Architectural Design for Enhanced C2 Product Selectivity in Electrochemical CO2 Reduction Using Cu-Based Catalysts: A Review

Oxidation State and Surface Reconstruction of Cu under CO2 Reduction Conditions from In Situ X-ray Characterization

(2021) Soo Hong Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selectivity Map for the Late Stages of CO and CO2 Reduction to C2 Species on Cu Electrodes

(2021) Oriol Piqué et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photocatalytic C–C Coupling from Carbon Dioxide Reduction on Copper Oxide with Mixed-Valence Copper(I)/Copper(II)

(2021) Wei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atomic nickel cluster decorated defect-rich copper for enhanced C2 product selectivity in electrocatalytic CO2 reduction

(2021) Xiaolong Zhang et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Potential Link between Cu Surface and Selective CO 2 Electroreduction: Perspective on Future Electrocatalyst Designs

(2020) Gracita M. Tomboc et al.   ADVANCED MATERIALS

Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis

(2020) Xiao Jiang et al.   CHEMICAL REVIEWS

Efficient Methane Electrosynthesis Enabled by Tuning Local CO2 Availability

(2020) Xue Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic understanding of the electrocatalytic CO2 reduction reaction – New developments based on advanced instrumental techniques

(2020) Ying Zhang et al.   Nano Today

Molecular enhancement of heterogeneous CO2 reduction

(2020) Dae-Hyun Nam et al.   NATURE MATERIALS

CO2 electrolysis to multicarbon products at activities greater than 1 A cm−2

(2020) F. Pelayo García de Arquer et al.   SCIENCE

Strategies in catalysts and electrolyzer design for electrochemical CO2 reduction toward C2+ products

(2020) Lei Fan et al.   Science Advances

Stability and degradation mechanisms of copper-based catalysts for electrochemical CO2 reduction

(2020) Stefan Popović et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical Reduction of CO 2 to Ethane through Stabilization of an Ethoxy Intermediate

(2020) Anthony Vasileff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Protecting Copper Oxidation State via Intermediate Confinement for Selective CO2 Electroreduction to C2+ Fuels

(2020) Peng-Peng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facet-Dependent Selectivity of Cu Catalysts in Electrochemical CO2 Reduction at Commercially Viable Current Densities

(2020) Gian Luca De Gregorio et al.   ACS Catalysis

Enhancing CO2 Electroreduction to Ethanol on Copper–Silver Composites by Opening an Alternative Catalytic Pathway

(2020) Louisa Rui Lin Ting et al.   ACS Catalysis

Efficient electrically powered CO2-to-ethanol via suppression of deoxygenation

(2020) Xue Wang et al.   Nature Energy

Highly Electrocatalytic Ethylene Production from CO2 on Nanodefective Cu Nanosheets

(2020) Bingxing Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Towards molecular understanding of local chemical environment effects in electro- and photocatalytic CO2 reduction

(2020) Andreas Wagner et al.   Nature Catalysis

Insight into the mechanisms of CO2 reduction to CHO over Zr-doped Cu nanoparticle

(2020) H. Li et al.   CHEMICAL PHYSICS

Structural Sensitivities in Bimetallic Catalysts for Electrochemical CO2 Reduction Revealed by Ag-Cu Nanodimers

(2019) Jianfeng Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electro-Reduction of CO₂ on Cu Clusters: The Effects of Size, Symmetry, and Temperature

(2019) Yi-Fan Bu et al.   ChemElectroChem

Cocatalysts for Selective Photoreduction of CO2 into Solar Fuels

(2019) Xin Li et al.   CHEMICAL REVIEWS

Controllable Isomerization of Alkenes by Dual Visible-Light-Cobalt Catalysis

(2019) Qing-Yuan Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Catalysts

(2019) Yao Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

(2019) Stephanie Nitopi et al.   CHEMICAL REVIEWS

AuCu Alloy Nanoparticle Embedded Cu Submicrocone Arrays for Selective Conversion of CO 2 to Ethanol

(2019) Sibo Shen et al.   Small

Electrochemically converting carbon monoxide to liquid fuels by directing selectivity with electrode surface area

(2019) Lei Wang et al.   Nature Catalysis

Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate

(2019) Wesley Luc et al.   Nature Catalysis

Cascade Reactions in Nanozymes: Spatially Separated Active Sites inside Ag-Core–Porous-Cu-Shell Nanoparticles for Multistep Carbon Dioxide Reduction to Higher Organic Molecules

