Article
Engineering, Chemical
Tao Yang, Guoliang Liu, Chen Gu, Hui Wen, Ze-Jiu Diao, Si-Yi Liu, Shi-Chao Qi, Mingrui Zuo, Lifeng Ding, Xiao-Qin Liu, Lin-Bing Sun
Summary: In this study, a photo-responsive adsorbent (Azo-U) consisting of azobenzene-modified UiO-67 was successfully constructed for controllable CO2 capture. It exhibited reversible photo-responsive properties, high stability, and a CO2 regulation efficiency of up to 25.5%. This research provides new insights for the design and fabrication of target-specific photo-responsive adsorbents.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Review
Chemistry, Multidisciplinary
Wojciech Danowski, Thomas van Leeuwen, Wesley R. Browne, Ben L. Feringa
Summary: Molecular machines, switches, and motors allow precise control of nanoscale molecular motion in artificial systems. Integrating these compounds into robust material scaffolds is a strategy for producing smart materials with unique properties. This review focuses on a subclass of structures, namely light-responsive porous materials, and their potential applications.
NANOSCALE ADVANCES
(2021)
Article
Engineering, Chemical
Ding-Ming Xue, Wen-Juan Zhang, Xiao-Qin Liu, Shi-Chao Qi, Lin-Bing Sun
Summary: A series of azobenzene-functionalized porous polymers (PTM-AZOs) were successfully synthesized, and their CO₂ capture performance was improved by regulating the variable pore structure.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Multidisciplinary
Avik Chowdhury, Sudip Bhattacharjee, Rupak Chatterjee, Asim Bhaumik
Summary: The increase in atmospheric CO2 concentration has led to global warming and climate change, highlighting the need for effective adsorbents and catalysts for CO2 capture and fixation. In this study, a new porous cross-linked organic polymer DAT-1 was synthesized, exhibiting high CO2 capture capacity and excellent catalytic activity for CO2 conversion to reactive organics.
JOURNAL OF CO2 UTILIZATION
(2022)
Article
Materials Science, Multidisciplinary
Sheng-Tao Wang, Peng Tan, Wen-Qiang Weng, Long Zheng, Xiao-Qin Liu, Lin-Bing Sun
Summary: In this study, a new type of photoresponsive metal-organic polyhedra (PMOP) with pendant azobenzene units was successfully synthesized and dispersed into a metal-organic framework (MOF), resulting in improved CO2 uptake and controllability. Visible light allows CO2 molecules to freely enter the nanospace of PMOP, while ultraviolet light prevents their entrance. Additionally, UV/visible light irradiation enables the reversible cis-/trans-isomerization of the azobenzene groups in PMOP. The adsorption variation of CO2 captured by the PMOP@MOF composite under light is 15.5%, significantly higher than that of bulk PMOP (5.9%). These findings provide insights into the potential of PMOPs and inspire the development of efficient strategies for controlling adsorption processes.
SCIENCE CHINA-MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Thien S. Nguyen, Nesibe A. Dogan, Haeseong Lim, Cafer T. Yavuz
Summary: The development of porous solid materials with tunable amine content is necessary for efficient CO2 capture, and unifying both sorbents in one system can address regeneration issues.
ACCOUNTS OF CHEMICAL RESEARCH
(2023)
Article
Engineering, Environmental
Yanfang Liu, Zhiqiang Wang, Wenhui Zhao, Jili Hou, Longpeng Cui, Liang Zou, Chenghao Li, Hongwei Li, Yu Wu, Run Xu, Yongfa Zhu
Summary: The preparation of hierarchical porous nanosilica using coal gasification fly ash as a silicon source was achieved by microwave-assisted alkaline extraction followed by hydrothermal synthesis. This method showed fast and efficient silicon extraction with less impurity metal ions. The use of specific compounds as swelling agents induced intergranular pores, which significantly improved the CO2 adsorption capacity of the nanosilica. The isosteric heat of adsorption indicated the presence of both physisorption and chemisorption in the adsorption process.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Michael C. C. Brand, Nicola Rankin, Andrew I. I. Cooper, Rebecca L. L. Greenaway
Summary: Porous materials, including solids and emerging liquids, have attracted extensive research attention due to their potential applications in gas adsorption and molecular separations. In this study, a new method of gas release from porous liquids is explored. By incorporating a photoresponsive MOF in an ionic liquid, selective CO2 uptake over CH4 is achieved, and gas release can be controlled using UV light.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
James N. Burrow, Ryan A. Ciufo, Lettie A. Smith, Yu Wang, David C. Calabro, Graeme Henkelman, C. Buddie Mullins
Summary: Ca2+ acts as a structure-directing agent to transform melon-based carbon nitride to crystalline CaPHI with ordered pore channels, extended visible light absorption, and altered band structure as compared to KPHI. Protons can replace Ca2+ atoms in CaPHI to enhance porosity without disrupting crystal structure. The proton-exchanged PHI frameworks exhibit high adsorption affinity for CO2 and exceptional performance for selective carbon capture.
