Review
Chemistry, Analytical
Asta Hooge, Henrik Hauggaard-Nielsen, Wiebke M. Heinze, Gry Lyngsie, Tiffany M. Ramos, Monica H. Sandgaard, Jes Vollertsen, Kristian Syberg
Summary: The aim of this study was to review the occurrence of microplastics in sewage sludge from wastewater treatment plants and evaluate the implications of sludge application to agricultural soils. Sludge serves as a significant sink for microplastics in wastewater treatment plants, emphasizing its importance as a pathway for environmental exposure. The application of sludge on agricultural fields is associated with increased concentrations of microplastics in soils, potentially impacting soil health. However, sludge treatments prior to application may alter the abundance and properties of microplastics, such as shape and size, subsequently affecting environmental risk. Knowledge gaps still exist regarding sludge treatments and their effects on microplastics. Further investigation is needed to assess the risk of microplastics exposure in wastewater treatment plants, explore the effects of sludge treatments on soil health, and better understand how management practices in wastewater treatment plants and agricultural systems influence microplastic properties.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2023)
Article
Environmental Sciences
Elke Brandes, Martin Henseler, Peter Kreins
Summary: Microplastic contamination in agricultural soils has attracted significant attention, calling for more research to understand the quantities and impacts of this pollutant. Limited data on the emissions of MPs into agricultural soils are currently available, but combining MP analysis results with national statistics can provide insights into the spatial distribution in Germany.
ENVIRONMENTAL RESEARCH LETTERS
(2021)
Article
Biochemical Research Methods
Carmen Mejias, Juan Luis Santos, Julia Martin, Irene Aparicio, Esteban Alonso
Summary: In this paper, a method for the determination of antibiotics and their metabolites in sewage sludge and agricultural soil was proposed. The method utilizes ultrasound-assisted extraction, dispersive solid-phase extraction clean-up, and liquid chromatography-tandem mass spectrometry. The method was validated and showed good accuracy and precision. The results revealed that macrolides and fluoroquinolones were the antibiotic classes found at the highest concentrations in all types of samples.
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2023)
Article
Agronomy
Yuwei Hu, Asanka R. Bandara, Jianchu Xu, Pattana Kakumyan, Kevin D. Hyde, Peter E. Mortimer
Summary: The cultivation of Agaricus subrufescens may have positive impacts on agricultural soils, increasing nutrient levels and improving soil health. Additionally, the fungal mycelia of A. subrufescens have the potential to degrade the pesticide beta-cypermethrin.
Article
Environmental Sciences
Gabin Colombini, Cornelia Rumpel, Sabine Houot, Philippe Biron, Marie -France Dignac
Summary: The input of microplastics into agroecosystems, especially through compost application, is a major concern. This study evaluates the impact of different composts derived from urban waste on the quantity of coarse microplastics in soils. The results indicate that composts made from municipal solid waste result in the highest quantity of plastic particles in soils, highlighting the need to reduce plastic use and improve waste sorting.
ENVIRONMENTAL POLLUTION
(2022)
Article
Environmental Sciences
Martin Henseler, Micheal Bernard Gallagher, Peter Kreins
Summary: Microplastic pollution in soils is a recent environmental problem that has raised questions and concerns among researchers and politicians due to the lack of knowledge about its impacts and extent. This study assesses the severity of microplastic pollution in German agricultural soils resulting from the use of sewage sludge and compost, and compares the efficiency and effectiveness of different measures to reduce it.
ENVIRONMENTAL MODELING & ASSESSMENT
(2022)
Review
Environmental Sciences
Ibrahim Sa'adu, Andrea Farsang
Summary: Researchers are focused on addressing the global issue of plastic contamination in agricultural soils due to its detrimental effects on the soil ecosystem. This study aimed to review the latest knowledge on plastic contamination, propose the best method for microplastic studies, and identify future research areas. The study reviewed literature published from January 2018 to March 2022, specifically focusing on agricultural soils. The findings revealed that plastic contamination in agricultural soils is influenced by various sources and is distributed spatially and temporally.