(2019) Peter B. O’Mara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

(2019) Yuvraj Y. Birdja et al.   Nature Energy

Aqueous Electrochemical Reduction of Carbon Dioxide and Carbon Monoxide into Methanol with Cobalt Phthalocyanine

(2019) Etienne Boutin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atomic Layer Deposition of ZnO on CuO Enables Selective and Efficient Electroreduction of Carbon Dioxide to Liquid Fuels

(2019) Dan Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electroreduction of CO2 on Single-Site Copper-Nitrogen-Doped Carbon Material: Selective Formation of Ethanol and Reversible Restructuration of the Metal Sites

(2019) Dilan Karapinar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni5Ga3 catalysts for CO2 reduction to methanol: Exploring the role of Ga surface oxidation/reduction on catalytic activity

(2019) Alessandro Gallo et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Carbon dioxide electroreduction to C2 products over copper-cuprous oxide derived from electrosynthesized copper complex

(2019) Qinggong Zhu et al.   Nature Communications

Constraining CO coverage on copper promotes high-efficiency ethylene electroproduction

(2019) Jun Li et al.   Nature Catalysis

Cooperative CO2-to-ethanol conversion via enriched intermediates at molecule–metal catalyst interfaces

(2019) Fengwang Li et al.   Nature Catalysis

Mixed Copper States in Anodized Cu Electrocatalyst for Stable and Selective Ethylene Production from CO2 Reduction

(2018) Si Young Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-based nanocatalysts for electrochemical reduction of CO 2

(2018) Huan Xie et al.   Nano Today

Recent advances in the nanoengineering of electrocatalysts for CO2 reduction

(2018) Fengwang Li et al.   Nanoscale

Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction

(2018) Zhe Weng et al.   Nature Communications

Mechanism of CO2 Reduction at Copper Surfaces: Pathways to C2 Products

(2018) Alejandro J. Garza et al.   ACS Catalysis

Surface and Interface Engineering in Copper-Based Bimetallic Materials for Selective CO 2 Electroreduction

(2018) Anthony Vasileff et al.   Chem

Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2

(2018) Zhi-Qin Liang et al.   Nature Communications

Progress toward Commercial Application of Electrochemical Carbon Dioxide Reduction

(2018) Chi Chen et al.   Chem

A Highly Porous Copper Electrocatalyst for Carbon Dioxide Reduction

(2018) Jing-Jing Lv et al.   ADVANCED MATERIALS

Laser-Prepared CuZn Alloy Catalyst for Selective Electrochemical Reduction of CO2 to Ethylene

(2018) Yi Feng et al.   LANGMUIR

CO Electroreduction: Current Development and Understanding of Cu-Based Catalysts

(2018) Haochen Zhang et al.   ACS Catalysis

Gas-Diffusion Electrodes for Carbon Dioxide Reduction: A New Paradigm

(2018) Drew Higgins et al.   ACS Energy Letters

Reaction Mechanism of Cu(I)-Mediated Reductive CO2 Coupling for the Selective Formation of Oxalate: Cooperative CO2 Reduction To Give Mixed-Valence Cu2(CO2•–) and Nucleophilic-Like Attack

(2017) Jialing Lan et al.   INORGANIC CHEMISTRY

Current Status and Bioinspired Perspective of Electrochemical Conversion of CO2 to a Long-Chain Hydrocarbon

(2017) Ki Dong Yang et al.   Journal of Physical Chemistry Letters

Building Blocks for High Performance in Electrocatalytic CO2 Reduction: Materials, Optimization Strategies, and Device Engineering

(2017) Gastón O. Larrazábal et al.   Journal of Physical Chemistry Letters

Highly Active and Selective Hydrogenation of CO2 to Ethanol by Ordered Pd–Cu Nanoparticles

(2017) Shuxing Bai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical CO2 Reduction over Compressively Strained CuAg Surface Alloys with Enhanced Multi-Carbon Oxygenate Selectivity

(2017) Ezra L. Clark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu metal embedded in oxidized matrix catalyst to promote CO 2 activation and CO dimerization for electrochemical reduction of CO 2

