Journal
SYNLETT
Volume 32, Issue 18, Pages 1796-1815Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1472-4594
Keywords
total synthesis; natural products; enyne cycloisomerization; polyene cyclization; quinone methides
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Funding
- National Natural Science Foundation of China (NSFC) [21971219, 21672181]
- Research Grants Council (RGC), University Grants Committee (Hong Kong) [CUHK14304819, CUHK14309216, CUHK14303815, 403012]
- Innovation and Technology Commission -Hong Kong
- Chinese University of Hong Kong (CUHK)
- State Key Laboratory of Synthetic Chemistry
- University Development Fund Grants from The Chinese University of Hong Kong, Shenzhen
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This review summarizes the prominent applications of three pivotal reactions - enyne cycloisomerization, polyene cyclization, and quinone methide formation - in synthesizing the complex polycyclic skeleton of cryptotrione, covering literature results between 2011 and 2020.
Three pivotal reactions, namely, enyne cycloisomerization, polyene cyclization, and quinone methide formation, are applied to synthesize the complex polycyclic skeleton of cryptotrione. This review summarizes the most prominent applications of these three reactions to the total syntheses of natural products, covering results published in the literature between 2011 and 2020.
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