ENVIRONMENTAL SCIENCES EUROPE
(2023)
Article
Environmental Sciences
Doorgha Ragoobur, Esperanza Huerta-Lwanga, Geeta Devi Somaroo
Summary: The study investigated the presence of microplastics in agricultural soils, wastewater effluents, and sewage sludge in Mauritius, revealing high concentrations of microplastics in these samples. Polypropylene was found to be the predominant type of microplastics present, mainly in the form of fibers, fragments, and flakes, with high abundance in both agricultural soil samples and wastewater treatment plants.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Geosciences, Multidisciplinary
Luigi Alessandrino, Maria Pia Gervasio, Fabio Vincenzi, Nicolo Colombani, Giuseppe Castaldelli, Micol Mastrocicco
Summary: The study found that the effects of compost application combined with minimum tillage and traditional fertilization in two agricultural soils in the Po River plain are transient, with nutrient leaching diminishing over time if new incorporations do not occur. Nutrient leaching in shallow groundwater was minimal and followed a decreasing order of nitrate > ammonium > nitrite > phosphate. The distribution of nutrients also depended on groundwater fluxes and boundary conditions, and soil organic carbon increase was temporary and ceased after three years.
Article
Chemistry, Analytical
Marina Arenas, Juan Luis Santos, Julia Martin, Irene Aparicio, Esteban Alonso
Summary: An analytical method was optimized and validated for the extraction and determination of chiral beta-blockers, antidepressants, and their metabolites in agricultural soils, compost, and digested sludge. The method utilized ultrasound-assisted extraction and dispersive solid-phase extraction for sample treatment and liquid chromatography-tandem mass spectrometry with a chiral column for analysis. The method exhibited good enantiomeric resolution, accuracy, precision, and low quantification limits in different sample matrices. Enantiomeric enrichment was observed, particularly in compost and digested sludge samples.
ANALYTICA CHIMICA ACTA
(2023)
Article
Environmental Sciences
G. Lopez-Berenguer, A. Acosta-Dacal, O. P. Luzardo, J. Penalver, E. Martinez-Lopez
Summary: Despite being a hotspot of marine biodiversity, the Mediterranean Sea is also highly polluted with various environmental pollutants. This study investigated the concentration of organic pesticides and pollutants in stranded cetaceans in the northern coast of the Gulf of Vera. Most samples had detectable levels of these compounds, with DDT and its metabolites, PCBs, and metoxychlor being the dominant pollutants. Striped dolphins had higher concentrations of these pollutants. The study highlights the potential health consequences for Mediterranean cetaceans and emphasizes the importance of conservation efforts in the region.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Review
Environmental Sciences
Pelin Koyuncuoglu, Gulbin Erden
Summary: Microplastics are widely detected in wastewater treatment plants and can be efficiently removed from wastewaters, but they accumulate in sewage sludge. Studies on quantifying and identifying microplastics in sewage sludge are limited and require further investigation. The economic use of treated sewage sludge for soil amendment creates a pathway for microplastics entering the soil environment, potentially harming soil safety and organisms.
ENVIRONMENTAL MONITORING AND ASSESSMENT
(2021)
Article
Soil Science
Lauren Hale, Daniel Curtis, Nicole Leon, Milton McGiffen, Dong Wang
Summary: This study found that applying compost improved soil organic carbon, aggregate stability, EPSac, and total microbial biomass while also influencing microbial community structures, particularly in turfgrass. Deficit irrigation treatments resulted in higher quantities of soil EPSac per unit microbial biomass, with indicators of microbial physiological stress being closely associated with soil EPSac production.
