Article
Chemistry, Analytical
Lin Minyi, Xia Dehua
Summary: Advanced oxidation processes based on sulfate radicals are promising technologies for inactivating pathogenic microorganisms in water and wastewater due to their high oxidation potential, wide pH adaptability, and negligible formation of undesired byproducts.
ENVIRONMENTAL CHEMISTRY
(2022)
Review
Environmental Sciences
Huiling Xia, Chengwei Li, Guoying Yang, Zhiang Shi, Chenxi Jin, Wenzhi He, Jingcheng Xu, Guangming Li
Summary: This paper provides a detailed classification and comprehensive review of microwave-assisted advanced oxidation processes (MW-AOPs) in wastewater treatment. The latest applications of microwave in different advanced oxidation systems are discussed, along with the discussion of reaction parameters, performance, and operating costs of MW-AOPs. Recommendations for future research on MW-AOPs are also provided, highlighting the potential development and evolution of this technology.
Article
Environmental Sciences
Hannah Milh, Xingyue Yu, Deirdre Cabooter, Raf Dewil
Summary: In this study, the efficiency of UV-based sulfate radical advanced oxidation processes (SR-AOP) and UV-based advanced reduction processes (ARP) in degrading ciprofloxacin (CIP) in wastewater was investigated. It was found that the UV/PS process was more efficient than the UV/PMS process in SR-AOPs, while the UV/sulfite process was the most efficient among ARPs. The optimal process parameters and the contribution of different reactive species were determined for each process.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Engineering, Environmental
Jiayue Dong, Peizeng Yang, Jing Chen, Yuefei Ji, Junhe Lu
Summary: The removal and transformation of nitrophenolic byproducts in a simulated drinking water treatment train were examined. It was found that these byproducts can enter the treatment system and react with residual chlorine to form more hazardous compounds.
Review
Engineering, Environmental
Xin Lei, Yu Lei, Xinran Zhang, Xin Yang
Summary: This review focuses on the degradation kinetics and mechanisms of disinfection byproducts (DBPs) under UV and solar irradiation and in UV-based advanced oxidation processes (AOPs). The study highlights the differences in photodegradation rates of N-nitrosamines and halogenated DBPs, and the potential predictors of photodegradation rates under low pressure UV irradiation. Additionally, the review summarizes the reaction mechanisms under UV irradiation and in HO center dot-mediated oxidation, providing insights into the degradation pathways of various DBPs.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Review
Engineering, Environmental
Alena Kulist'akova
Summary: The majority of current wastewater treatment technologies are ineffective in removing pharmaceutical micropollutants, resulting in their discharge into surface water bodies and causing significant harm to fragile ecosystems. The European Commission has published an expansion of legislation for surface water that includes the monitoring and limitation of the discharge of nine pharmaceuticals. Photochemical advanced oxidation processes (AOPs) have shown promise in efficiently removing micropollutants and could potentially reduce the pharmaceutical burden in wastewater. However, there are challenges that limit their widespread use in treatment plants. This review fills the gap in summarizing and assessing the current trends in the utilization of photochemical AOPs for pharmaceutical micropollutant removal in wastewater treatment, representing the first attempt to address this topic.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Review
Engineering, Environmental
P. V. Nidheesh, Ashitha Gopinath, N. Ranjith, Apurva Praveen Akre, Vandana Sreedharan, M. Suresh Kumar
Summary: Biochar has gained extensive research attention in advanced oxidation processes due to its multifunctional role; pyrolysis is the most commonly used method for acquiring desired properties, and biochar can function as a catalyst, support material, and cathode material due to its high conductivity and porous structure; research focuses on activation mechanisms, ROS generation, sulfate radical mediated degradation, and future directions in the field.
CHEMICAL ENGINEERING JOURNAL
(2021)
Review
Engineering, Chemical
P. V. Nidheesh, G. Divyapriya, Fatima Ezzahra Titchou, Mohamed Hamdani
Summary: This article extensively discusses various aspects of sulfate radicals based advanced oxidation processes (SR-AOPs) in treating textile wastewaters, including activation processes, reactive molecules and radicals species, performance evaluations, comparisons with other AOPs, and studies on experimental scales.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Pinapala Chanikya, P. Nidheesh, D. Syam Babu, Ashitha Gopinath, M. Suresh Kumar
Summary: The comparative study of EAOP + EC and EC + EAOP processes for treating real dyeing wastewater shows that EAOP followed by EC is more effective, resulting in a COD reduction of 93.5% with lower energy consumption and less sludge generation.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Environmental
Xinyu Liu, Jianlong Wang
Summary: Ammonia nitrogen pollution is a global concern, causing eutrophication of aquatic ecosystems. Various AOPs have been studied for ammonium removal and selective oxidation to nitrogen gas. This review provides a comprehensive analysis of the reactive species, reaction mechanisms, and operational conditions of different AOPs for selective oxidation of ammonia.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Environmental Sciences
Qingkai Shi, Si Deng, Yuling Zheng, Yinlin Du, Ling Li, Suzhao Yang, Gaoxia Zhang, Li Du, Guangfu Wang, Min Cheng, Yang Liu
Summary: Sulfate radical-based advanced oxidation processes are important for degrading organic pollutants in water. Transition metal-modified biochar is widely used as a catalyst in these processes, providing excellent properties and synergistic effects.
