4.7 Article

Formation of Noncovalent Complexes between Complex Mixtures of Polycyclic Aromatic Hydrocarbons (Asphaltenes) and Substituted Aromatics Studied by Fluorescence Spectroscopy

Journal

ENERGY & FUELS
Volume 35, Issue 10, Pages 8742-8755

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.1c00555

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Funding

  1. Abu Dhabi National Oil Company (ADNOC) [RDProj.040-FA]
  2. Abu Dhabi Department of Education and Knowledge (ADEK)
  3. Khalifa University of Science and Technology [CIRA-2018-068]
  4. Research Computing Department of Khalifa University

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Quantification of molecular complexes between simple organic aromatic molecules is straightforward for pure components, but becomes challenging when dealing with complex mixtures of thousands of polycyclic aromatic hydrocarbons (PAHs). Fluorescence spectroscopy shows that electron-deficient aromatic additives interact strongly with PAHs, leading to the formation of molecular complexes. Computational modeling reveals that cohesive pi-pi stacking interactions between PAHs dominate as the number of PAH molecules in the cluster increases.
Quantification of the formation of molecular complexes between simple organic aromatic molecules is straightforward for pure components of definite composition; however, it becomes challenging when the interacting species are complex, intractable mixtures of thousands of polycyclic aromatic hydrocarbons (PAHs). Using the example of asphaltenes, a complex mixture of oil-derived PAHs, we demonstrate the potential of fluorescence spectroscopy for quantification of molecular processes that are at the core of their aggregation. It is found that small electron-deficient aromatic additives, especially surfactant-like additives with electron-withdrawing functional groups, interact strongly with the PAHs and lead to the formation of molecular complexes. Computational modeling revealed that as we increase the number of PAH molecules in the cluster, cohesive pi-pi stacking interactions between PAHs dominate in preference to adhesive hydrogen bonding or pi-pi stacking interactions between the PAHs and additives.

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