Tuning the Selectivity and Reactivity of Metal-Substituted Polyoxometalates as Artificial Proteases by Varying the Nature of the Embedded Lewis Acid Metal Ion

Highly Amino Acid Selective Hydrolysis of Myoglobin at Aspartate Residues as Promoted by Zirconium(IV)-Substituted Polyoxometalates

(2015) Hong Giang T. Ly et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural Characterization of the Complex between Hen Egg-White Lysozyme and ZrIV-Substituted Keggin Polyoxometalate as Artificial Protease

(2015) Annelies Sap et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective hydrolysis of oxidized insulin chain B by a Zr(iv)-substituted Wells–Dawson polyoxometalate

(2015) Annelies Sap et al.   DALTON TRANSACTIONS

Comparative Study of the Reactivity of Zirconium(IV)-Substituted Polyoxometalates towards the Hydrolysis of Oligopeptides

(2015) Hong Giang T. Ly et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Regioselective Hydrolysis of Human Serum Albumin by ZrIV-Substituted Polyoxotungstates at the Interface of Positively Charged Protein Surface Patches and Negatively Charged Amino Acid Residues

(2014) Karen Stroobants et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular Origin of the Hydrolytic Activity and Fixed Regioselectivity of a ZrIV-Substituted Polyoxotungstate as Artificial Protease

(2014) Karen Stroobants et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cover Picture: Stereo- and Regioselective Phyllobilane Oxidation in Leaf Homogenates of the Peace Lily (Spathiphyllum wallisii): Hypothetical Endogenous Path to Yellow Chlorophyll Catabolites (Chem. Eur. J. 1/2015)

(2014) Clemens Vergeiner et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Mechanistic Study of the Spontaneous Hydrolysis of Glycylserine as the Simplest Model for Protein Self-Cleavage

(2013) Tzvetan T. Mihaylov et al.   CHEMISTRY-A EUROPEAN JOURNAL

Polyoxometalates as a Novel Class of Artificial Proteases: Selective Hydrolysis of Lysozyme under Physiological pH and Temperature Promoted by a Cerium(IV) Keggin-Type Polyoxometalate

(2013) Karen Stroobants et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amino acid side chain induced selectivity in the hydrolysis of peptides catalyzed by a Zr(iv)-substituted Wells–Dawson type polyoxometalate

(2013) Stef Vanhaecht et al.   DALTON TRANSACTIONS

Amide bond hydrolysis in peptides and cyclic peptides catalyzed by a dimeric Zr(iv)-substituted Keggin type polyoxometalate

(2013) Hong Giang T. Ly et al.   DALTON TRANSACTIONS

Hydrolysis of Dipeptides Catalyzed by a Zirconium(IV)-Substituted Lindqvist Type Polyoxometalate

(2013) Hong Giang T. Ly et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Peptide Bond Hydrolysis Catalyzed by the Wells–Dawson Zr(α2-P2W17O61)2 Polyoxometalate

(2012) Gregory Absillis et al.   INORGANIC CHEMISTRY

Reactive ZrIV and HfIV Butterfly Peroxides on Polyoxometalate Surfaces: Bridging the Gap between Homogeneous and Heterogeneous Catalysis

(2011) Mauro Carraro et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cytochrome C Biosensor—A Model for Gas Sensing

(2011) Michael Hulko et al.   SENSORS

Polyoxometalates: Building Blocks for Functional Nanoscale Systems

(2010) De-Liang Long et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselective Catalysis with Organosoluble Lewis Acidic Polyoxotungstates

(2010) Nathalie Dupré et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dendritic Zirconium-Peroxotungstosilicate Hybrids: Synthesis, Characterization, and Use as Recoverable and Reusable Sulfide Oxidation Catalysts

(2010) Claire Jahier et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and structural investigation of sandwich polyoxotungstates containing cerium (III/IV) and mono-lacunary Keggin tungstophosphate units

(2010) Jun Iijima et al.   INORGANICA CHIMICA ACTA

Synthesis and structures of dinuclear ZrIV and HfIV hydroxo complexes with the monolacunar Keggin and Dawson anions

(2010) M. N. Sokolov et al.   RUSSIAN CHEMICAL BULLETIN

Green Oxidation Reactions by Polyoxometalate-Based Catalysts: From Molecular to Solid Catalysts

(2010) Noritaka Mizuno et al.   TOPICS IN CATALYSIS

A kinetic and mechanistic study on the silver (I)-catalyzed oxidation of l-alanine by cerium (IV) in sulfuric acid medium

(2010) T. Sumathi et al.   Arabian Journal of Chemistry

The Construction of High-Nuclearity Isopolyoxoniobates with Pentagonal Building Blocks: [HNb27O76]16− and [H10Nb31O93(CO3)]23−

(2009) Ryo Tsunashima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrolytic cleavage of DNA-model substrates promoted by polyoxovanadates

(2009) Nele Steens et al.   DALTON TRANSACTIONS

Zirconium and hafnium aqua complexes [(H2O)3M(P2W17O61)]6−: Synthesis, characterization and substitution of water by chiral ligand

(2009) Maxim N. Sokolov et al.   INORGANICA CHIMICA ACTA

Relation among the 2:2-, 1:1- and 1:2-type complexes of hafnium(IV)/zirconium(IV) with mono-lacunary α2-Dawson polyoxometalate ligands: Synthesis and structure of the 2:2-type complexes [{α2-P2W17O61M(μ-OH)(H2O)}2]14− (M=Hf, Zr)

(2009) Yoshio Saku et al.   INORGANICA CHIMICA ACTA

Molecular Interactions between Wells−Dawson Type Polyoxometalates and Human Serum Albumin

(2008) Guangjin Zhang et al.   BIOMACROMOLECULES

Phosphoesterase activity of polyoxomolybdates: diffusion ordered NMR spectroscopy as a tool for obtaining insights into the reactivity of polyoxometalate clusters

(2008) Luk Van Lokeren et al.   CHEMICAL COMMUNICATIONS

Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

(2008) Anna Proust et al.   CHEMICAL COMMUNICATIONS

Synthesis of a Dialuminum-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives

(2008) Yuji Kikukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrolytic Cleavage of an RNA-Model Phosphodiester Catalyzed by a Highly Negatively Charged Polyoxomolybdate [Mo7O24]6−Cluster

(2008) Gregory Absillis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Questioning the paradigm of metal complex promoted phosphodiester hydrolysis: [Mo7O24]6−polyoxometalate cluster as an unlikely catalyst for the hydrolysis of a DNA model substrate

(2007) Els Cartuyvels et al.   CHEMICAL COMMUNICATIONS