SOIL BIOLOGY & BIOCHEMISTRY
(2021)
Article
Engineering, Environmental
Hui Lin, Qianyu Yuan, Qiaogang Yu, Zhaoming Chen, Junwei Ma
Summary: Vegetable production systems are found to have significant impacts on N2O emissions and antibiotic pollution. This study reveals that the growth of vegetables can reduce N2O emissions while the contamination of enrofloxacin increases N2O emissions. By interacting with soil nitrate and certain bacteria, growing vegetables can either decrease the production of N2O or increase the consumption of N2O, resulting in lower N2O emissions.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Environmental Sciences
Melanie Braun, Matthias Mail, Rene Heyse, Wulf Amelung
Summary: The study found detectable plastic particles in compost, posing a potential threat to soil health. Compost application may result in high plastic content per hectare annually, requiring technical solutions to reduce contamination risks.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Biochemistry & Molecular Biology
Eva Sanchez-Hernandez, Joaquin Balduque-Gil, Vicente Gonzalez-Garcia, Juan J. Barriuso-Vargas, Jose Casanova-Gascon, Jesus Martin-Gil, Pablo Martin-Ramos
Summary: This study characterized the phytoconstituents of Sambucus nigra leaves and flowers' aqueous ammonia extracts using infrared spectroscopy and gas chromatography-mass spectrometry. The flower extract contained compounds such as octyl 2-methylpropanoate and 1-methyl-2-piperidinemethanol, while the leaf extract contained 1,6-anhydro-beta-D-glucopyranose and oleic acid. The extracts showed antimicrobial activity against almond tree pathogens, with the flower extract exhibiting higher activity than the leaf extract.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Plant Sciences
Joaquin Balduque-Gil, Francisco J. Lacueva-Perez, Gorka Labata-Lezaun, Rafael del-Hoyo-Alonso, Sergio Ilarri, Eva Sanchez-Hernandez, Pablo Martin-Ramos, Juan J. Barriuso-Vargas
Summary: Machine Learning (ML) techniques are used to convert Big Data into valuable information for agri-environmental applications, such as predictive pest modeling. This study focuses on optimizing the Touzeau model, a correlation model between temperature and L. botrana development, using data-driven ML models. Field observations and 30 GB of weather data were combined to train the ML models and make predictions on pest flights. The results show that ML models outperform the Touzeau model, with the best-performing model being an artificial neural network with four layers.
Review
Environmental Sciences
Khageshwar Singh Patel, Saroj Sharma, Jyoti Prakash Maity, Pablo Martin-Ramos, Zeljka Fiket, Prosun Bhattacharya, Yanbei Zhu
Summary: Uranium, thorium, and rare earth elements (REEs) are strategically important elements in high and green technology and power generation. The extraction, use, and disposal processes of these elements can lead to elevated concentrations in air, water, soil, and sediments, with potential environmental and toxicological effects. Plants can also accumulate these elements, with some known hyperaccumulators containing high concentrations. Further research is needed to understand the fate and effects of these elements, and alternative methods for their recovery from industrial and mining wastes should be developed.
FRONTIERS IN ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Physical
Alma Cioci, Denisse G. Dante, Pablo Martin-Ramos, Pedro Chamorro-Posada, Domenica Marabello, Paola Benzi, Maria Carmen Valsania, Roberto C. Dante
Summary: Alpha, beta, gamma, delta-Copper(II) tetraphenylporphyrinate (CuTPP) was analyzed for its spectroscopic, structural, and morphological properties in thin film composites for optoelectronic devices. The study found that the substrate interaction induced aliphatic CH2 or CH3 formation and rearranged the bending bands of the phenyl groups. UV-vis spectroscopy showed the presence of two bands at 350 and 472 nm in the films, instead of the expected intense band between 380 and 500 nm. X-ray diffraction analysis revealed the structure of the complex, and scanning electron microscopy confirmed the growth of two-dimensional square-shaped aggregates after annealing.
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES
(2023)
Article
Agriculture, Multidisciplinary
Natalia Langa-Lomba, Vicente Gonzalez-Garcia, Pablo Martin-Ramos, Jose Casanova-Gascon
Summary: Grapevine trunk diseases (GTDs) are causing significant damage in vineyards and have a growing socioeconomic impact. Effective control strategies or curative treatments are currently unavailable due to European legislation. Screening for less sensitive cultivars is considered a sustainable approach for GTDs management.
JOURNAL OF PLANT DISEASES AND PROTECTION
(2023)
Article
Biochemistry & Molecular Biology
Eva Sanchez-Hernandez, Pablo Martin-Ramos, Luis Manuel Navas-Gracia, Jesus Martin-Gil, Ana Garces-Claver, Alejandro Flores-Leon, Vicente Gonzalez-Garcia
Summary: The cliff rose (Armeria maritima) has an antioxidant system that enables it to grow in saline habitats and exhibits antifungal activity. The main phytochemicals found in the flowers of A. maritima were identified and tested for their antifungal potential against several plant pathogens. Results showed that the extract, along with its main constituents combined with chitosan oligomers, displayed strong antifungal activity against the tested pathogens.
