monomer, show promising electrochemical performance with stable specific capacities up to 1000 cycles for the cathode and high specific capacities up to 1600 mAh g(-1) for the anode after 100 cycles. These results suggest that TPA-NTCPI and TPA-PMPI could be potential organic electrode materials for next generation Li-ion batteries.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Julie Anne D. del Rosario, Guangfu Li, Marc Francis M. Labata, Joey D. Ocon, Po-Ya Abel Chuang
Summary: The influence of alkali metal cations on alkaline oxygen evolution reaction is studied through examining the electrical double layer structure and interfacial interactions. Potassium plays a crucial role in enhancing the performance of Ir0.6Co0.4 amorphous oxide in the oxygen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Green & Sustainable Science & Technology
Ashish Gulagi, Myron Alcanzare, Dmitrii Bogdanov, Eugene Esparcia Jr., Joey Ocon, Christian Breyer
Summary: Transitioning towards sustainable energy systems using indigenous renewable resources is feasible for the Philippines, with the possibility of achieving a 100% fossil-free energy system by 2050. This transition could bring various socio-economic benefits while maintaining a cost structure comparable to that of 2015.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2021)
Article
Green & Sustainable Science & Technology
Jethro Daniel A. Pascasio, Eugene A. Esparcia, Michael T. Castro, Joey D. Ocon
Summary: Geographic isolation in remote Philippine islands limits energy access, with most islands relying on costly and unsustainable diesel power. A study shows that utilizing hybrid energy systems with solar PV and wind power can ensure reliable and continuous energy supply with minimal costs and increased shares of renewable energy.
Article
Green & Sustainable Science & Technology
Marcelo M. Morato, Jose Vergara-Dietrich, Eugene A. Esparcia Jr, Joey D. Ocon, Julio E. Normey-Rico
Summary: This paper provides a thorough analysis of off-grid microgrids from the Philippine archipelago, using seven different energy clusters to represent diverse scenarios. It employs a Robust Model Predictive Control framework for energy management, analyzing the reliability of energy generation and the flexibility of demand-side compliance.
Article
Energy & Fuels
Michael T. Castro, Julie Anne D. Del Rosario, Meng Nan Chong, Po-Ya Abel Chuang, Jaeyoung Lee, Joey D. Ocon
Summary: The increasing demand for batteries in various applications has led to research efforts focused on improving their performance and safety features. Multiphysics modeling plays a key role in investigating battery research, with established fundamental electrochemical models and ongoing development of new models for specific applications. Integration of new concepts in multiphysics modeling requires consideration of phenomena beyond the continuum scale.
JOURNAL OF ENERGY STORAGE
(2021)
Review
Chemistry, Multidisciplinary
Marcel Roy Domalanta, Jaira Neibel Bamba, D. J. Donn Matienzo, Julie Anne del Rosario-Paraggua, Joey Ocon
Summary: Hydrogen is a clean, flexible, and powerful energy source that shows promise as an alternative to fossil fuels. Green hydrogen production is recognized as a prevalent solution for decarbonizing the energy system. Water electrolysis research has increased due to growing industrial interest, with a focus on improving catalysts, system design, and configuration to achieve high-performing water electrolysis. Further research efforts are needed to meet performance targets and bridge the gap between laboratory and industry.
Review
Electrochemistry
Justine Marie E. Abarro, Jon Nyner L. Gavan, Daniel Eldrei D. Loresca, Maura Andrea A. Ortega, Eugene A. Esparcia, Julie Anne D. R. Paraggua
Summary: The century-old technology of nickel-iron (Ni-Fe) batteries has regained attention in the last decade due to their robustness and longevity, making them suitable for niche applications such as off-grid energy storage systems. Persistent issues with iron passivation and hydrogen evolution reaction limit the battery's energy density, cyclability, and rate performance, despite efforts to modify electrode composition and morphology. This review comprehensively examines the fundamental reaction mechanisms and discusses and summarizes design improvements for both the anode and cathode of Ni-Fe batteries, providing insights on promising approaches and future research directions.
Review
Chemistry, Multidisciplinary
Eugene Esparcia, Jin Joo, Jinwoo Lee
Summary: Vanadium oxide bronzes are considered as battery cathode materials due to their large interlayer distance, mixed valences, and good electronic conductivity. Research has primarily focused on lithium-based batteries, with fewer studies on non-lithium-based batteries. Recent developments in using vanadium oxide bronzes for non-lithium-based batteries have been explored by multiple battery research groups, focusing on crystal structure, interactions with other battery components, and comparative electrochemical performances.
Article
Materials Science, Multidisciplinary
Jazer Jose H. Togonon, Pin-Chieh Chiang, Hong-Jhen Lin, Wei-Che Tsai, Hung-Ju Yen
Summary: This review focuses on the application and control mechanisms of carbon-based electrode materials in different metal-ion batteries, summarizes the latest developments and electrochemical performance, and considers the critical challenges and prospects for future use.
Article
Chemistry, Multidisciplinary
Ace Christian F. Serraon, Julie Anne D. Del Rosario, Po-Ya Abel Chuang, Meng Nan Chong, Yoshitada Morikawa, Allan Abraham B. Padama, Joey D. Ocon
Summary: Density functional theory was used to investigate the effects of doping alkaline earth metal atoms on graphene, revealing predominantly ionic bonding and changes in electronic and magnetic properties, potentially important for spintronic and other electronic device applications. Different characteristics were observed for beryllium doping compared to magnesium, calcium, and strontium doping, leading to varied behaviors such as non-spin-polarized p-type semiconductor and Dirac half-metal-like behavior.