A Mild One-Pot Reduction of Phosphine(V) Oxides Affording Phosphines(III) and Their Metal Catalysts

Direct and Scalable Electroreduction of Triphenylphosphine Oxide to Triphenylphosphine

(2020) Shuhei Manabe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Beyond CO2 Reduction: Vistas on Electrochemical Reduction of Heavy Nonmetal Oxides with Very Strong E—O Bonds (E = Si, P, S)

(2020) Biswarup Chakraborty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of optically active tertiary phosphine oxides: A historical overview and the latest advances

(2019) Jacek Chrzanowski et al.   HETEROATOM CHEMISTRY

Exploring an Umpolung strategy for quaternization of phosphorus

(2019) Anna C. Vetter et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

Circular chemistry to enable a circular economy

(2019) Tom Keijer et al.   Nature Chemistry

Reduction of Phosphine Oxide by Using Chlorination Reagents and Dihydrogen: DFT Mechanistic Insights

(2019) Hui Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Impact of Oxygen on Leading and Emerging Ru-Carbene Catalysts for Olefin Metathesis: An Unanticipated Correlation Between Robustness and Metathesis Activity

(2019) Stephanie J. Ton et al.   ACS Catalysis

Silicon chemistry in zero to three dimensions: from dichlorosilylene to silafullerane

(2018) J. Teichmann et al.   CHEMICAL COMMUNICATIONS

Long sought synthesis of quaternary phosphonium salts from phosphine oxides: inverse reactivity approach

(2018) Anna C. Vetter et al.   CHEMICAL COMMUNICATIONS

Exhaustively Trichlorosilylated C1 and C2 Building Blocks: Beyond the Müller-Rochow Direct Process

(2018) Isabelle Georg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic phosphonium cation-mediated phosphane oxide reduction using oxalyl chloride and hydrogen

(2018) Arne Jan Stepen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dynamic kinetic resolution of 1-substituted-3-methyl-3-phospholene oxides via the formation of diastereomeric alkoxyphospholenium salts

(2018) Péter Bagi et al.   TETRAHEDRON

Direct Electrochemical P(V) to P(III) Reduction of Phosphine Oxide Facilitated by Triaryl Borates

(2018) Joseph S. Elias et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trapping Experiments on a Trichlorosilanide Anion: a Key Intermediate of Halogenosilane Chemistry

(2017) Julian Teichmann et al.   INORGANIC CHEMISTRY

Trifluoromethanesulfonate Anion as Nucleophile in Organic Chemistry

(2017) Bibek Dhakal et al.   JOURNAL OF ORGANIC CHEMISTRY

A novel preparation of chlorophospholenium chlorides and their application in the synthesis of phospholene boranes

(2017) Réka Herbay et al.   TETRAHEDRON LETTERS

Disilanes as oxygen scavengers and surrogates of hydrosilanes suitable for selective reduction of nitroarenes, phosphine oxides and other valuable substrates

(2017) Ashot Gevorgyan et al.   Organic Chemistry Frontiers

Preparation of P-heterocyclic phosphine boranes and optically active phosphine oxides via phosphonium salts

(2016) Réka Herbay et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

Pot economy and one-pot synthesis

(2016) Yujiro Hayashi   Chemical Science

Organocatalyzed Reduction of Tertiary Phosphine Oxides

(2015) Marie-Luis Schirmer et al.   ADVANCED SYNTHESIS & CATALYSIS

Reduction of secondary and tertiary phosphine oxides to phosphines

(2015) Damien Hérault et al.   CHEMICAL SOCIETY REVIEWS

Lithium Borohydride for Achiral and ­Stereospecific Reductive Boronation at Phosphorus: Lack of Electronic Effects on Stereoselective Formation of Alkoxyphosphonium Salts

(2015) Sulaiman S. Al Sulaimi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Greening the global phosphorus cycle: how green chemistry can help achieve planetary P sustainability

(2015) Paul J. A. Withers et al.   GREEN CHEMISTRY

Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives

(2015) Marcin Kalek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reduction of phosphine oxides to the corresponding phosphine derivatives in Mg/Me3SiCl/DMI system

(2015) Manabu Kuroboshi et al.   TETRAHEDRON LETTERS

Tandem redox mediator/Ni(ii) trihalide complex photocycle for hydrogen evolution from HCl

