Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 28, Pages 4565-4572Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201600682
Keywords
Rhodium; Iridium; Fluorine; Peroxido ligands
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Funding
- Deutsche Forschungsgemeinschaft (DFG)
- DFG research training group Fluorine as a Key Element
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The rhodium and iridium fluorido bifluorido complexes trans-[Rh(4-C5F4N)(F)(FHF)(CNtBu)(PEt3)(2)] (1) and trans-[Ir(4-C5F4N)(F)(FHF)(CNtBu)(PiPr(3))(2)] (2) have been synthesized by protonation of the peroxido complexes trans-[M(4-C5F4N)(O-2)(CNtBu)(PR3)(2)] with an HF source (M = Rh, R = Et; M = Ir, R = iPr). Abstraction of the coordinated HF resulted in the formation of the difluorido compounds trans-[M(4-C5F4N)(F)(2)(CNtBu)(PR3)(2)] (4: M = Rh, R = Et; 5: M = Ir, R = iPr).
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