4.7 Article

Polydopamine functionalized graphene sheets decorated with magnetic metal oxide nanoparticles as efficient nanozyme for the detection and degradation of harmful triazine pesticides

Journal

CHEMOSPHERE
Volume 268, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2020.129328

Keywords

Polydopamine functionalized graphene; Nanozyme; Detection; Photocatalyst; Degradation

Funding

  1. Council of Scientific and Industrial Research (CSIR) [MLP 1013, OLP-2023]

Ask authors/readers for more resources

In this study, graphene was functionalized using dopamine and decorated with magnetic Fe3O4 nanoparticles to create an artificial nanozyme. The resulting FDGs nanozymes exhibit dual characteristics towards detection and degradation of simazine pesticide. The nanozyme also shows excellent photocatalytic activity for the degradation of simazine under direct natural sunlight irradiation.
A facile and an eco-friendly reduction and functionalization of reduced graphene oxide (rGO) sheets is carried out using dopamine and decorated with magnetic Fe3O4 nanoparticles with an average size of 12 nm by a simple co-precipitation method which is established as an artificial nanozyme. Here, functionalization of graphene using dopamine has introduced several advantages and insights into this study. The Fe(3)O(4 )nanoparticles decorated functionalized rGO sheets (FDGs) nanozymes are characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HRTEM), Raman spectroscopy, atomic force microscopy (AFM), thermogravimetric (TGA) and vibrating sample magnetometer (VSM) analysis. FDGs nanozymes exhibits dual characteristics towards detection and degradation of harmful simazine pesticide. The hydrogen bonding interactions between pesticide molecules and 3,3',5,5'-tetramethylbenzidine (TMB) causes inhibition of the catalytic activity of the FDGs towards oxidation of TMB molecule. Based on that, the presence of simazine pesticide in an aqueous medium can be easily determined and a certain value (2.24 mu M) of detection limit was achieved. The photocatalytic degradation of simazine is also executed and excellent photocatalytic activity was observed under irradiation of direct natural sunlight. The FDGs nanozyme is also reusable up to several times with insignificant loss in its catalytic activity towards simazine degradation. (C) 2020 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Gold-coated iron oxide core-shell nanostructures for the oxidation of indoles and the synthesis of uracil-derived spirooxindoles

Shivanee Borpatra Gohain, Purna Kanta Boruah, Manash Ranjan Das, Ashim Jyoti Thakur

Summary: The encapsulation of iron oxide-based nanoparticles with gold nanoparticles shows promise for catalysis, providing a solution to the hydrophilic surface of iron species and enabling easy separation of colloidal gold nanoparticles. The resulting Fe3O4/Au NPs-rGO structure has been successfully used for synthesizing isatins, potential precursors of SARS-CoV-2 protease inhibitors, and uracil-based spirooxindoles, potential precursors of anti-cancer compounds, under mild reaction conditions with high yields.

NEW JOURNAL OF CHEMISTRY (2022)

Article Chemistry, Physical

Cathodic Activation of Titania-Fly Ash Cenospheres for Efficient Electrochemical Hydrogen Production: A Proposed Solution to Treat Fly Ash Waste

Tariq Altalhi, Amine Mezni, Mohamed M. Ibrahim, Moamen S. Refat, Adil A. Gobouri, Ayham M. Safklou, Adel M. Mousli, Mohamed S. Attia, Purna K. Boruah, Manash R. Das, Jacek Ryl, Rabah Boukherroub, Mohammed A. Amin

Summary: In this study, FA-TiO2 nanocomposites were prepared using fly ash waste and titanium oxide. The nanocomposites exhibited considerable electrocatalytic activity for the hydrogen evolution reaction (HER), and their performance was significantly enhanced through cathodic activation. The activated FA-TiO2 showed comparable performance to commercial Pt/C catalysts for HER.

CATALYSTS (2022)

Article Chemistry, Physical

Dual Responsive Sustainable Cu2O/Cu Nanocatalyst for Sonogashira and Chan-Lam Cross-Coupling Reactions

Manashi Sarmah, Debasish Sarmah, Anindita Dewan, Porag Bora, Purna K. Boruah, Manash R. Das, Pankaj Bharali, Utpal Bora

Summary: The Cu2O/Cu nanocatalyst was synthesized via a simple method using papaya peel extract, and it exhibited efficient catalytic activity in Pd-free Sonogashira and Chan-Lam cross-coupling reactions. Characterization techniques such as XRD and XPS confirmed the structure and formation of the catalyst.

