Origin of the Activity of Co–N–C Catalysts for Chemoselective Hydrogenation of Nitroarenes

In situ-formed cobalt embedded into N-doped carbon as highly efficient and selective catalysts for the hydrogenation of halogenated nitrobenzenes under mild conditions

(2020) Yueling Cao et al.   APPLIED CATALYSIS A-GENERAL

Atomic-level tuning of Co–N–C catalyst for high-performance electrochemical H2O2 production

(2020) Euiyeon Jung et al.   NATURE MATERIALS

Water-promoted interfacial pathways in methane oxidation to methanol on a CeO2-Cu2O catalyst

(2020) Zongyuan Liu et al.   SCIENCE

Co,N-Codoped Porous Carbon-Supported CoyZnS with Superior Activity for Nitroarene Hydrogenation

(2020) Guangji Zhang et al.   ACS Sustainable Chemistry & Engineering

Unveiling the Axial Hydroxyl Ligand on FeN 4 C Electrocatalysts and Its Impact on the pH‐Dependent Oxygen Reduction Activities and Poisoning Kinetics

(2020) Xin Yang et al.   Advanced Science

Highly Efficient Hydrogenation of Nitroarenes by N-Doped Carbon-Supported Cobalt Single-Atom Catalyst in Ethanol/Water Mixed Solvent

(2020) Huanjun Wang et al.   ACS Applied Materials & Interfaces

pH Effect on the H2O2-Induced Deactivation of Fe-N-C Catalysts

(2020) Geunsu Bae et al.   ACS Catalysis

Local structure tuning in Fe-N-C catalysts through support effect for boosting CO2 electroreduction

(2020) Jinqin Tuo et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

A pyridinic Fe-N4 macrocycle models the active sites in Fe/N-doped carbon electrocatalysts

(2020) Travis Marshall-Roth et al.   Nature Communications

Almost 100 % Peroxymonosulfate Conversion to Singlet Oxygen on Single‐Atom CoN 2+2 Sites

(2020) Xueyue Mi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Axial ligand effect on the stability of Fe–N–C electrocatalysts for acidic oxygen reduction reaction

(2020) Feiteng Wang et al.   Nano Energy

Identification of durable and non-durable FeNx sites in Fe–N–C materials for proton exchange membrane fuel cells

(2020) Jingkun Li et al.   Nature Catalysis

Performance enhancement and degradation mechanism identification of a single-atom Co–N–C catalyst for proton exchange membrane fuel cells

(2020) Xiaohong Xie et al.   Nature Catalysis

A highly CO-tolerant atomically dispersed Pt catalyst for chemoselective hydrogenation

(2019) Lili Lin et al.   Nature Nanotechnology

Nitrogen-Doped Carbon Nanotube Confined Co-N x Sites for Selective Hydrogenation of Biomass-Derived Compounds

(2019) Wanbing Gong et al.   ADVANCED MATERIALS

Accurate Evaluation of Active-Site Density (SD) and Turnover Frequency (TOF) of PGM-Free Metal–Nitrogen-Doped Carbon (MNC) Electrocatalysts using CO Cryo Adsorption

(2019) Fang Luo et al.   ACS Catalysis

Cobalt in N-doped carbon matrix catalyst for chemoselective hydrogenation of nitroarenes

(2019) Yihu Dai et al.   APPLIED CATALYSIS A-GENERAL

Co based N, S co-doped carbon hybrids for catalytic hydrogenation: Role of cobalt salt and doped S

(2019) Ruixiao Gao et al.   APPLIED CATALYSIS A-GENERAL

Electrochemical Reduction of CO2 on Metal-Nitrogen-Doped Carbon Catalysts

(2019) Ana Sofia Varela et al.   ACS Catalysis

Solvent-mediated charge separation drives alternative hydrogenation path of furanics in liquid water

(2019) Zheng Zhao et al.   Nature Catalysis

Competitive adsorption on single-atom catalysts: Mechanistic insights into the aerobic oxidation of alcohols over Co N C