Article
Chemistry, Applied
Yucong Zu, Jiawen Li, Xilin Li, Tongyi Zhao, Hao Ren, Fuxing Sun
Summary: Porous organic frameworks composed of organic building blocks have attracted attention for their tunable porosity, lightweight, and hydrolytic stability. Three new porous aromatic frameworks based on the [4 + 3] design strategy have been synthesized. These frameworks have high surface areas and exhibit excellent CO2 adsorption performance, making them promising candidates for CO2 capture.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Kai Qu, Jipeng Xu, Liheng Dai, Yixing Wang, Hongyan Cao, Dezhu Zhang, Yulin Wu, Weiyi Xu, Kang Huang, Cheng Lian, Xuhong Guo, Wanqin Jin, Zhi Xu
Summary: In this study, a crystal-rearrangement strategy induced by electrostatic attraction was used to design a POC membrane with heterostructure. The rearranged crystal layer, which was uniform and defect-free, displayed excellent CO2 separation performance and stability.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Jocasta Avila, L. Fernando Lepre, Catherine C. Santini, Martin Tiano, Sandrine Denis-Quanquin, Kai Chung Szeto, Agilio A. H. Padua, Margarida Costa Gomes
Summary: Porous ionic liquids based on ZIF-8 and phosphonium salts show increased carbon dioxide absorption capacity at low pressures. By combining MOFs with ionic liquids, the absorption of carbon dioxide can be greatly enhanced, leading to the development of high-performance liquid materials for effective low pressure carbon capture.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Long Zheng, Qian Song, Peng Tan, Sheng-Tao Wang, Xiao-Qin Liu, Lin-Bing Sun
Summary: A facile strategy is developed to introduce photoresponsive metal-organic polyhedra (PMOP) into covalent organic frameworks (COFs) as adsorbents with photoresponsive sites. The obtained photoresponsive host-guest composite (PHGC) adsorbents exhibit photomodulated adsorption capacity on propylene with a change of up to 43.3% and stability during multiple cycles.
Article
Materials Science, Multidisciplinary
Santosh Kumar, Atikur Hassan, Neeladri Das, Joonseok Koh
Summary: The increasing levels of CO2 in the atmosphere have led to serious problems. In this study, nano architectonics porous organic polymers (NPOPs) were synthesized by a catalyst-free coupling reaction for CO2 capture. The NPOPs showed thermal stability and a large surface area, indicating potential application in carbon capture and storage technology.
Article
Chemistry, Inorganic & Nuclear
Jian-Hua Qin, Zhi Xiao, Peng Xu, Zhi-Hua Li, Xiaoyan Lu, Xiao-Gang Yang, Weiwei Lu, Lu-Fang Ma, Dong-Sheng Li
Summary: In this study, a gas-phase photocatalytic CO2 reduction to CH4 using a anionic porous Zn-metalated porphyrin metal-organic framework (MOF) induced by an ionic liquid was presented. The MOF catalyst exhibited strong CO2 affinity and a favorable conduction band position, enabling high selectivity (around 70%) for CO2 to CH4 conversion in H2O vapor.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Hong-Kai Li, Hai-Lin Ye, Xiao-Xue Zhao, Xiao-Long Sun, Qian-Qian Zhu, Zhang-Ye Han, Rongrong Yuan, Hongming He
Summary: This study successfully developed an ultra-sensitive electrochemical aptasensor for detecting trace chloramphenicol by synthesizing PCN-222/GO composite, demonstrating great performance and broad application prospects.
CHINESE CHEMICAL LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Zhang-Ye Han, Hong-Kai Li, Qian-Qian Zhu, Rongrong Yuan, Hongming He
Summary: A novel POF was prepared via Friedel-Crafts reaction, in which silver nanoparticles were embedded to generate an Ag@POF composite for fabricating an intriguing electrochemical aptasensor. The biosensor showed excellent electrochemical detection behavior, with ultra-sensitiveness, high selectivity, remarkable stability, good repeatability, and simple operability, even in various real samples, with a limit of detection of 0.191 pg/mL in a wide concentration range.
