Article
Nanoscience & Nanotechnology
Junlong Da, Ying Li, Kai Zhang, Junyu Ren, Jianqun Wang, Xinpeng Liu, Xiaoyao Liu, Jiahui Zhang, Lixue Liu, Wenxuan Zhang, Shujian Zhang, Yuyao Guo, Bin Zhang, Han Jin
Summary: A novel microenvironment-stimuli-responsive drug delivery nanoplatform was developed for the treatment of maxillofacial infection. The nanoplatform showed excellent biocompatibility and had the ability to scavenge ROS and inhibit inflammatory response, promoting tissue repair.
INTERNATIONAL JOURNAL OF NANOMEDICINE
(2022)
Review
Environmental Sciences
Fatemeh Nemati, Maryam Rezaie, Hadi Tabesh, Kamel Eid, Guobao Xu, Mohammad Reza Ganjali, Morteza Hosseini, Ceren Karaman, Nevin Erk, Pau-Loke Show, Najmeh Zare, Hassan Karimi-Maleh
Summary: Graphene-based nanomaterials have shown great potential in various applications due to their remarkable properties. Functionalized graphene nanocomposites have advantages in increasing surface area and porosity, improving adsorption capacities, reducing adsorption energy barrier, and preventing agglomeration. Combining cerium structures with graphene networks has been widely investigated to enhance the properties of the composite. This research reviews the recent developments in cerium functionalized graphene derivatives and their industrial applications, providing comprehensive information on these nanonetworks. The applications of functionalized graphene derivatives are successfully summarized. This systematic review study has the potential to pave the way for scientific research in material science and various applications.
ENVIRONMENTAL RESEARCH
(2022)
Article
Chemistry, Applied
Weizheng Wang, Yaoqi Yin, Sundaram Gunasekaran
Summary: We developed a system using two-dimensional MXene material (FL-Ti3C2Tx) to simultaneously degrade tetracycline in food matrices. By catalyzing the reaction between hydrogen peroxide (H2O2) and 3, 3', 5, 5’-tetramethylbenzidine (TMB), FL-Ti3C2Tx can turn the H2O2/TMB system bluish-green. However, the bluish-green color does not appear in the presence of tetracycline. We developed a colorimetric assay to detect tetracycline with a limit of detection of 615.38 nM and proposed two degradation pathways, enabling a highly sensitive colorimetric bioassay.
Article
Chemistry, Physical
Jinlin Hao, Yuankun Ning, Yushuang Hou, Shuhui Ma, Cuncai Lin, Jiawei Zhao, Chao Li, Xin Sui
Summary: Ion-selective membranes play a crucial role in osmotic energy conversion, and nanofluid channels based on two-dimensional materials have shown great potential for efficient energy harvesting. In this study, a cation-selective polydopamine-coated graphene oxide composite membrane with a sandwich structure was successfully prepared, resulting in significantly improved surface charge density and high power density under river water and seawater. This innovative membrane design exhibits both high cation selectivity and ionic conductivity, offering a promising strategy for high-performance osmotic energy conversion.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Engineering, Environmental
Yizhong Shen, Xiang Gao, Yiyin Zhang, Huanhuan Chen, Yingwang Ye, Yongning Wu
Summary: Development of a simple and efficient dual-mode analytical technique with cross reference correction feature is important for accurate detection of target pollutants in the environment. The study describes the synthesis of a Fe-doped polydopamine-based nanozyme and the development of a dual-recognition strategy-driven fluorescence-colorimetric dual-mode detection platform for L. monocytogenes. The platform successfully detected L. monocytogenes in real environmental samples, demonstrating the potential of dual-recognition strategy for efficient and reliable analytical platforms.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Pornsuda Maraming, Nang Noon Shean Aye, Patcharee Boonsiri, Sakda Daduang, Onanong Buhome, Jureerut Daduang
Summary: Polydopamine nanoparticles (PDA-NPs)-functionalized electrochemical aptasensor was developed for the rapid, sensitive, and cost-effective detection of glycated albumin (GA). The aptasensor showed a broad linearity for GA detection in a clinically relevant range, with low detection limit, good reproducibility, and practicality. Furthermore, the aptasensor demonstrated high selectivity towards GA and potential clinical application in serum samples.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Analytical
Shu-Yu Lin, Chia-Yu Lin
Summary: This study presents a high specificity and electrocatalytic activity nanozyme based on carbon nanotube/2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) nanocomposite for the point-of-care diagnosis of microalbuminuria in urine. The modified electrode exhibits promising sensing characteristics without the need for sample pretreatment or additional label probes.
