Journal
ACS APPLIED ENERGY MATERIALS
Volume 4, Issue 2, Pages 1537-1547Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.0c02736
Keywords
NiCo2O4; spinel oxide; energy storage; supercapacitor; MOF; coordination modulation
Funding
- Auburn University startup fund
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Highly porous Co3O4/NiCo2O4 nanostructures were synthesized by adjusting the oxide composite structure through modifications in ZIF-67 crystallite size and pore structure using the coordination modulation method. The nanostructured Co3O4/NiCo2O4 exhibited a maximum capacitance of 770 F g(-1) with good cycle stability, maintaining 70% of the initial capacitance after 10,000 charge-discharge cycles.
Highly porous Co3O4/NiCo2O4 nanostructures were synthesized using zeolitic imidazolate framework-67 (ZIF-67) nanocrystals. The oxide composite structure was adjusted by modifying ZIF-67 crystallite size and the pore structure by the coordination modulation method. After forming the zeolite imidazolate framework-67 (ZIF-67)/Ni-Co layered double hydroxide intermediate composite through reaction with nickel nitrate, the intermediate composite was heated in air to result in Co3O4/NiCo2O4. Nitrogen adsorption was used for pore structure characterization of the template and resultant oxide composite. The maximum capacitance of nanostructured Co3O4/NiCo2O4 was 770 F g(-1) at a discharge current density of 1 A g(-1) with acceptable cycle stability, maintaining 70% of the initial capacitance after 10,000 charge-discharge cycles.
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