CHINESE CHEMICAL LETTERS
(2021)
Article
Chemistry, Analytical
Han-Wen Zhang, Qian-Qian Zhu, Rongrong Yuan, Hongming He
Summary: The UiO-66-NH2@COF composite, constructed through a covalent linking approach, significantly enhances the electrochemical detection performance, showing promising applications in the field.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Rongrong Yuan, Hongxu Chen, Qian-Qian Zhu, Hongming He
Summary: In this study, a two-dimensional porous metal-organic framework was successfully prepared by solvothermal method, demonstrating excellent selectivity for CO2 adsorption with recyclability and different sorption abilities for benzene, toluene, and xylene.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Nanoscience & Nanotechnology
Han-Wen Zhang, Hong-Kai Li, Zhang-Ye Han, Rongrong Yuan, Hongming He
Summary: In this study, C-60@UiO-66-NH2 nanocomposites were used as materials to modify electrodes and fix aptamers, resulting in the development of a rapid and sensitive electrochemical aptasensor for the detection of tobramycin. This research is of great significance in the synthesis of functional fullerene@metal-organic matrix hybrid materials for electrochemical biosensing applications.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Rongrong Yuan, Zhuojun Yan, Hongming He
Summary: Trapping fullerenes in covalent organic frameworks is crucial for obtaining functional composites due to their remarkable physicochemical properties. Utilizing a mesoporous COF as a scaffold for encapsulating electroactive C-60 results in a composite with high surface area, stability, electroactivity, and large conjugated structure. The C-60@COF-modified electrode shows high load capacity and can be used for an electrochemical impedimetric aptasensor with extremely low limit of detection for tobramycin.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Hongming He, Qian-Qian Zhu, Ying Yan, Han-Wen Zhang, Zhang-Ye Han, Hongming Sun, Jing Chen, Cheng-Peng Li, Zhihong Zhang, Miao Du
Summary: The researchers have successfully designed a high-efficient electrocatalyst for nitrogen reduction reaction (NRR) that combines metal-organic frameworks (MOF) with Au nanoparticles (NPs), achieving high NH3 yield and Faradaic efficiency in ambient conditions and water medium.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Analytical
Hong-Kai Li, Ya-Xuan An, En-Hui Zhang, Sheng-Nan Zhou, Mo-Xuan Li, Zi-Juan Li, Xin Li, Rongrong Yuan, Weijie Zhang, Hongming He
Summary: The development of covalent organic framework nanosheet (COF NS) is an important research field due to its high permeability, ordered structure, high utilization of functional site, favourable dispersability, and large aspect ratio. In this study, Tp-Bpy COF NS was fabricated and used as a functional material for constructing an electrochemical aptasensor, showing enhanced biosensing performance for tobramycin detection.
ANALYTICA CHIMICA ACTA
(2022)
Article
Chemistry, Physical
Hongming He, Hong-Kai Li, Qian-Qian Zhu, Cheng-Peng Li, Zhihong Zhang, Miao Du
Summary: This study explores a molecular-level post-modification strategy to enhance the performance of electrocatalytic N-2 fixation by introducing alkyl chains of varying lengths in a metal-organic framework. The best results achieved were a Faradaic efficiency of 70.7% and a NO3- yield of 110.9 mu g h(-1) mg(cat).(-1).
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Review
Chemistry, Inorganic & Nuclear
Hongming He, Hao-Ming Wen, Hong-Kai Li, Han-Wen Zhang
Summary: This article provides a comprehensive overview of metal-organic frameworks (MOFs) and their derivatives as catalysts for the electrocatalytic nitrogen reduction reaction (NRR) to ammonia (NH3). The unique advantages and challenges of MOFs in the field of nitrogen fixation to ammonia are discussed.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Multidisciplinary
Hongming He, Hao-Ming Wen, Hong-Kai Li, Ping Li, Jiajun Wang, Yijie Yang, Cheng-Peng Li, Zhihong Zhang, Miao Du
Summary: 2D ferric covalent organic framework/MXene nanosheets with controllable hydrophobic behaviors were prepared via a multiple-in-one synthetic strategy. The boosted hydrophobicity of COF-Fe/MXene effectively inhibits the competitive hydrogen evolution reaction and enhances nitrogen reduction reactions.
