Comparison of the performance of atmospheric pressure glow discharges operated between a flowing liquid cathode and either a pin-type anode or a helium jet anode for the Ga and In determination by the optical emission spectrometry

Novel atmospheric pressure glow discharge (APGD) microplasma systems, sustained between a miniaturized flowing liquid cathode (FLC) and either a pin-type anode or a He nozzle jet were investigated for the determination of Ga and In by the optical emission spectrometry (OES). The most influential working parameters, i.e., solution flow rate, acid concentration, discharge current, and He flow rate, were optimized for both studied systems. Furthermore, the effect of the addition of low molecular weight organic compounds (LMWOCs) into the FLC solution on the signals intensity of Ga and In was investigated. Subsequently, the impact of concomitant ions on the signals intensity of Ga and In was thoroughly studied and it was established that both studied methods are relatively resistant to matrix effects. Under the optimized conditions, the detection limits (DLs, assessed on the basis of the 3s criterion) of the studied elements were similar for both discharges and ranged between 1.8 and 2.3 mu g L-1 for Ga and 0.37-0.40 mu g L-1 for In. The received DLs were therefore better than those obtained for other spectrometric methods being premised upon microplasma systems and comparable with those obtained by currently employed large-scale instrumentation. The system with the pin-type anode was successfully applied for the Ga and In determination in four leachates of solders and electronic scrap as well as river water, using external calibration with simple standard solutions. The received results were compared to those obtained from ICP-OES or ICP-MS measurements and their recoveries were fallen within the range of 98-114%, confirming the excellent accuracy and reliability of the developed FLC-APGD-OES method.

Automated summary

In this study, novel atmospheric pressure microplasma systems were investigated for the determination of Ga and In by optical emission spectrometry (OES), with optimized working parameters and the addition of low molecular weight organic compounds (LMWOCs) into the solution. The impact of concomitant ions on the signals intensity of Ga and In was also studied, showing the resistance to matrix effects. The detection limits obtained under optimized conditions were comparable to those obtained by large-scale instrumentation, confirming the accuracy and reliability of the developed FLC-APGD-OES method.