ENVIRONMENTAL RESEARCH
(2022)
Review
Engineering, Environmental
Golnoosh Khajouei, Harry O. O. Finklea, Lian-Shin Lin
Summary: Advanced oxidation processes (AOPs), including UV/chlorine, have gained attention as alternatives to conventional water treatment technologies. UV/chlorine process offers multiple disinfection modes and maintains chlorine residuals, while also having advantages like higher radical production efficiency. This process has been applied to degrade a wide range of organic and inorganic compounds. This review evaluates the efficiency of UV/chlorine process and discusses strategies to tackle the formation of disinfection by-products (DBPs).
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Yawen Wu, Liushen Lu, Yan Zhang, Zhenbo Yuan, Lifeng Yang, Lijun Wang, Yijian Rao
Summary: A novel cercosporin/polymethylmethacrylate (CP/PMMA) photocatalyst was developed in this study, showing high efficiency in degrading broad-spectrum pharmaceuticals and shortening decontamination time under natural sunlight. Additionally, it demonstrated antibacterial activity against Staphylococcus aureus, providing new insights into the design of multifunctional photocatalysts for environmental remediation using natural products and macroporous resins.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Engineering, Environmental
Yu Lei, Yafei Yu, Xin Lei, Xi Liang, ShuangShuang Cheng, Gangfeng Ouyang, Xin Yang
Summary: Advanced oxidation processes (AOPs) are widely used for water and wastewater treatment. This study determined second order rate constants for reactions between probes and quenchers with various reactive species and chemical oxidants. Previously ill-quantified reactions were found to be favorable. The improved kinetic database and proposed criteria for probe and quencher selection and dosing will benefit future research in AOPs and other radical-involved reactions.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Engineering, Environmental
Lap-Cuong Hua, Ching Huang, Chihpin Huang
Summary: This study examines a novel hybrid oxidation-coagulation PMS/Fe(II) process for effective removal of algogenic organic matter (AOM)-derived disinfection byproduct (DBP) precursors. The results show that under neutral pH conditions, PMS/Fe(II) is able to significantly remove dissolved organic carbon (DOC) and AOM-fluorescent components, as well as effectively degrade AOM-derived DBPs. This research fills the knowledge gap in the study of PMS/Fe(II) and highlights its potential as an alternative for sustainable water treatment.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Kai Wang, Chen Han, Fuping Li, Yu Liu, Zongping Shao, Lihong Liu, Shaobin Wang, Shaomin Liu
Summary: A series of strontium cobaltite perovskite oxides with different dopants were designed and investigated for their catalytic activity in degrading aqueous organic pollutants. The study found that the crystalline structure and surface properties of the oxides are correlated with their catalytic activity, with the Co-O bond length being a key factor in peroxymonosulfate (PMS) activation. This study provides new insights for the design of efficient perovskite oxide catalysts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Environmental Sciences
Ziwei Wang, Yannan Tan, Xiaoguang Duan, Yongbing Xie, Haibo Jin, Xiaowei Liu, Lei Ma, Qiangyang Gu, Huangzhao Wei
Summary: When a membrane is used to treat dye wastewater, the dye molecules accumulate at the membrane surface over time, causing a decrease in membrane flux. Pretreating dye wastewater with layered double hydroxide (LDH) to degrade organic pollutants has been thoroughly investigated in this study. LDH activates peroxymonosulfate (PMS) to produce oxidative free radicals, enhancing the reaction rate. Singlet oxygen (O-1(2)), sulfate radicals (SO4 center dot-), and hydroxyl radicals (center dot OH) were identified as the reactive species. The CoFe-LDH/PMS system showed a high degradation efficiency for Acid Red 27 dye with strong resistance to inorganic ions and pH.