(2019) Kuntao Huang et al.   JOURNAL OF CATALYSIS

Understanding Active Sites in Pyrolyzed Fe–N–C Catalysts for Fuel Cell Cathodes by Bridging Density Functional Theory Calculations and 57Fe Mössbauer Spectroscopy

(2019) Tzonka Mineva et al.   ACS Catalysis

Identification of Catalytic Sites for Oxygen Reduction in Metal/Nitrogen-Doped Carbons with Encapsulated Metal Nanoparticles

(2019) Ming-Xi Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hollow and Yolk–Shell Co-N-C@SiO2 Nanoreactors: Controllable Synthesis with High Selectivity and Activity for Nitroarene Hydrogenation

(2019) Xiaocheng Lan et al.   ACS Applied Materials & Interfaces

Evolution Pathway from Iron Compounds to Fe1(II)–N4 Sites through Gas-Phase Iron during Pyrolysis

(2019) Jingkun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Water-Mediated Heterogeneously Catalyzed Reactions

(2019) Gengnan Li et al.   ACS Catalysis

Carbon Nanosheets Containing Discrete Co-Nx-By-C Active Sites for Efficient Oxygen Electrocatalysis and Rechargeable Zn–Air Batteries

(2018) Yingying Guo et al.   ACS Nano

A Durable Nickel Single-Atom Catalyst for Hydrogenation Reactions and Cellulose Valorization under Harsh Conditions

(2018) Wengang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ordered Porous N-Doping Carbon Matrix with Atomically Dispersed Co Sites as an Efficient Catalyst for Dehydrogenation/Transfer Hydrogenation of N-Heterocycles

(2018) Yadong Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Review on selective hydrogenation of nitroarene by catalytic, photocatalytic and electrocatalytic reactions

(2018) Jiajia Song et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Solvent-Controlled Reactivity of Au/CeO2 Towards Hydrogenation of p-Chloronitrobenzene

(2018) Zhun Hu et al.   CATALYSIS LETTERS

MOF-Derived Cobalt Phosphide/Carbon Nanocubes for Selective Hydrogenation of Nitroarenes to Anilines

(2018) Shuliang Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Designed Precursor for the Controlled Synthesis of Highly Active Atomic and Sub-nanometric Platinum Catalysts on Mesoporous Silica

(2018) Sudipta De et al.   Chemistry-An Asian Journal

Cobalt nanocomposites on N-doped hierarchical porous carbon for highly selective formation of anilines and imines from nitroarenes

(2018) Tao Song et al.   GREEN CHEMISTRY

Single cobalt sites in mesoporous N-doped carbon matrix for selective catalytic hydrogenation of nitroarenes

(2018) Xiaohui Sun et al.   JOURNAL OF CATALYSIS

Engineering Single-Atom Cobalt Catalysts toward Improved Electrocatalysis

(2018) Gang Wan et al.   Small

Single-site catalyst promoters accelerate metal-catalyzed nitroarene hydrogenation

(2018) Liang Wang et al.   Nature Communications

Hydrogen Transfer Catalysis beyond the Primary Coordination Sphere

(2018) Lillian V. A. Hale et al.   ACS Catalysis

Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes

(2018) Mirco Eckardt et al.   Scientific Reports

Heterogeneous single-atom catalysis

(2018) Aiqin Wang et al.   Nature Reviews Chemistry

Scale-Up Biomass Pathway to Cobalt Single-Site Catalysts Anchored on N-Doped Porous Carbon Nanobelt with Ultrahigh Surface Area

(2018) Youqi Zhu et al.   ADVANCED FUNCTIONAL MATERIALS

Single atom catalysts on carbon-based materials

(2018) Philippe Serp et al.   ChemCatChem

Single Cobalt Atoms Anchored on Porous N-Doped Graphene with Dual Reaction Sites for Efficient Fenton-like Catalysis

(2018) Xuning Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solid-state nanocasting synthesis of ordered mesoporous CoNx–carbon catalysts for highly efficient hydrogenation of nitro compounds

(2018) Xiangru Wei et al.   Nanoscale

Atomic engineering of high-density isolated Co atoms on graphene with proximal-atom controlled reaction selectivity

(2018) Huan Yan et al.   Nature Communications

Single-atom catalyst: a rising star for green synthesis of fine chemicals

(2018) Leilei Zhang et al.   National Science Review

Hydrogenation of terminal and internal olefins using a biowaste-derived heterogeneous cobalt catalyst

(2018) Florian Korbinian Scharnagl et al.   Science Advances

Reduction of Nitro Compounds Using 3d-Non-Noble Metal Catalysts

(2018) Dario Formenti et al.   CHEMICAL REVIEWS

Catalysis with Two-Dimensional Materials Confining Single Atoms: Concept, Design, and Applications

(2018) Yong Wang et al.   CHEMICAL REVIEWS

Solvent Tunes the Selectivity of Hydrogenation Reaction over α-MoC Catalyst

(2018) Yuchen Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Physical and Chemical Considerations for Improving Catalytic Activity and Stability of Non-Precious-Metal Oxygen Reduction Reaction Catalysts

(2018) Kavita Kumar et al.   ACS Catalysis

Different active sites in a bifunctional Co@N-doped graphene shells based catalyst for the oxidative dehydrogenation and hydrogenation reactions

(2017) Jinlei Li et al.   JOURNAL OF CATALYSIS

In situ mosaic strategy generated Co-based N-doped mesoporous carbon for highly selective hydrogenation of nitroaromatics

(2017) Fengwei Zhang et al.   JOURNAL OF CATALYSIS

Co-based heterogeneous catalysts from well-defined α-diimine complexes: Discussing the role of nitrogen

(2017) Dario Formenti et al.   JOURNAL OF CATALYSIS

Cobalt nanoparticles supported on N-doped mesoporous carbon as a highly efficient catalyst for the synthesis of aromatic amines

(2017) Xueliang Cui et al.   JOURNAL OF COLLOID AND INTERFACE SCIENCE

Activating Cobalt Nanoparticles via the Mott–Schottky Effect in Nitrogen-Rich Carbon Shells for Base-Free Aerobic Oxidation of Alcohols to Esters

(2017) Hui Su et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal (Hydr)oxides@Polymer Core–Shell Strategy to Metal Single-Atom Materials

(2017) Maolin Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discriminating Catalytically Active FeNx Species of Atomically Dispersed Fe–N–C Catalyst for Selective Oxidation of the C–H Bond

(2017) Wengang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

MOF-derived cobalt nanoparticles catalyze a general synthesis of amines

(2017) Rajenahally V. Jagadeesh et al.   SCIENCE

High performance of a cobalt–nitrogen complex for the reduction and reductive coupling of nitro compounds into amines and their derivatives

(2017) Peng Zhou et al.   Science Advances

A Reusable Co Catalyst for the Selective Hydrogenation of Functionalized Nitroarenes and the Direct Synthesis of Imines and Benzimidazoles from Nitroarenes and Aldehydes

(2016) Tobias Schwob et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Non-noble metal catalysts for hydrogenation: A facile method for preparing Co nanoparticles covered with thin layered carbon

(2016) Lichen Liu et al.   JOURNAL OF CATALYSIS

Chemoselective hydrogenation of functionalized nitroarenes using MOF-derived co-based catalysts

(2016) Xi Wang et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts

(2016) Vanessa Armel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni–C–N Nanosheets as Catalyst for Hydrogen Evolution Reaction

(2016) Jie Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-atom dispersed Co–N–C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes

(2016) Wengang Liu et al.   Chemical Science

Identifying active sites of CoNC/CNT from pyrolysis of molecularly defined complexes for oxidative esterification and hydrogenation reactions

(2016) Tianyuan Cheng et al.   Catalysis Science & Technology

Solvent effects in catalysis: rational improvements of catalysts via manipulation of solvent interactions

(2016) Paul J. Dyson et al.   Catalysis Science & Technology

Fe2O3/NGr@C- and Co–Co3O4/NGr@C-catalysed hydrogenation of nitroarenes under mild conditions

