4.7 Article

Green Composites Based on PLA and Agricultural or Marine Waste Prepared by FDM

Journal

POLYMERS
Volume 13, Issue 9, Pages -

Publisher

MDPI
DOI: 10.3390/polym13091361

Keywords

Posidonia oceanica; Opuntia ficus indica; polylactic acid; additive manufacturing; 3D printing; aspect ratio; biocomposites; degradation; mechanical properties; water contact angle

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The study demonstrated that adding lignocellulosic fillers from Opuntia ficus indica and Posidonia oceanica to PLA can reduce costs and promote environmental sustainability without compromising processing and mechanical performance. Additionally, the increase in surface hydrophilicity may positively impact the biodegradability of the materials after disposal.
Three dimensional-printability of green composites is recently growing in importance and interest, especially in the view of feasibility to valorize agricultural and marine waste to attain green fillers capable of reducing bioplastic costs, without compromising their processability and performance from an environmental and mechanical standpoint. In this work, two lignocellulosic fillers, obtained from Opuntia ficus indica and Posidonia oceanica, were added to PLA and processed by FDM. Among the 3D printed biocomposites investigated, slight differences could be found in terms of PLA molecular weight and filler aspect ratio. It was shown that it is possible to replace up to 20% of bioplastic with low cost and ecofriendly natural fillers, without significantly modifying the processability and the mechanical performance of the neat matrix; at the same time, an increase of surface hydrophilicity was found, with possible positive influence on the biodegradability of such materials after disposal.

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