Journal
SCIENCE OF THE TOTAL ENVIRONMENT
Volume 755, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.scitotenv.2020.142504
Keywords
PCBs; Unintentional production; Pigments; 3,3 '-Dichlorobiphenyl; Decachlorobiphenyl
Categories
Funding
- Environment Research and Technology Development Fund of the Environmental Restoration and Conservation Agency of Japan (ERCA) [SII-3-2]
- Project On-site Education Program in Analytical Chemistry (OEPAC) by the University of Tokyo, Japan
- Japan Analytical Instruments Manufacturer's Association (JAIMA)
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This review article provides a comprehensive overview of the formation, emission, environmental occurrence, and potential adverse effects of unintentionally produced polychlorinated biphenyls (PCBs) in pigments. PCBs are typically formed during the manufacturing of organic pigments and can contaminate atmospheric, terrestrial, and aquatic ecosystems, affecting organisms living in these environments. The variability in PCB concentrations and profiles among pigment types and producers highlights the importance of appropriate monitoring, management, and abatement strategies for these pollutants.
The formation, emission, environmental occurrence, and potential adverse effects of unintentionally produced polychlorinated biphenyls (PCBs) in pigments are reviewed, providing a comprehensive and up-to-date picture on these pollutants. PCBs are typically formed during manufacturing of organic pigments that involve chlorinated intermediates and reaction solvents, rather than those of inorganic pigments. Concentrations and profiles of PCBs vary greatly among pigment types and producers, with total PCB levels ranging from lower than detection limits to several hundred ppm; major components can be low-chlorinated (e.g., CB-11) or high-chlorinated congeners (e.g., CB-209). Pigment-derived PCBs can be released into the environment through different steps including pigment production, application, and disposal. They can contaminate atmospheric, terrestrial, and aquatic ecosystems, and then affect organisms living there. This situation garners scientific and public attention to nonlegacy emissions of PCBs and suggests the need for appropriatemonitoring, management, and abatement strategies regarding these pollutants. (C) 2020 Elsevier B.V. All rights reserved.
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