Article
Chemistry, Physical
Alberto Santiago-Aliste, Eva Sanchez-Hernandez, Celia Andres-Juan, Pedro Chamorro-Posada, Guillermo Antorrena, Jesus Martin-Gil, Pablo Martin-Ramos
Summary: In this study, a F,O,S-codoped graphitic carbon nitride photocatalyst was synthesized and applied in the synthesis of benzoxazoles and benzimidazoles, achieving high yields of up to 90%. The results demonstrate the excellent photocatalytic performance and reusability of this F,O,S-codoped graphitic carbon nitride.
Article
Horticulture
Eva Sanchez-Hernandez, Vicente Gonzalez-Garcia, Ana Palacio-Bielsa, Jose Casanova-Gascon, Luis Manuel Navas-Gracia, Jesus Martin-Gil, Pablo Martin-Ramos
Summary: This study examined the chemical constituents of the Euphorbia serrata L. plant and proposed potential uses for crop protection. The main phytocompounds were identified as 3-methylbutyl formate, quinic acid, N1-(4-hydroxybutyl)-N3-methylguanidine acetate, and 2,3-dihydro-3,5-dihydroxy-6-methyl-4H-pyran-4-one, which exhibited antimicrobial activity. In vitro tests showed that these compounds had minimum inhibitory concentrations (MICs) of 750 and 1000 μg·mL(-1) against the bacterium and fungal pathogens, respectively. The combination of the extract with chitosan oligomers (COS) enhanced this activity, demonstrating potential as a bio-rational approach for crop protection.
Article
Horticulture
Eva Sanchez-Hernandez, Vicente Gonzalez-Garcia, Jesus Martin-Gil, Belen Lorenzo-Vidal, Ana Palacio-Bielsa, Pablo Martin-Ramos
Summary: The yew tree is known for its longevity and regeneration, and despite being poisonous, it has a long history of medicinal use. This study used GC-MS chemical profiling to identify bioactive compounds in the aqueous ammonia/hydromethanolic extracts of various parts of the yew tree. The extracts showed antimicrobial activity against bacterial pathogens responsible for potato diseases, and could potentially be used in integrated pest management.
Article
Archaeology
Jose Maria Rodanes-Vicente, Jose Antonio Cuchi-Oterino, Takeshi Minami, Kazuya Takahashi, Jesus Martin-Gil, Jose Ignacio Lorenzo-Lizalde, Pablo Martin-Ramos
Summary: In the Cueva de la Sierra burial site in Huesca, Spain, a burial dating back to the Late Neolithic and Early Chalcolithic periods was found. Analysis using various techniques revealed that the red pigment used in the burial was cinnabar, originating from the Northwestern Iberian Peninsula, rather than the previously believed Almade 'n outcrop. This discovery challenges our understanding of the interactions between communities in the northern Iberian Peninsula during the late 4th millennium BC.
JOURNAL OF ARCHAEOLOGICAL SCIENCE-REPORTS
(2023)
Article
Humanities, Multidisciplinary
Pablo Martin-Ramos, Jose Antonio Cuchi-Oterino, Manuel Bea-Martinez
Summary: This study presents the results of the analysis of pigments used in eight main rock shelters in the River Vero canyon using portable X-ray fluorescence spectroscopy. The findings provide insights into the composition and conservation of these cave paintings.
Article
Materials Science, Multidisciplinary
Jaroslaw Rybusinski, Tomasz Fos, Pablo Martin-Ramos, Victor Lavin, Jacek Szczytko, Jan Suffczynski, Inocencio R. Martin, Jesus Martin-Gil, Manuela Ramos, Bruno Cury Camargo
Summary: We demonstrate the selective control of magnetic response and photoluminescence properties of Er3+ centers by associating them with a highly conjugated beta-diketonate ligand (1,3-di(2-naphthyl)-1,3-propanedione). We show that this optically-pumped molecular compound emits in the infrared and can be used as a precise heat-driving and detecting unit for low temperatures.
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2023)
Article
Biochemistry & Molecular Biology
Eva Sanchez-Hernandez, Javier Alvarez-Martinez, Vicente Gonzalez-Garcia, Jose Casanova-Gascon, Jesus Martin-Gil, Pablo Martin-Ramos
Summary: In this study, the hydromethanolic extract of Helichrysum stoechas inflorescences was characterized and its antifungal activity against tomato crop diseases was assessed. The extract showed promising inhibitory concentrations against various fungi and exhibited high protection against Colletotrichum coccodes. The activity of the extract was comparable to synthetic fungicides, making it a potential bio-rational alternative for crop protection.