CATALYSIS LETTERS (2023)

Article Chemistry, Multidisciplinary

CoFe2O4 Nanoparticles Grown within Porous Al2O3 and Immobilized on Graphene Nanosheets: A Hierarchical Nanocomposite for Broadband Microwave Absorption

Debika Gogoi, Raghavendra Korde, Virendra Singh Chauhan, Manoj Kumar Patra, Debmalya Roy, Manash R. Das, Narendra Nath Ghosh

Summary: The demand for efficient microwave-absorbing materials is increasing with the advancement of information technology and the widespread use of electromagnetic devices. This study reports the development of a nanocomposite material, consisting of CoFe2O4 nanoparticles grown within the porous structure of Al2O3 and immobilized on graphene sheets. The nanocomposite exhibited excellent microwave-absorption properties in the X-band region, making it a potential candidate for applications in stealth technology.

ACS OMEGA (2022)

Review Chemistry, Physical

Metal nanoparticles decorated two-dimensional nanosheets as heterogeneous catalysts for coupling reactions

Manash R. Das, Najrul Hussain, Ritupana Duarah, Nidhi Sharma, Priyakhee Sarmah, Ashutosh Thakur, Prantika Bhattacharjee, Utpal Bora, Rabah Boukherroub

Summary: This review discusses the synthetic techniques used to prepare metal nanoparticles on various 2D materials, with special focus on graphene and other 2D analogues such as g-C3N4, h-BN, MoS2, WS2 etc. The review also outlines the applications of metal nanoparticles-2D composite materials in catalytic coupling reactions and explores the effect of size and morphology on their catalytic performance.

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING (2022)

Article Chemistry, Multidisciplinary

Robust and Promising Electrocatalytic Oxygen Evolution Reaction by Activated Cu-Co-B Amorphous Nanosheets

Ankur Kumar, Javed Muhommad, Siddhartha K. Purkayastha, Ankur K. Guha, Manash R. Das, Sasanka Deka

Summary: A newly developed transition metal boron amorphous alloy electrocatalyst can improve the efficiency of electrochemical water splitting by reducing the energy consumption of the oxygen evolution reaction (OER).

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

Article Nanoscience & Nanotechnology

Porous Nitrogen-Doped Crumpled Graphene Nanoparticles: A Metal-Free Nanozyme for Selective Detection of Dopamine in Aqueous Medium and Human Serum

Purna K. Boruah, Priyakshree Borthakur, Gayatri Neog, Benjamin Le Ouay, Nazim Uddin Afzal, Prasenjit Manna, Manash R. Das

Summary: This article describes the synthesis of porous 3D nitrogen-doped crumpled graphene nanoparticles (CGNPs) and their use as a platform for the sensitive detection of dopamine (DA) in complex biological media such as blood serum. The CGNPs were prepared by doping graphene oxide (GO) using ammonium hydroxide in a hydrothermal treatment. The system selectively detected DA with a limit of detection of 1.15 μM and a linearity range of 1 to 20 μM, and it showed good selectivity in the presence of various interfering species and in human blood serum.

ACS APPLIED NANO MATERIALS (2023)

Article Engineering, Electrical & Electronic

Carrier Recombination Dynamics of Surface-Passivated Epitaxial (100)Ge, (110)Ge, and (111)Ge Layers by Atomic Layer Deposited Al2O3

Mantu K. K. Hudait, Steven W. W. Johnston, Manash R. R. Das, Sengunthar Karthikeyan, Partha P. P. Sahu, Jagat Das, Jing Zhao, Robert J. J. Bodnar, Rutwik Joshi

Summary: In this study, crystallographically oriented epitaxial Ge/AlAs heterostructures were grown and passivated with ALD Al2O3 dielectrics. The microwave photoconductive decay (mu-PCD) technique was used to evaluate carrier lifetimes at room temperature. It was found that the carrier lifetime was strongly dependent on surface orientation and surface passivation, and passivated (100)Ge and (110)Ge surfaces showed significant increase in carrier lifetime, providing a path for the development of nanoscale transistors.

