A Tutorial on Selectivity Determination in C(sp2)–H Oxidative Addition of Arenes by Transition Metal Complexes

Achieving Site-Selectivity for C–H Activation Processes Based on Distance and Geometry: A Carpenter’s Approach

(2020) Guangrong Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

How Big is the Pinacol Boronic Ester as a Substituent?

(2020) Valerio Fasano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Origins of Regioselectivity in Cobalt-Catalyzed C(sp2)-H Borylation of Benzoate Esters and Arylboronate Esters

(2020) Tyler P. Pabst et al.   Chem

Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand

(2019) Stephan M. Rummelt et al.   ORGANOMETALLICS

Oligothiophene Synthesis by a General C–H Activation Mechanism: Electrophilic Concerted Metalation–Deprotonation (eCMD)

(2019) Long Wang et al.   ACS Catalysis

Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp2)-H Oxidative Addition Results in ortho-to-Fluorine Selectivity

(2019) Tyler P. Pabst et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Carbon–Hydrogen Bonds via 1,2-RH-Addition/-Elimination to Early Transition Metal Imides

(2018) Peter T. Wolczanski   ORGANOMETALLICS

Pitfalls in Computational Modeling of Chemical Reactions and How To Avoid Them

(2018) Ho Ryu et al.   ORGANOMETALLICS

Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future

(2018) Louis-Charles Campeau et al.   ORGANOMETALLICS

C(sp2)–H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities

(2017) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Platinum-Catalyzed C–H Functionalization

(2016) Jay A. Labinger   CHEMICAL REVIEWS

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

(2016) Paula Ruiz-Castillo et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

(2016) Tim Cernak et al.   CHEMICAL SOCIETY REVIEWS

Mechanistic Investigation of Iridium-Catalyzed C–H Borylation of Methyl Benzoate: Ligand Effects in Regioselectivity and Activity

(2016) Jesús Jover et al.   ORGANOMETALLICS

Ligand-enabled meta-C–H activation using a transient mediator

(2015) Xiao-Chen Wang et al.   NATURE

A meta-selective C–H borylation directed by a secondary interaction between ligand and substrate

(2015) Yoichiro Kuninobu et al.   Nature Chemistry

Editorial: Introducing Tutorials

(2015) Paul J. Chirik   ORGANOMETALLICS

Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

(2014) Theresia Ahrens et al.   CHEMICAL REVIEWS

Iridium-Catalyzed C–H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism

(2014) Matthew A. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Distortion/Interaction Analysis Reveals the Origins of Selectivities in Iridium-Catalyzed C–H Borylation of Substituted Arenes and 5-Membered Heterocycles

(2014) Aaron G. Green et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conformation-induced remote meta-C–H activation of amines

(2014) Ri-Yuan Tang et al.   NATURE

Cross-Coupling of Remote meta-C–H Bonds Directed by a U-Shaped Template

(2013) Li Wan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of remote meta-C–H bonds assisted by an end-on template

(2012) Dasheng Leow et al.   NATURE

Iridium-Catalyzed, Substrate-Directed C–H Borylation Reactions of Benzylic Amines

(2012) Andrew J. Roering et al.   ORGANIC LETTERS

Radical Mechanisms in the Reaction of Organic Halides with Diiminepyridine Cobalt Complexes

(2012) Di Zhu et al.   ORGANOMETALLICS

Natural Bond Orbital Analysis of the Electronic Structure of [LnM(CH3)] and [LnM(CF3)] Complexes

(2012) Andrés G. Algarra et al.   ORGANOMETALLICS

Iridium-catalyzed C–H borylation of quinolines and unsymmetrical 1,2-disubstituted benzenes: insights into steric and electronic effects on selectivity

(2012) Hazmi Tajuddin et al.   Chemical Science

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

(2011) Eric Clot et al.   ACCOUNTS OF CHEMICAL RESEARCH

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes

(2011) Serge I. Gorelsky et al.   JOURNAL OF ORGANIC CHEMISTRY

Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

(2010) Britt A. Vanchura et al.   CHEMICAL COMMUNICATIONS

Binuclear Oxidative Addition of Aryl Halides

(2010) Di Zhu et al.   ORGANOMETALLICS

Ortho-C–H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium–phosphine complexes

(2009) Tatsuo Ishiyama et al.   CHEMICAL COMMUNICATIONS

Carbon–hydrogen vs. carbon–halogen oxidative addition of chlorobenzene by a neutral iridium complex explored by DFT

(2009) Hong Wu et al.   DALTON TRANSACTIONS

Kinetic C−H Oxidative Addition vs Thermodynamic C−X Oxidative Addition of Chlorobenzene by a Neutral Rh(I) System. A Density Functional Theory Study†

(2009) Hong Wu et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Exceptional Sensitivity of Metal−Aryl Bond Energies toortho-Fluorine Substituents: Influence of the Metal, the Coordination Sphere, and the Spectator Ligands on M−C/H−C Bond Energy Correlations

(2009) Eric Clot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trends in Ground-State Entropies for Transition Metal Based Hydrogen Atom Transfer Reactions

(2009) Elizabeth A. Mader et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Olefin Substitution in (silox)3M(olefin) (silox =tBu3SiO; M = Nb, Ta):  The Role of Density of States in Second vs Third Row Transition Metal Reactivity

(2008) Kurt F. Hirsekorn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY