Stretching-induced phase transitions in barium titanate-poly(vinylidene fluoride) flexible composite piezoelectric films

Improving the piezoelectric performance of poly(vinylidene fluoride) (PVDF) is important for many appli-cations, including energy harvesting. The addition of barium titanate (BaTiO3) nanoparticles in the polymer matrix is a popular method to facilitate beta phase formation in PVDF films. For pure PVDF, mechanical drawing (i.e. stretching) has also been shown to increase piezoelectric performance. This work examines, for the first time, the combined effect of stretching and BaTiO3 addition on phase transformations in BaTiO3-PVDF composite films. The results indicate that an alternative phase transformation mechanism occurs during the stretching of PVDF composite films. While stretching of pure PVDF films results in the conversion of non-polar alpha phase into the electroactive beta phase, stretching of BaTiO3-PVDF composite films results primarily in the conversion of weakly electroactive gamma phase into the more electroactive beta phase. Overall, stretching of BaTiO3-PVDF films is shown to be beneficial for increasing beta phase content of PVDF. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Automated summary

This study investigates the combined effect of stretching and BaTiO3 addition on phase transformations in BaTiO3-PVDF composite films, revealing a different phase transformation mechanism during stretching of pure PVDF films compared to BaTiO3-PVDF composite films. Stretching BaTiO3-PVDF films is shown to be beneficial for increasing the beta phase content of PVDF.