Chirality-Induced Catalyst Aggregation: Insights into Catalyst Speciation and Activity Using Chiral Aluminum Catalysts in Cyclic Ester Ring-Opening Polymerization

In Situ Versus Isolated Zinc Catalysts in the Selective Synthesis of Homo and Multi-block Polyesters

(2020) Weronika Gruszka et al.   MACROMOLECULES

Hyperpositive nonlinear effects in asymmetric catalysis

(2020) Yannick Geiger et al.   Nature Catalysis

Next Generation of Zinc Bisguanidine Polymerization Catalysts towards Highly Crystalline, Biodegradable Polyesters

(2020) Alina Hermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Dual-Stereocontrol Mechanism: Heteroselective Polymerization of rac-Lactide and Syndioselective Polymerization of meso-Lactide by Chiral Aluminum Salan Catalysts

(2019) Rami Hador et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Towards New Robust Zn(II) Complexes for the Ring‐Opening Polymerization of Lactide Under Industrially Relevant Conditions

(2019) Pascal M. Schäfer et al.   ChemistryOpen

Mechanism-Inspired Design of Bifunctional Catalysts for the Alternating Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides

(2019) Brooks A. Abel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploiting Noncovalent Interactions for Room-Temperature Heteroselective rac-Lactide Polymerization Using Aluminum Catalysts

(2019) S. Gesslbauer et al.   ACS Catalysis

Ring-Opening Polymerization of ε-Caprolactone Initiated by Multinuclear Aluminum Methanetris(aryloxido) Complexes

(2019) Masataka Oishi et al.   ORGANOMETALLICS

Highly active aluminium catalysts for room temperature ring-opening polymerisation of rac-lactide

(2018) S. Gesslbauer et al.   DALTON TRANSACTIONS

Aggregated initiators: defining their role in the ROP of rac-lactide

(2018) Jean-Marie E. P. Cols et al.   DALTON TRANSACTIONS

Highly Active Chiral Oxazolinyl Aminophenolate Magnesium Initiators for Isoselective Ring-Opening Polymerization of rac-Lactide: Dinuclearity Induced Enantiomorphic Site Control

(2018) Jianwen Hu et al.   MACROMOLECULES

ppm-Level Thermally Switchable Yttrium Phenoxide Catalysts for Moisture-Insensitive and Controllably Immortal Polymerization of rac-Lactide

(2018) Changjuan Chen et al.   MACROMOLECULES

Dinuclear catalysts for the ring opening polymerization of lactide

(2018) Alexandre B. Kremer et al.   COORDINATION CHEMISTRY REVIEWS

Lactide as the Playmaker of the ROP Game: Theoretical and Experimental Investigation of Ring-Opening Polymerization of Lactide Initiated by Aminonaphtholate Zinc Complexes

(2017) Dawid Jędrzkiewicz et al.   INORGANIC CHEMISTRY

Mechanistic Insights into the Alternating Copolymerization of Epoxides and Cyclic Anhydrides Using a (Salph)AlCl and Iminium Salt Catalytic System

(2017) Megan E. Fieser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A multifunctional catalyst that stereoselectively assembles prodrugs

(2017) Daniel A. DiRocco et al.   SCIENCE

Mechanism and Stereocontrol in Isotactic rac-Lactide Polymerization with Copper(II) Complexes

(2017) Pargol Daneshmand et al.   ACS Catalysis

A Simple Graphical Method to Determine the Order in Catalyst

(2016) Jordi Burés   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Controlling the stereoselectivity of rac-LA polymerization by chiral recognition induced the formation of homochiral dimeric metal alkoxides

(2016) P. Horeglad et al.   Polymer Chemistry

The FAIR Guiding Principles for scientific data management and stewardship

(2016) Mark D. Wilkinson et al.   Scientific Data

Isotacticrac-Lactide Polymerization with Copper Complexes: The Influence of Complex Nuclearity

(2015) Solène Fortun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Insight into the Stereochemical Control of Lactide Polymerization by Salan-Aluminum Catalysts

(2015) Konstantin Press et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Kinetic Profiling of Catalytic Organic Reactions as a Mechanistic Tool

(2015) Donna G. Blackmond   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of rac-lactide

(2015) Matthew D. Jones et al.   Chemical Science

Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization

(2015) D. C. Aluthge et al.   Chemical Science

Synthesis and characterisation of unsymmetrical Zr(iv) amine tris(phenolate) complexes and their application in ROP of rac-LA

(2014) Thomas R. Forder et al.   DALTON TRANSACTIONS

Potassium, zinc, and magnesium complexes of a bulky OOO-tridentate bis(phenolate) ligand: synthesis, structures, and studies of cyclic ester polymerisation

(2013) Yong Huang et al.   DALTON TRANSACTIONS

Zinc Complexes of Bipyrrolidine-Based Diamine-Diphenolato and Diamine-Diolato Ligands: Predetermination of Helical Chirality Around Tetrahedral Centres

(2013) Ekaterina Sergeeva et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Kinetic Analysis of the Living Ring-Opening Polymerisation ofL-Lactide with Tin(II) Initiators

(2013) Lingfang Wang et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Understanding the Mechanism of Polymerization of ε-Caprolactone Catalyzed by Aluminum Salen Complexes

(2013) Maria O. Miranda et al.   INORGANIC CHEMISTRY

{Phenoxy-imine}aluminum versus -indium Complexes for the Immortal ROP of Lactide: Different Stereocontrol, Different Mechanisms

(2013) Mickael Normand et al.   ORGANOMETALLICS

Transfer of chirality from ligands to metal centers: recent examples

(2012) Jeanne Crassous   CHEMICAL COMMUNICATIONS

Dimethylaluminum complexes bearing a chiral diketiminate ligand: Synthesis, characterization and ring-opening polymerization of ε-caprolactone

(2012) Dexu Kong et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Mechanism of Living Lactide Polymerization by Dinuclear Indium Catalysts and Its Impact on Isoselectivity

(2012) Insun Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Roles of Monomer Binding and Alkoxide Nucleophilicity in Aluminum-Catalyzed Polymerization of ε-Caprolactone

(2012) Keying Ding et al.   MACROMOLECULES

Salan ligands assembled around chiral bipyrrolidine: predetermination of chirality around octahedral Ti and Zr centres

(2009) Ekaterina Sergeeva et al.   CHEMICAL COMMUNICATIONS

Chiral transfer in coordination complexes: towards molecular materials

(2009) Jeanne Crassous   CHEMICAL SOCIETY REVIEWS

Chiral Salan Aluminium Ethyl Complexes and Their Application in Lactide Polymerization

(2009) Hongzhi Du et al.   CHEMISTRY-A EUROPEAN JOURNAL

2,2′-Bipyrrolidine versus 1,2-Diaminocyclohexane as Chiral Cores for Helically Wrapping Diamine−Diolate Ligands

(2009) Ekaterina Sergeeva et al.   INORGANIC CHEMISTRY