ANALYTICA CHIMICA ACTA
(2022)
Article
Materials Science, Multidisciplinary
Xiaobing Li, Zihui Cheng, Pan Chen, Lijuan Gao, Zixiang Wang, Jianfeng Chen
Summary: Graphene is an attractive candidate material for lubrication oil and lubricant additives due to its high thermal conductivity and impermeability. A study successfully prepared Ni/polydopamine-functionalized graphene composites and found that they exhibited good anti-wear and anti-friction properties.
DIAMOND AND RELATED MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Abedalkader Alkhouzaam, Hazim Qiblawey, Majeda Khraisheh
Summary: The high-degree functionalization of graphene oxide nanoparticles using polydopamine produced highly aminated GO-PDA NPs, with extensive spectral and structural analysis confirming their potential use as nanofillers in membrane separation. The GO-PDA NPs exhibited improved dispersibility in solvents and excellent hydrophilic properties, making them versatile for various applications.
Article
Chemistry, Analytical
Trung Hieu Vu, Phuong Thy Nguyen, Moon Il Kim
Summary: Surface engineering of nanozymes can enhance their catalytic activity and stability. Polydopamine-coated Co3O4 nanoparticles were synthesized and exhibited catalase-like activity and improved stability. The presence of sulfide ions significantly inhibited the activity of these nanoparticles, allowing for sensitive detection of sulfide ions based on their reduced catalytic activity.
Article
Chemistry, Multidisciplinary
Jini Varghese
Summary: Porous nanocomposites containing CuS-ZnS nanospheres and graphene layers were synthesized via a simple method, demonstrating efficient photocatalytic performance over a wide pH range. The nanocomposites showed excellent dye degradation efficiency due to enhanced surface area, porosity, better UV light harvesting capacity, and fast electron-hole transfer.CuS-ZnS decorated graphene is a promising photocatalyst for the degradation of dye mixtures in industrial applications.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2021)
Article
Biochemical Research Methods
Yu Zheng, Chenlu Pu, Hongli Zhao, Qinying Gu, Tianyi Zhu, Minbo Lan
Summary: A novel hydrophilic two-dimensional composite material was used to selectively enrich glycopeptides from biological samples, showing potential application in protein post-translational modification research.
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES
(2022)
Article
Chemistry, Analytical
Fenglin Zhang, Lifang Fan, Zhiguang Liu, Yujie Han, Yujing Guo
Summary: A highly sensitive label-free electrochemical aptasensor has been developed for the detection of ovarian cancer biomarker CA125. The sensor utilizes nickel hexacyanoferrate nanocubes as the signal probe and polydopamine functionalized graphene as the substrate. The designed platform exhibits excellent sensitivity and low detection limit.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2022)
Article
Chemistry, Analytical
Ruke Wang, Tong Zhang, Wengan Zhang, Binjie Chen, Jing Liu, Gengjun Liu, Hong Zhou, Peiwen Zhao, Haiyan Wang, Bo Wang
Summary: An enhanced nanozyme was synthesized by functionalizing natural microperoxidase-11 (MP-11) on a hybrid graphene oxide-gold (GO-Au) material. The designed nanozyme showed enhanced catalysis activity and achieved robust and efficient colorimetric detection of cysteine based on specific binding reaction. These enhanced properties of the nanozyme demonstrate promising applications and provide a great opportunity for developing efficient sensing systems.
ANALYTICA CHIMICA ACTA
(2023)
Article
Optics
Yansong Li, Mengyu Du, Shuxuan He, Ruiduo Wang, Zaikun Zhang, Qiang Wang
Summary: A GO and PDA-GO functionalized TLPG based biosensor was developed for sensitive and label-free detection of human hemoglobin. The deposition of GO and PDA-GO on fiber surface provided binding sites to adsorb hemoglobin, and also changed the RI of the fiber surface. The biosensor exhibited high sensitivity and low detection limit, and could be reused in the presence of interference compounds.
