4.6 Article

Highly Bright, Narrow Emissivity of InP Quantum Dots Synthesized by Aminophosphine: Effects of Double Shelling Scheme and Ga Treatment

Journal

ADVANCED OPTICAL MATERIALS
Volume 9, Issue 16, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adom.202100427

Keywords

aminophosphine precursor; Ga treatment; green‐ emissive InP quantum dots; near‐ unity quantum yield; ZnSe; ZnS double shell

Funding

  1. National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning (MSIP) [2017R1A2B3008628]
  2. Basic Science Research Program through the NRF - Ministry of Education [2015R1A6A1A03031833]
  3. Technology Innovation Program - Ministry of Trade, Industry & Energy (MOTIE, Korea) [20005011, 20010737]
  4. Korea Evaluation Institute of Industrial Technology (KEIT) [20005011] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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By optimizing the double shelling scheme and incorporating Ga treatment, InP quantum dots demonstrate unprecedented brightness and narrow emissivity. The addition of Ga during ZnSe inner shelling plays a crucial role in enhancing emissivity, resulting in near-unity PL quantum yield and narrow full-width-at-half-maximum.
Indium phosphide (InP) quantum dots (QDs) are in an unrivaled position in photoluminescence (PL) performances particularly for green and red color over other heavy-metal-free QD visible emitters. Herein, based on InP cores synthesized using an easy-to-handle, safe aminophosphine precursor, unprecedented bright, narrow emissivity is demonstrated synergically by optimizing double shelling scheme and Ga treatment. Two comparative double shells of ZnSe0.5S0.5/ZnS versus ZnSe/ZnS are generated on green-emissive InP cores, yielding better PL outcomes with respect to PL quantum yield (QY) and full-width-at-half-maximum (FWHM) from the latter scheme over the former one. With an intent to further enhance emissivity, incorporation of Ga onto InP cores in the course of ZnSe inner shelling is newly devised. Properly Ga-treated InP/ZnSe/ZnS QDs, where Ga is presumed to play a beneficial role in removing surface P dangling bond of InP core, produce a near-unity PLQY (97%) and narrow FWHM of 37 nm. The similar effectiveness is also verified in red InP/ZnSe/ZnS heterostructure, clearly indicating that Ga treatment is a viable, valid strategy toward bright emissivity in the InP QD system.

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