ACS APPLIED ELECTRONIC MATERIALS (2023)

Article Engineering, Environmental

Fe3O4 quantum dots anchored on functionalized graphene: A multimodal platform for sensing and remediation of Cr(VI)

Purna K. Boruah, Gitashree Darabdhara, Priyakshree Borthakur, Benjamin Le Ouay, Manash R. Das

Summary: This article presents a novel composite material consisting of Fe3O4 quantum dots immobilized on polydopamine-functionalized graphene, which acts as a powerful platform for detecting Cr(VI) ions and reducing them to non-toxic ions.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Physical

Designing Nanoarchitecture of NiCu Dealloyed Nanoparticles on Hierarchical Co Nanosheets for Alkaline Overall Water Splitting at Low Cell Voltage

Ankur Kumar, Siddhartha K. Purkayastha, Ankur K. Guha, Manash R. Das, Sasanka Deka

Summary: A nanoarchitecture composed of NiCu alloy on Co nanosheets was developed and used as an efficient electrocatalyst for HER, OER, and overall water splitting. The optimized catalyst displayed excellent activities with low overpotentials, Tafel slopes, and high mass activities, turnover frequencies, and exchange current densities. It achieved a current density of >1000 mA cm(-1) at low voltage in the electrolyzer, surpassing the commercial IrO2||Pt/C catalyst. The proposed mechanisms were supported by experimental and computational studies, revealing the involvement of nanoporous Cu-rich alloy and (100) surface exposed Co nanosheets as active sites for HER and OER, respectively.

ACS CATALYSIS (2023)

Article Chemistry, Multidisciplinary

Facile Synthesis of gC3N4-Exfoliated BiFeO3 Nanocomposite: A Versatile and Efficient S-Scheme Photocatalyst for the Degradation of Various Textile Dyes and Antibiotics in Water

Darshana Anand Upar, Debika Gogoi, Manash R. Das, Bhanudas Naik, Narendra Nath Ghosh

Summary: Water pollution caused by textile dyes and antibiotics is a global issue that requires the development of efficient photocatalysts. This study presents a hierarchical photocatalyst composed of graphitic carbon nitride and exfoliated BiFeO3 nanoflakes, which demonstrated excellent photocatalytic activity for the degradation of various dyes and antibiotics under simulated solar light irradiation.

ACS OMEGA (2023)

Article Chemistry, Physical

2D-Ti3C2Tx MXene-supported Cu2S nanoflakes for supercapacitors and electrocatalytic oxygen evolution reaction

Debika Gogoi, Rajeshvari Samatbhai Karmur, Manash R. Das, Narendra Nath Ghosh

Summary: In this study, multifunctional Cu2S-MXene hybrid heterostructures were synthesized and applied in supercapacitors and oxygen evolution reaction. The materials showed superior charge storage properties, device performance, and catalytic activity, indicating their potential for various applications.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Nanoscience & Nanotechnology

Experimental and Computational Insights into the Overall Water Splitting Reaction by the Fe-Co-Ni-P Electrocatalyst

Lakshya Kumar, Bindu Antil, Ankur Kumar, Manash R. Das, Omar Lopez-Estrada, Samira Siahrostami, Sasanka Deka

Summary: In this study, novel nonprecious transition-metal phosphide nanoparticles were developed as efficient electrocatalysts for hydrogen and oxygen evolution reaction and overall water splitting. The surface chemistry of these nanoparticles was explored to understand the reaction mechanism. The optimized catalyst exhibited attractive catalytic activities and durability.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Physical

2D-Ti3C2Tx MXene-supported Cu2S nanoflakes for supercapacitors and electrocatalytic oxygen evolution reaction

Debika Gogoi, Rajeshvari Samatbhai Karmur, Manash R. Das, Narendra Nath Ghosh

Summary: In this study, novel Cu2S-MXene heterostructures were synthesized and demonstrated superior electrochemical properties for supercapacitors and oxygen evolution reaction. A flexible all-solid-state supercapacitor device constructed using 50Cu(2)S-50MXene exhibited high energy density and long cycle life.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Multidisciplinary

Minimizing base stoichiometry in Pd(0)/g-C3N4O catalyzed Suzuki-Miyaura cross-coupling reaction

Dipika Konwar, Rakhee Saikia, Risha Kalita, Manash R. Das, Utpal Bora

Summary: A biogenically synthesized Pd nanoparticle-decorated graphitic carbon nitride oxide sheet was developed for efficient Suzuki-Miyaura cross-coupling reactions. The catalyst not only functioned as a catalyst, but also served as a base, reducing the need for exogenous base. Furthermore, the catalyst exhibited good activity and could be easily recovered and reused.

NEW JOURNAL OF CHEMISTRY (2023)

No Data Available