Article
Chemistry, Multidisciplinary
Shivanee Borpatra Gohain, Purna Kanta Boruah, Manash Ranjan Das, Ashim Jyoti Thakur
Summary: The encapsulation of iron oxide-based nanoparticles with gold nanoparticles shows promise for catalysis, providing a solution to the hydrophilic surface of iron species and enabling easy separation of colloidal gold nanoparticles. The resulting Fe3O4/Au NPs-rGO structure has been successfully used for synthesizing isatins, potential precursors of SARS-CoV-2 protease inhibitors, and uracil-based spirooxindoles, potential precursors of anti-cancer compounds, under mild reaction conditions with high yields.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Physical
Tariq Altalhi, Amine Mezni, Mohamed M. Ibrahim, Moamen S. Refat, Adil A. Gobouri, Ayham M. Safklou, Adel M. Mousli, Mohamed S. Attia, Purna K. Boruah, Manash R. Das, Jacek Ryl, Rabah Boukherroub, Mohammed A. Amin
Summary: In this study, FA-TiO2 nanocomposites were prepared using fly ash waste and titanium oxide. The nanocomposites exhibited considerable electrocatalytic activity for the hydrogen evolution reaction (HER), and their performance was significantly enhanced through cathodic activation. The activated FA-TiO2 showed comparable performance to commercial Pt/C catalysts for HER.
Article
Chemistry, Physical
Manashi Sarmah, Debasish Sarmah, Anindita Dewan, Porag Bora, Purna K. Boruah, Manash R. Das, Pankaj Bharali, Utpal Bora
Summary: The Cu2O/Cu nanocatalyst was synthesized via a simple method using papaya peel extract, and it exhibited efficient catalytic activity in Pd-free Sonogashira and Chan-Lam cross-coupling reactions. Characterization techniques such as XRD and XPS confirmed the structure and formation of the catalyst.
Article
Chemistry, Multidisciplinary
Debika Gogoi, Raghavendra Korde, Virendra Singh Chauhan, Manoj Kumar Patra, Debmalya Roy, Manash R. Das, Narendra Nath Ghosh
Summary: The demand for efficient microwave-absorbing materials is increasing with the advancement of information technology and the widespread use of electromagnetic devices. This study reports the development of a nanocomposite material, consisting of CoFe2O4 nanoparticles grown within the porous structure of Al2O3 and immobilized on graphene sheets. The nanocomposite exhibited excellent microwave-absorption properties in the X-band region, making it a potential candidate for applications in stealth technology.
Review
Chemistry, Physical
Manash R. Das, Najrul Hussain, Ritupana Duarah, Nidhi Sharma, Priyakhee Sarmah, Ashutosh Thakur, Prantika Bhattacharjee, Utpal Bora, Rabah Boukherroub
Summary: This review discusses the synthetic techniques used to prepare metal nanoparticles on various 2D materials, with special focus on graphene and other 2D analogues such as g-C3N4, h-BN, MoS2, WS2 etc. The review also outlines the applications of metal nanoparticles-2D composite materials in catalytic coupling reactions and explores the effect of size and morphology on their catalytic performance.
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING
(2022)
Article
Chemistry, Multidisciplinary
Ankur Kumar, Javed Muhommad, Siddhartha K. Purkayastha, Ankur K. Guha, Manash R. Das, Sasanka Deka
Summary: A newly developed transition metal boron amorphous alloy electrocatalyst can improve the efficiency of electrochemical water splitting by reducing the energy consumption of the oxygen evolution reaction (OER).
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Nanoscience & Nanotechnology
Purna K. Boruah, Priyakshree Borthakur, Gayatri Neog, Benjamin Le Ouay, Nazim Uddin Afzal, Prasenjit Manna, Manash R. Das
Summary: This article describes the synthesis of porous 3D nitrogen-doped crumpled graphene nanoparticles (CGNPs) and their use as a platform for the sensitive detection of dopamine (DA) in complex biological media such as blood serum. The CGNPs were prepared by doping graphene oxide (GO) using ammonium hydroxide in a hydrothermal treatment. The system selectively detected DA with a limit of detection of 1.15 μM and a linearity range of 1 to 20 μM, and it showed good selectivity in the presence of various interfering species and in human blood serum.