(2016) Dario Formenti et al.   Catalysis Science & Technology

A metal–organic framework-derived bifunctional oxygen electrocatalyst

(2016) Bao Yu Xia et al.   Nature Energy

Enhanced Electron Penetration through an Ultrathin Graphene Layer for Highly Efficient Catalysis of the Hydrogen Evolution Reaction

(2015) Jiao Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In situ Cobalt–Cobalt Oxide/N-Doped Carbon Hybrids As Superior Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution

(2015) Haiyan Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-based nanocatalysts for green oxidation and hydrogenation processes

(2015) Rajenahally V Jagadeesh et al.   Nature Protocols

Molecular metal–N x centres in porous carbon for electrocatalytic hydrogen evolution

(2015) Hai-Wei Liang et al.   Nature Communications

Highly Robust Hydrogen Generation by Bioinspired Ir Complexes for Dehydrogenation of Formic Acid in Water: Experimental and Theoretical Mechanistic Investigations at Different pH

(2015) Wan-Hui Wang et al.   ACS Catalysis

Transforming Nano Metal Nonselective Particulates into Chemoselective Catalysts for Hydrogenation of Substituted Nitrobenzenes

(2015) Pedro Serna et al.   ACS Catalysis

In Situ-Generated Co0-Co3O4/N-Doped Carbon Nanotubes Hybrids as Efficient and Chemoselective Catalysts for Hydrogenation of Nitroarenes

(2015) Zhongzhe Wei et al.   ACS Catalysis

Co–N–C Catalyst for C–C Coupling Reactions: On the Catalytic Performance and Active Sites

(2015) Leilei Zhang et al.   ACS Catalysis

Fabrication of Nitrogen-Modified Annealed Nanodiamond with Improved Catalytic Activity

(2014) Yangming Lin et al.   ACS Nano

Catalytic hydrogenation of 2,4-dinitroethylbenzene to 2,4-diaminoethylbenzene over Ni/HY catalysts: The solvent effect

(2014) Bin Ren et al.   CATALYSIS COMMUNICATIONS

General and selective reductive amination of carbonyl compounds using a core–shell structured Co3O4/NGr@C catalyst

(2014) Tobias Stemmler et al.   GREEN CHEMISTRY

FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes

(2014) Haisheng Wei et al.   Nature Communications

Acid-Resistant Catalysis without Use of Noble Metals: Carbon Nitride with Underlying Nickel

(2014) Teng Fu et al.   ACS Catalysis

“All-water” one-pot diverse synthesis of 1,2-disubstituted benzimidazoles: hydrogen bond driven ‘synergistic electrophile–nucleophile dual activation’ by water

(2013) Damodara N. Kommi et al.   GREEN CHEMISTRY

Correlations between Mass Activity and Physicochemical Properties of Fe/N/C Catalysts for the ORR in PEM Fuel Cell via 57Fe Mössbauer Spectroscopy and Other Techniques

(2013) Ulrike I. Kramm et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterogenized cobalt oxide catalysts for nitroarene reduction by pyrolysis of molecularly defined complexes

(2013) Felix A. Westerhaus et al.   Nature Chemistry

Mechanistic Insight through Factors Controlling Effective Hydrogenation of CO2 Catalyzed by Bioinspired Proton-Responsive Iridium(III) Complexes

(2013) Wan-Hui Wang et al.   ACS Catalysis

Poisoning the Oxygen Reduction Reaction on Carbon-Supported Fe and Cu Electrocatalysts: Evidence for Metal-Centered Activity

(2011) Matthew S. Thorum et al.   Journal of Physical Chemistry Letters

High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt

(2011) G. Wu et al.   SCIENCE

Tuning the Acid/Base Properties of Nanocarbons by Functionalization via Amination

(2010) Rosa Arrigo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Stereoselective Proton/Hydride Exchange: Assistance of Hydrogen Bonding for the Heterolytic Splitting of H2

(2009) Anja Friedrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic surface rearrangement and thermal stability of nitrogen functional groups on carbon nanotubes

(2008) Rosa Arrigo et al.   CHEMICAL COMMUNICATIONS