(2017) Hai Xiao et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Subsurface oxide plays a critical role in CO 2 activation by Cu(111) surfaces to form chemisorbed CO 2 , the first step in reduction of CO 2

(2017) Marco Favaro et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Copper nanoparticle ensembles for selective electroreduction of CO2to C2–C3products

(2017) Dohyung Kim et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

CO2reduction to acetate in mixtures of ultrasmall (Cu)n,(Ag)mbimetallic nanoparticles

(2017) Ying Wang et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Electrochemical Reduction of CO2 Using Copper Single-Crystal Surfaces: Effects of CO* Coverage on the Selective Formation of Ethylene

(2017) Yun Huang et al.   ACS Catalysis

Prism-Shaped Cu Nanocatalysts for Electrochemical CO2 Reduction to Ethylene

(2017) Hyo Sang Jeon et al.   ACS Catalysis

Fundamentals and Challenges of Electrochemical CO 2 Reduction Using Two-Dimensional Materials

(2017) Zhenyu Sun et al.   Chem

Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide

(2016) Dong Dong Zhu et al.   ADVANCED MATERIALS

Morphology-Directed Selective Production of Ethylene or Ethane from CO2on a Cu Mesopore Electrode

(2016) Ki Dong Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction

(2016) Anna Loiudice et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO2 over Cu Nanowire Arrays

(2016) Ming Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure-sensitive electroreduction of acetaldehyde to ethanol on copper and its mechanistic implications for CO and CO 2 reduction

(2016) Isis Ledezma-Yanez et al.   CATALYSIS TODAY

CO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts

(2016) Xiaoxia Chang et al.   Energy & Environmental Science

Opportunities and challenges in the electrocatalysis of CO 2 and CO reduction using bifunctional surfaces: A theoretical and experimental study of Au–Cd alloys

(2016) Zarko P. Jovanov et al.   JOURNAL OF CATALYSIS

Mechanistic Insights into the Selective Electroreduction of Carbon Dioxide to Ethylene on Cu2O-Derived Copper Catalysts

(2016) Albertus D. Handoko et al.   Journal of Physical Chemistry C

Identification of Possible Pathways for C–C Bond Formation during Electrochemical Reduction of CO2: New Theoretical Insights from an Improved Electrochemical Model

(2016) Jason D. Goodpaster et al.   Journal of Physical Chemistry Letters

Electroreduction of Carbon Dioxide to Hydrocarbons Using Bimetallic Cu–Pd Catalysts with Different Mixing Patterns

(2016) Sichao Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene

(2016) Hemma Mistry et al.   Nature Communications

Morphology Matters: Tuning the Product Distribution of CO2 Electroreduction on Oxide-Derived Cu Foam Catalysts

(2016) Abhijit Dutta et al.   ACS Catalysis

Tuning the Selectivity of Carbon Dioxide Electroreduction toward Ethanol on Oxide-Derived CuxZn Catalysts

(2016) Dan Ren et al.   ACS Catalysis

Recent Advances in Breaking Scaling Relations for Effective Electrochemical Conversion of CO2

(2016) Yawei Li et al.   Advanced Energy Materials

A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles

(2016) Xiaofeng Feng et al.   ACS Central Science

Acetaldehyde as an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide-Derived Copper

(2015) Erlend Bertheussen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrocatalytic Production of C3-C4 Compounds by Conversion of CO2on a Chloride-Induced Bi-Phasic Cu2O-Cu Catalyst

(2015) Seunghwa Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts

(2015) F. Sloan Roberts et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient photocatalytic reduction of CO2 by amine-functionalized g-C3N4

(2015) Qian Huang et al.   APPLIED SURFACE SCIENCE

Enzymatic conversion of carbon dioxide

(2015) Jiafu Shi et al.   CHEMICAL SOCIETY REVIEWS

Electrode Build-Up of Reducible Metal Composites toward Achievable Electrochemical Conversion of Carbon Dioxide

(2015) Seunghwa Lee et al.   ChemSusChem

Electrochemical Reduction of Carbon Dioxide to Ethane Using Nanostructured Cu2O-Derived Copper Catalyst and Palladium(II) Chloride

(2015) Chung Shou Chen et al.   Journal of Physical Chemistry C

Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide

(2015) Ruud Kortlever et al.   Journal of Physical Chemistry Letters

Achieving Selective and Efficient Electrocatalytic Activity for CO2 Reduction Using Immobilized Silver Nanoparticles