ACS APPLIED NANO MATERIALS
(2023)
Article
Engineering, Electrical & Electronic
Mantu K. K. Hudait, Steven W. W. Johnston, Manash R. R. Das, Sengunthar Karthikeyan, Partha P. P. Sahu, Jagat Das, Jing Zhao, Robert J. J. Bodnar, Rutwik Joshi
Summary: In this study, crystallographically oriented epitaxial Ge/AlAs heterostructures were grown and passivated with ALD Al2O3 dielectrics. The microwave photoconductive decay (mu-PCD) technique was used to evaluate carrier lifetimes at room temperature. It was found that the carrier lifetime was strongly dependent on surface orientation and surface passivation, and passivated (100)Ge and (110)Ge surfaces showed significant increase in carrier lifetime, providing a path for the development of nanoscale transistors.
ACS APPLIED ELECTRONIC MATERIALS
(2023)
Article
Engineering, Environmental
Purna K. Boruah, Gitashree Darabdhara, Priyakshree Borthakur, Benjamin Le Ouay, Manash R. Das
Summary: This article presents a novel composite material consisting of Fe3O4 quantum dots immobilized on polydopamine-functionalized graphene, which acts as a powerful platform for detecting Cr(VI) ions and reducing them to non-toxic ions.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Ankur Kumar, Siddhartha K. Purkayastha, Ankur K. Guha, Manash R. Das, Sasanka Deka
Summary: A nanoarchitecture composed of NiCu alloy on Co nanosheets was developed and used as an efficient electrocatalyst for HER, OER, and overall water splitting. The optimized catalyst displayed excellent activities with low overpotentials, Tafel slopes, and high mass activities, turnover frequencies, and exchange current densities. It achieved a current density of >1000 mA cm(-1) at low voltage in the electrolyzer, surpassing the commercial IrO2||Pt/C catalyst. The proposed mechanisms were supported by experimental and computational studies, revealing the involvement of nanoporous Cu-rich alloy and (100) surface exposed Co nanosheets as active sites for HER and OER, respectively.
Article
Chemistry, Multidisciplinary
Darshana Anand Upar, Debika Gogoi, Manash R. Das, Bhanudas Naik, Narendra Nath Ghosh
Summary: Water pollution caused by textile dyes and antibiotics is a global issue that requires the development of efficient photocatalysts. This study presents a hierarchical photocatalyst composed of graphitic carbon nitride and exfoliated BiFeO3 nanoflakes, which demonstrated excellent photocatalytic activity for the degradation of various dyes and antibiotics under simulated solar light irradiation.
Article
Chemistry, Physical
Debika Gogoi, Rajeshvari Samatbhai Karmur, Manash R. Das, Narendra Nath Ghosh
Summary: In this study, multifunctional Cu2S-MXene hybrid heterostructures were synthesized and applied in supercapacitors and oxygen evolution reaction. The materials showed superior charge storage properties, device performance, and catalytic activity, indicating their potential for various applications.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Nanoscience & Nanotechnology
Lakshya Kumar, Bindu Antil, Ankur Kumar, Manash R. Das, Omar Lopez-Estrada, Samira Siahrostami, Sasanka Deka
Summary: In this study, novel nonprecious transition-metal phosphide nanoparticles were developed as efficient electrocatalysts for hydrogen and oxygen evolution reaction and overall water splitting. The surface chemistry of these nanoparticles was explored to understand the reaction mechanism. The optimized catalyst exhibited attractive catalytic activities and durability.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Debika Gogoi, Rajeshvari Samatbhai Karmur, Manash R. Das, Narendra Nath Ghosh
Summary: In this study, novel Cu2S-MXene heterostructures were synthesized and demonstrated superior electrochemical properties for supercapacitors and oxygen evolution reaction. A flexible all-solid-state supercapacitor device constructed using 50Cu(2)S-50MXene exhibited high energy density and long cycle life.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Multidisciplinary
Dipika Konwar, Rakhee Saikia, Risha Kalita, Manash R. Das, Utpal Bora
Summary: A biogenically synthesized Pd nanoparticle-decorated graphitic carbon nitride oxide sheet was developed for efficient Suzuki-Miyaura cross-coupling reactions. The catalyst not only functioned as a catalyst, but also served as a base, reducing the need for exogenous base. Furthermore, the catalyst exhibited good activity and could be easily recovered and reused.
NEW JOURNAL OF CHEMISTRY
(2023)