Article
Chemistry, Analytical
Rongrong Yuan, Zhonghao Fu, Yujie He, Yanxia Deng, Jie Xi, Xiaoxiao Xing, Hongming He
Summary: Covalent organic framework (COF) nanospheres with controlled size of -500 and -1100 nm were successfully synthesized by adjusting the amount of HOAc in the reaction system. The resulting COFs exhibited a large aromatic skeleton, high stability, abundant pores, and uniform morphology. These COF-based advantages were utilized to immobilize aptamers for fabricating targeted electrochemical aptasensors. The sensing performance of the COF-based aptasensors was evaluated using oxytetracycline (OTC) as an analytical model, and it was found that the smaller COF (-500 nm) was more sensitive than the larger COF (-1100 nm). Furthermore, the COF (-500 nm)-based aptasensor demonstrated a detection limit of 7.4 fg mL-1 using the impedance signal, and showed excellent reproducibility, stability, specificity, and usability in real samples.
Article
Chemistry, Inorganic & Nuclear
Rongrong Yuan, Hongxu Chen, Jiawei Liu, Ruyu Li, Hongming He
Summary: In this study, a CNT@UiO-66 composite was prepared by assembling the microporous Zr-MOF UiO-66 with carbon nanotubes (CNTs). The composite exhibited high surface area, excellent stability, good electrical conductivity, and abundant Zr(iv) sites, making it highly suitable for fabricating high-performance electrochemical aptasensors. The fabricated sensor based on CNT@UiO-66 showed fine stability, excellent selectivity, and reproducibility, and could quantitatively detect the concentration of oxytetracycline (OTC) in real samples.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Rongrong Yuan, Yujie He, Bo Tang, Hongming He
Summary: Uniform spherical covalent organic frameworks (COFs) were synthesized at room temperature and used to immobilize horseradish peroxidase (HRP) with high loading capacity. The resulting HRP@COF displayed excellent reusability and enhanced tolerance to extreme conditions.
Article
Chemistry, Inorganic & Nuclear
Caleb J. Bennett, Helen E. A. Brand, Alexander K. L. Yuen, Maria K. Nicholas, Brendan J. Kennedy
Summary: The temperature dependence of the crystal structure of Potassium Hexaiodoplatinate(IV) between 80 and 500 K is studied. Different crystal structures are observed at different temperatures, including monoclinic, tetragonal, and cubic structures. Accurate determination of the structures of K2PtI6 is important for further theoretical and practical research.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Zhuo Zeng, Jiangfu Zheng, Xiaoming Li, Changzheng Fan, Rongying Zeng, Wenqing Tang
Summary: An efficient method for phosphate removal from wastewater is urgently needed due to the environmental issue caused by excessive phosphorus. In this study, calcium aluminum layered double hydroxides (CaAl-LDHs) and six amino acid intercalated calcium aluminum layered double hydroxides (CaAl-amino acid-LDHs) were prepared and compared for their phosphate adsorption performance. L-Aspartic acid intercalated calcium aluminum layered double hydroxides (CaAl-Asp-LDHs) exhibited the highest phosphate adsorption capacity and faster removal rate compared to CaAl-LDHs. The phosphate adsorption mechanism on CaAl-Asp-LDHs involved electrostatic attraction, hydrogen bonds, complexation, and ion exchange. This environmentally friendly material shows promising potential for efficient phosphate removal from aquatic environments.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rouzbeh Aghaei Hakkak, Thomas Schleid
Summary: The novel guanidinium hydro-closo-borates with [BnHn]2- (n = 10 and 12) anions were successfully synthesized via direct reaction. The crystal structures exhibit hydrogen bonding interactions and have the potential to facilitate H2 generation.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liqiang Ma, Pengpeng Wei, Jingfang Li, Liye Liang, Guangming Li
Summary: A novel catalyst, H4PVMo2W9O40@rht-MOF-1, was developed using a one-pot hydrothermal method. It exhibited high efficiency and reusability in esterification reactions.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Liudmila A. Gorelova, Valentiva A. Yukhno, Maria G. Krzhizhanovskaya, Oleg S. Vereshchagin
Summary: Two new Ga-Ge disordered feldspar-related compounds were successfully synthesized using melt crystallization methods. Their stability and thermal expansion properties were studied under high-temperature conditions. The results showed that both compounds are stable within the studied temperature range and exhibit anisotropic thermal expansion.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Seifeddine Bdey, Nesrine Boussadoune, Francois Allard, Jacques Huot, Gabriel Antonius, Noura Fakhar Bourguiba, Pedro Nunez