(2015) Seung Jun Hwang et al.   Chemical Science

The Mitsunobu reaction in the 21st century

(2015) S. Fletcher   Organic Chemistry Frontiers

Chloride-Induced Aufbau of Perchlorinated Cyclohexasilanes from Si2Cl6: A Mechanistic Scenario

(2014) Jan Tillmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cleavage of PO in the Presence of P-N: Aminophosphine Oxide Reduction with In Situ Boronation of the PIIIProduct

(2013) Niall P. Kenny et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-free reduction of tertiary phosphine oxides with Hantzsch ester

(2013) Tong-Xin Zhang et al.   CHINESE CHEMICAL LETTERS

A short and modular synthesis of bulky and electron-rich N-phosphinomethyl-functionalised N-heterocyclic carbene complexes

(2013) Marcel Brill et al.   DALTON TRANSACTIONS

Synthesis of 2,3-Dihydro-1-phenylbenzo[b]phosphole (1-Phenylphosphindane) and Its Use as a Mechanistic Test in the Asymmetric Appel Reaction: Decisive Evidence against Involvement of Pseudorotation in the Stereoselecting Step

(2013) Damien J. Carr et al.   JOURNAL OF ORGANIC CHEMISTRY

Bulky N-Phosphinomethyl-Functionalized N-Heterocyclic Carbene Chelate Ligands: Synthesis, Molecular Geometry, Electronic Structure, and Their Ruthenium Alkylidene Complexes

(2013) Hiyam Salem et al.   ORGANOMETALLICS

Systematic survey of positive chlorine sources in the asymmetric Appel reaction: oxalyl chloride as a new phosphine activator

(2013) Kamalraj V. Rajendran et al.   TETRAHEDRON LETTERS

One Hundred Years of Vitamins-A Success Story of the Natural Sciences

(2012) Manfred Eggersdorfer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct evidence of a multicentre halogen bond: unexpected contraction of the P–XXX–P fragment in triphenylphosphine dihalides

(2012) Kirill Nikitin et al.   CHEMICAL COMMUNICATIONS

Theoretical Investigation of the Mechanisms and Stereoselectivities of Reductions of Acyclic Phosphine Oxides and Sulfides by Chlorosilanes

(2012) Elizabeth H. Krenske   JOURNAL OF ORGANIC CHEMISTRY

General and Selective Copper-Catalyzed Reduction of Tertiary and Secondary Phosphine Oxides: Convenient Synthesis of Phosphines

(2012) Yuehui Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Chemoselective Metal-Free Reduction of Phosphine Oxides to Phosphines

(2012) Yuehui Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactions

(2012) Peter A. Byrne et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride

(2011) Kamalraj V. Rajendran et al.   CHEMICAL COMMUNICATIONS

Phosphine−Phosphinite and Phosphine−Phosphite Ligands: Preparation and Applications in Asymmetric Catalysis

(2011) Héctor Fernández-Pérez et al.   CHEMICAL REVIEWS

Reductions of Phosphine Oxides and Sulfides by Perchlorosilanes: Evidence for the Involvement of Donor-Stabilized Dichlorosilylene

(2011) Elizabeth H. Krenske   JOURNAL OF ORGANIC CHEMISTRY

Synthesis and Catalytic Evaluation in Olefin Metathesis of a Second-Generation Homobimetallic Ruthenium–Arene Complex Bearing a Vinylidene Ligand

(2011) Yannick Borguet et al.   ORGANOMETALLICS

New Route for Synthesis of MeO-MOP

(2011) Qingle Zeng et al.   SYNTHETIC COMMUNICATIONS

Electroreduction of tetra-coordinate phosphonium derivatives; one-pot transformation of triphenylphosphine oxide into triphenylphosphine

(2011) Manabu Kuroboshi et al.   TETRAHEDRON

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

A Practical One-Pot Transformation of Triphenylphosphine Oxide to Triphenylphosphine by Reduction of in situ Generated Triphenylphosphine Dichloride

(2010) Hideo Tanaka et al.   SYNLETT

Electroreduction of triphenylphosphine dichloride and the efficient one-pot reductive conversion of phosphine oxide to triphenylphosphine

(2009) Tomotake Yano et al.   TETRAHEDRON LETTERS

Ruthenium–indenylidene complexes: powerful tools for metathesis transformations

(2008) Fabien Boeda et al.   CHEMICAL COMMUNICATIONS

Reduction of Tertiary Phosphine Oxides with DIBAL-H

(2008) Carl A. Busacca et al.   JOURNAL OF ORGANIC CHEMISTRY