Article
Environmental Sciences
Ta Cong Khiem, Po-Hsin Mao, Young-Kwon Park, Xiaoguang Duan, Bui Xuan Thanh, Chechia Hu, Suresh Ghotekar, Yiu Fai Tsang, Kun-Yi Andrew Lin
Summary: In order to degrade AZRS, a highly oxidizing agent needs to be developed and Co3O4 nanoparticles with ordered pores need to be synthesized using a templating agent. This allows for the stable dispersion and activation of the oxidizing agent within the pores, improving the degradation efficiency.
Article
Energy & Fuels
Xinyuan Xu, Jinqiang Zhang, Hong Wu, Lei Shi, Jie Zhang, Kuan Ding, Shu Zhang, Shuaijun Wang, Shaobin Wang, Hongqi Sun
Summary: In this study, the concentration and position of sulfur vacancies in ultrathin ZnIn2S4 nanosheets were successfully controlled to optimize the photo-driven lignin model reforming process, leading to excellent selectivity for hydrogen and chemical monomers. The proton migration pathway was modulated through sulfur vacancy engineering, achieving high concentrations of sulfur vacancies in the bulk and on the surface of ZnIn2S4. This provides new mechanistic insights into biomass photoreforming and elucidates the structure/chemistry-catalysis correlation of ZnIn2S4 photocatalysts, which are crucial for photocatalyst design and solar fuel production.
Article
Chemistry, Physical
Di Wu, Menghan Chu, Yongsheng Xu, Xiaomei Liu, Xiaoguang Duan, Xiaobin Fan, Yang Li, Guoliang Zhang, Fengbao Zhang, Wenchao Peng
Summary: In this study, it was discovered that the presence of non-active ZnO crystals significantly accelerated the degradation of BPA in the PMS/Co3O4 system, with a 3.7-fold increase in degradation rate. Mechanistic investigation revealed that the ZnO particles generated negative electric microfields around them, which were closely related to the zeta potentials of ZnO and influenced by solution pH. COMSOL simulation showed that the electrostatic repulsion between ZnO and PMS facilitated the migration of HSO5 towards the active Co3O4 surface, leading to an increased concentration of HSO5 around the active Co3O4 particles and improved degradation performance. The particle size of ZnO also had a significant impact on the promoting effect through COMSOL simulation. Therefore, this study provides novel insights into the synergistic effect of electric microfields in enhancing heterogeneous Fenton-like reactions and offers a cost-effective strategy for enhanced persulfate catalysis.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
W. Han, D. Li, X. Hu, W. Qin, H. Sun, S. Wang, X. Duan
Summary: In this study, the efficiency of carbon quantum dots (CQDs) as photocatalysts is improved by fine-tuning the surface chemistry through selectively substituting surface carbonyl group (C=O) with phenylhydrazine (PH). The modified CQDs-PH show enhanced light absorption and separation of photogenerated electron-hole pairs, leading to boosted generation of reactive oxygen species (ROS) via peroxymonosulfate (PMS) activation. Theoretical calculations demonstrate spatial separation of electrons and holes on CQDs due to the spontaneous surface polarization induced by PH functionalization. This research provides a feasible approach to enhance the photocatalytic activity of CQDs for sustainable water decontamination.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Chemistry, Physical
Jinqiang Zhang, Xiaojie Tan, Lei Shi, Haijun Chen, Yazi Liu, Shuaijun Wang, Xiaoguang Duan, Mingbo Wu, Hongqi Sun, Shaobin Wang
Summary: Photocatalytic hydrogen production is achieved by epitaxial growth of a van der Waals homojunction on an intralayer homojunction of carbon nitride, which enables controlled charge flow. The tandem internal electric field (IEF) in the integrated hybrid, composed of a lateral IEF along the intralayer homojunction and a vertical IEF within the VDW homojunction, facilitates efficient charge separations and mobilities, as well as intensified hydrogen reduction. The hydrogen evolution rate is significantly improved compared to in-planar homojunction and g-C3N4 benchmark, demonstrating the effectiveness of this strategy for robust photocatalysis.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Physical
Ta Cong Khiem, Nguyen Nhat Huy, Eilhann Kwon, Xiaoguang Duan, Stanislaw Waclawek, Jorge Bedia, Yu-Chih Tsai, Afshin Ebrahimi, Farshid Ghanbari, Kun-Yi Andrew Lin
Summary: Designing defects-rich hollow heterostructure bimetal sulfides is an efficient strategy for accelerated monoper-sulfate (MPS) activation. The mono-step sulfidation method was used to develop sulfur vacancy (SV)-rich hollow oxygen-doped Co9S8/Fe7S8 (O-CSFS), which exhibited superior performance due to the highly elec-troactive sites induced by SV and oxygen doping, low charge resistance, and increased conductivity. The ROS-driven pathway and ET-driven pathway were found to be responsible for PCM degradation in the O-CSFS/MPS system, with the ET-driven pathway playing a more significant role.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2023)
Article
Engineering, Environmental
Defenna Li, Cong Pan, Yang Zong, Deli Wu, Yaobin Ding, Chengjun Wang, Shaobin Wang, John C. Crittenden
Summary: In this study, Ru(III) ions were used to activate periodate (PI) for oxidation of trace organic pollutants (TOPs, such as carbamazepine (CBZ)). The Ru(III)/PI system showed significantly higher performance than other transition metal ions and noble metal ions activated PI systems in the oxidation of CBZ. The dominant oxidant in the process was high-valent Ru-oxo species (Ru(V)=O).