Summary: The structure of a novel arsenate compound Na3Al3(AsO4)4 has been determined using X-ray diffraction. The crystal exhibits a monoclinic space group with suitable pathways for Na+ ion migration. The accuracy of the structural model was confirmed using various validation tools and density functional theory calculations.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Amit Kumar Atri, Ujwal Manhas, Sumit Singh, Irfan Qadir, Shikha Sharma, Preteek Sharma, Devinder Singh
Summary: This study synthesizes new oxygen deficient triple layered Ruddlesden-Popper (RP) phases via sol-gel method and investigates the effects of Cr3+ doping on their structural, optical, magnetic, and photocatalytic properties. The experimental results demonstrate that Cr3+ doping alters the interactions and leads to excellent photocatalytic performance in some phases.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Dat Le Thanh, Amandine Guiet, Emmanuelle Suard, Romain Berthelot
Summary: In this study, FeNb11O29 powder samples were prepared using a microwave-assisted solid-state synthesis method for the first time. The samples obtained rapidly from submicrometric oxide precursors showed enhanced cycling performance, possibly due to the easier ionic diffusion occurring in the smaller particles.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Raimund Ziegler, Felix R. S. Purtscher, Thomas S. Hofer, Gunter Heymann, Hubert Huppertz
Summary: We have successfully synthesized a new tellurium borate crystal under high-pressure and high-temperature conditions. The crystal structure and theoretical calculations have been thoroughly discussed.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Subhendu Jana, Eric A. Gabilondo, Paul A. Maggard
Summary: This study reports the synthesis and characterization of two previously unknown multinary selenides, Ba8Hf2Se11(Se-2) and Ba9Hf3Se14(Se-2), which display unique structures and optoelectronic properties competitive with existing perovskite-type chalcogenides.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Fei Ruan, Chonggui Lei, Fenglong Zhang, Jinxiao Bao, Fen Zhou, Min Xie, Pengfei Xu, Jianquan Gao
Summary: Studying the diffusion properties of hydrogen is important for designing new proton conductors. In the past, the chemical diffusion coefficient of hydrogen in proton conductors was usually obtained through a manual calculation method, resulting in difficulty in controlling the calculation accuracy. To address this issue, a mathematical algorithm and C language computer program were developed to calculate the chemical diffusion coefficient based on Fick's second law and Romberg numerical integral. The algorithm showed high precision and powerful computing function, and has the potential to replace the manual calculation method in calculating the chemical diffusion coefficient for hydrogen in proton conductors.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Deepika Shanubhogue, Suraj Mangavati, Ashok Rao, Ru-Ting Tsao, Yung-Kang Kuo
Summary: In this study, the effect of Y doping at the Sn-site on the structural, electrical, and low-temperature thermoelectric properties of the Cu2SnSe3 system is investigated. Y-doped compounds Cu2Sn1-xYxSe3 show reduced electrical resistivity, enhanced power factor, and decreased thermal conductivity, resulting in higher ZT values.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Wei Hong, Min Qing, Xun He, Lei Wang, Yu Pu, Qiyu Li, Zhimin He, Qin Dong, Rong Li, Xinglong Gou
Summary: This study developed a simple method to prepare SnS2 nanosheets and assembled them with MXene to form SnS2/MXene. The composite material exhibited abundant active sites, superior electron/ion transfer kinetics, and a unique 2D interlayer structure, resulting in high specific capacity, outstanding rate capability, and excellent cycling stability, with potential applications in LIBs.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Heng-Yu Ruan, Xue-Qian Wu, Tian-Yu Zhang, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: Two isostructural metalorganic frameworks (MOFs), CTGU-36-Co and CTGU-36-Ni, were synthesized, and CTGU-36-Ni demonstrated high activity as a molecular electrocatalyst for the methanol oxidation reaction.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
Article
Chemistry, Inorganic & Nuclear
Rachid Fakhreddine, Ali Ouasri, Abderrahim Aatiq
Summary: This paper reports the synthesis, structure, and spectroscopic studies of three novel metal orthophosphate salts. The structures of these compounds were refined using X-ray powder diffraction data. The infrared and Raman analysis revealed their symmetries and the UV-visible investigation determined their optical properties.
JOURNAL OF SOLID STATE CHEMISTRY
(2024)