(2015) Cheonghee Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mesostructure-Induced Selectivity in CO2 Reduction Catalysis

(2015) Anthony Shoji Hall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Dense Cu Nanowires for Low-Overpotential CO2 Reduction

(2015) David Raciti et al.   NANO LETTERS

Insights into an autonomously formed oxygen-evacuated Cu2O electrode for the selective production of C2H4 from CO2

(2015) Dahee Kim et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts

(2015) Dan Ren et al.   ACS Catalysis

Facet Dependence of CO2 Reduction Paths on Cu Electrodes

(2015) Wenjia Luo et al.   ACS Catalysis

Stable and selective electrochemical reduction of carbon dioxide to ethylene on copper mesocrystals

(2015) Chung Shou Chen et al.   Catalysis Science & Technology

Highly selective defect-mediated photochemical CO2 conversion over fluorite ceria under ambient conditions

(2014) Dong Jiang et al.   CHEMICAL COMMUNICATIONS

Reaction mechanisms of CO2 electrochemical reduction on Cu(111) determined with density functional theory

(2014) Xiaowa Nie et al.   JOURNAL OF CATALYSIS

Particle Size Effects in the Catalytic Electroreduction of CO2 on Cu Nanoparticles

(2014) Rulle Reske et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper

(2014) Christina W. Li et al.   NATURE

Electrochemical CO2 reduction on Cu2O-derived copper nanoparticles: controlling the catalytic selectivity of hydrocarbons

(2014) Recep Kas et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Electrochemical Reduction of CO2 at Copper Nanofoams

(2014) Sujat Sen et al.   ACS Catalysis

Competition between CO2 Reduction and H2 Evolution on Transition-Metal Electrocatalysts

(2014) Yin-Jia Zhang et al.   ACS Catalysis

Electrochemical conversion of CO2 to C2 hydrocarbons using different ex situ copper electrodeposits

(2013) M.R. Gonçalves et al.   ELECTROCHIMICA ACTA

The influence of pH on the reduction of CO and CO2 to hydrocarbons on copper electrodes

(2013) Klaas Jan P. Schouten et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY

Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO2 Reduction to CO

(2013) Heine A. Hansen et al.   Journal of Physical Chemistry Letters

Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption

(2013) Dusan Strmcnik et al.   Nature Chemistry

Electrochemical conversion of CO2 to useful chemicals: current status, remaining challenges, and future opportunities

(2013) Huei-Ru “Molly” Jhong et al.   Current Opinion in Chemical Engineering

An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction

(2012) Yanghe Fu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ultrathin W18O49 Nanowires with Diameters below 1 nm: Synthesis, Near-Infrared Absorption, Photoluminescence, and Photochemical Reduction of Carbon Dioxide

(2012) Guangcheng Xi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrocatalytic pathways towards sustainable fuel production from water and CO2

(2012) Jane L. Inglis et al.   COORDINATION CHEMISTRY REVIEWS

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces

(2012) Kendra P. Kuhl et al.   Energy & Environmental Science

Nanoparticle Silver Catalysts That Show Enhanced Activity for Carbon Dioxide Electrolysis

(2012) Amin Salehi-Khojin et al.   Journal of Physical Chemistry C

Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes

(2012) Klaas Jan P. Schouten et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Self-doped SrTiO3−δ photocatalyst with enhanced activity for artificial photosynthesis under visible light

(2011) Kui Xie et al.   Energy & Environmental Science

Electron-Induced Dissociation of CO2on TiO2(110)

(2011) Junseok Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Oxidation of Alcohols on Gold in Alkaline Media: Base or Gold Catalysis?

(2011) Youngkook Kwon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The importance of surface morphology in controlling the selectivity of polycrystalline copper for CO2 electroreduction

(2011) Wei Tang et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Structure effects on the energetics of the electrochemical reduction of CO2 by copper surfaces

(2011) William J. Durand et al.   SURFACE SCIENCE

A new mechanism for the selectivity to C1 and C2 species in the electrochemical reduction of carbon dioxide on copper electrodes

(2011) K. J. P. Schouten et al.   Chemical Science

Alkali-promoted CO dissociation on Cu(111) and Ni(111) at room temperature

(2008) A. Politano et al.   JOURNAL OF CHEMICAL PHYSICS