Study on the eutectic formation and its correlation with the hydrogen storage properties of Mg98Ni2-xLax alloys

Transition metals and rare-earth elements have excellent catalytic effects on improving the de-/hydrogenation properties of Mg-based alloys. In this study, a small amount of La is used to substitute the Ni in Mg98Ni2 alloy, and some Mg(98N)i(2-x)La(x) (x = 0, 0.33, 0.67, and 1) alloys show the better overall hydrogen storage properties. The effects of La on the solidification and de-/hydrogenation behaviors of the alloys are revealed. The results indicate that different factors dominate the processes of hydrogen absorption and desorption. The Mg98Ni1.67La0.33 alloy absorb 7.04 wt % hydrogen at 300 degrees C, with the highest isothermal absorption rate, the Mg98Ni1.33La0.67 hydride show the highest isothermal desorption rates and the lowest peak desorption temperature of 327 degrees C. The La addition can increase the driving force of hydrogenation, thus the hydrogenation rates and capacities of the Mg-98-Ni1.67La0.33 and Mg98Ni1.33La0.67 alloys are improved. The formation of refined eutectic structures is a key factor that facilitates the desorption processes of the Mg(98N)i(2-x)La(x) hydrides with x = 0.67 and 1. High-density LaH3 nanophses are in-situ formed from the LaMgx (8.5 < x < 12) phase, which results in the improved de-/hydrogenation properties. The further La addition deteriorates the hydrogen storage properties of Mg98Ni2-xLax alloy. (c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Automated summary

Transition metals and rare-earth elements have excellent catalytic effects on improving the de-/hydrogenation properties of Mg-based alloys. The addition of La in Mg98Ni2 alloy improves the overall hydrogen storage properties. La enhances the driving force of hydrogenation, leading to improved hydrogenation rates and capacities. The formation of refined eutectic structures and high-density LaH3 nanophses contribute to the enhanced de-/hydrogenation properties.