4.7 Article

Exfoliated and plicated g-C3N4 nanosheets for efficient photocatalytic organic degradation and hydrogen evolution

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 46, Issue 39, Pages 20547-20559

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2021.03.174

Keywords

G-C3N4 nanosheets; Acidic etching; Photocatalysis

Funding

  1. National Natural Science Foundation of China [51808143, 51838005]
  2. Natural Science Foundation of Guangdong Province [2018A030313367]
  3. National Key R&D Program of China [2016YFA0203204]

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Exfoliated and plicated g-C3N4 nanosheets (CNsF) were prepared by thermal-chemical exfoliation and acidic etching, which disrupted weak van der Waals forces between layers to form monolayer or few-layer nanosheets, while creating disordered defects on the surface.
Exfoliated and plicated g-C3N4 nanosheets (CNsF) were prepared through a thermalchemical exfoliation in which the bulk g-C3N4 was obtained first under thermal exfoliation, and then was exposed to an acidic etching using hydrofluoric acid under hydrothermal condition. The acidic etching not only exfoliated g-C3N4 nanosheets by disrupting weak van der Waals forces between layers, which led to formation of a monolayer or a few layers of g-C3N4 nanosheets, but also made disordered defects on its surface and created

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