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Wenyuan Han, Degang Li, Yifan Kong, Wei Liu, Wenwu Qin, Shaobin Wang, Xiaoguang Duan
Summary: In this study, carbon quantum dots (CQDs) with different oxygen contents were prepared and CQDs200 showed the best persulfate activation performance. It was postulated that the C=O groups on the surface of CQDs might be the predominant active sites, which was confirmed by selective chemical titrations.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Jinqiang Zhang, Xinyuan Xu, Yazi Liu, Xiaoguang Duan, Shaobin Wang, Hongqi Sun
Summary: Photoreforming of biomass, a process that utilizes renewable sunlight and biomass to produce hydrogen, holds promise for future energy sustainability. This study successfully developed highly efficient photocatalysts by anchoring Pt single atoms onto ultra-thin g-C3N4 nanosheets. The Pt-MCNN-3.0% catalyst demonstrated an impressive hydrogen generation rate approximately 59 times higher than that of MCNN, with satisfied photo-stability. This work is critical for the design of efficient photocatalysts, bringing us closer to realizing the potential of biomass photoreforming as a sustainable and clean energy conversion technology.
SURFACES AND INTERFACES
(2023)
Review
Green & Sustainable Science & Technology
Abdallah Abdelfattah, Sameh Samir Ali, Hassan Ramadan, Eslam Ibrahim El-Aswar, Reham Eltawab, Shih-Hsin Ho, Tamer Elsamahy, Shengnan Li, Mostafa M. El-Sheekh, Michael Schagerl, Michael Kornaros, Jianzhong Sun
Summary: The rapid expansion of the global economy and human population has led to a shortage of water resources suitable for direct human consumption, making water remediation a global priority. Microalgae cultivation in various types of wastewaters has shown promise in removing contaminants from industrial and urban effluents. Microalgae-based wastewater treatment has gained attention for its low energy requirements, ability to thrive in diverse environmental conditions, and potential to transform wastewater nutrients into valuable compounds. This review highlights the application of microalgae in wastewater remediation, including the removal of various pollutants and the potential for resource recovery through different mechanisms.
ENVIRONMENTAL SCIENCE AND ECOTECHNOLOGY
(2023)
Article
Engineering, Chemical
Jinqiang Zhang, Xinyuan Xu, Lei Shi, Huayang Zhang, Shaobin Wang, Hongqi Sun
Summary: Biomass photoreforming is a promising avenue for green hydrogen production. By loading 2D ZnIn2S4 onto 2D carbon nitride nanosheets, Van der Waals heterojunctions are formed, resulting in optimal charge dynamics and intensified H2 generation.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Chemistry, Physical
Yandong Chai, Hongling Dai, Xiaoguang Duan, Zhiqiang Sun, Fengping Hu, Jin Qian, Xiaoming Peng
Summary: By decorating the Fe single-atom catalyst (Fe-NC) through electronic structure modulation and introducing P into the second shell layer, the ability for peroxymonosulfate (PMS) activation was improved. The Fe-PNC showed outstanding activity for bisphenol A (BPA) oxidation due to its unique coordination environment and high spin state compared to Fe-NC, as supported by experimental data and density functional theory (DFT) calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Chaofa Chen, Minjia Yan, Yu Li, Yuwen Hu, Jianrong Chen, Shaobin Wang, Xi-Lin Wu, Xiaoguang Duan
Summary: In this study, single-atom Co catalytic sites were successfully constructed and confined in LDH for selective generation of radical species via PMS activation. The system exhibited high efficiency for up to 48 hours with suppressed PMS decomposition and self-quenching. The SA-Co-LDH/PMS system outperformed benchmark homogeneous and heterogeneous catalytic systems in degrading EOCs, with the lowest Co consumption and highest catalytic efficiency.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)