Article
Materials Science, Multidisciplinary
Subin Oh, Junsik Bang, Hyoung-Joon Jin, Hyo Won Kwak
Summary: Currently, the majority of oil-water separation membranes are made of fluorine-based polymers with low surface energy. However, these materials are non-biodegradable and require a large amount of organic and toxic solvents in the manufacturing process. Therefore, there is increasing interest in developing a new eco-friendly oil-water separation membrane that does not cause secondary pollution and exhibits selective wettability characteristics.
ADVANCED FIBER MATERIALS
(2023)
Article
Environmental Sciences
Xinjuan Zeng, Jiadong Lin, Weicheng Cai, Qiaorou Lu, Shuyi Fu, Jingjing Li, Xiqiang Yan, Xiufang Wen, Cailong Zhou, Min Zhang
Summary: The PA@PEI/PVDF membrane exhibited outstanding static and dynamic water stability, and was able to separate multiple oil-in-water emulsions with an average rejection rate exceeding 98.5% and a water flux up to 12203.6 L M-2.h(-1).bar(-1). The membrane showed excellent antifouling performance and recovery capability after four separation-washing cycles, indicating its great potential in practical treatment of emulsified oily wastewater.
Article
Engineering, Chemical
Wei Deng, Tianzhu Fan, Ying Li
Summary: The in situ biomineralization method was used to fabricate PVDF-TiO2 membranes with superhydrophilic and underwater superoleophobic properties, which showed excellent antifouling performance and high rejection of oil during crossflow filtration of oil-in-water emulsions. The superior performance of the membrane was attributed to the durable and super-wetting TiO2 coatings, as well as the relatively smooth surface structure that prevented oil trapping.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Engineering, Environmental
Yu Jin Seo, Nara Han, Hee Ju Kim, Ji Hee Choi, Hye Young Koo, Chengzhong Yu, Won San Choi
Summary: The scoop net equipped with an underwater anti-oil-fouling filter showed promising performance in cleaning low-sulfur fuel, with high water absorption capacity and excellent long-term stability against oil fouling.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Feng Shijie, Zhao Jiefeng, Zhang Pengyu, Gao Yunling, Yun Junxian
Summary: Environmentally friendly membranes with high hydrophilicity and underwater superoleophobicity were prepared by co-depositing polydopamine and chitosan-tripolyphosphate nanoparticles onto a nylon membrane. The modified membrane exhibited excellent antifouling performance and could effectively separate oil-in-water emulsions of different particle sizes.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Man Xu, Hao Zhang, Wenhai Peng, Xingmeng Ruan, Li Chen, Xiaohui Dai, Jiangdong Dai
Summary: This study presents the design of a dual functional poly-electrolyte membrane for the treatment of oily wastewater containing water-soluble dyes. The membrane possesses superior separation and degradation capabilities, allowing for efficient removal of oil droplets and dyes. It exhibits superhydrophilicity and underwater super-oleophobicity, as well as excellent photocatalytic degradation properties.
APPLIED SURFACE SCIENCE
(2023)
Article
Engineering, Chemical
M. Obaid, Hend Omar Mohamed, Abayomi Babatunde Alayande, Yesol Kang, Noreddine Ghaffour, In S. Kim
Summary: ENM-based filtration technology is an advanced solution for water scarcity, using gravity or low pressure to treat wastewater for reuse. Utilizing a two-step metal-phenolic network (MPN) coating process, superhydrophilic and underwater superoleophobic ENMs were developed for efficient separation of oily wastewater and oil-in-water emulsions, showing high flux values and excellent oil rejection capabilities.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Chemical
Bin Jiang, Kai Cheng, Na Zhang, Na Yang, Luhong Zhang, Yongli Sun
Summary: The study successfully transformed hydrophobic PVDF membranes into highly hydrophilic and underwater superoleophobic ones through one-step dip-coating in a TA/NaIO4-mixed solution. The modified membrane showed enhanced permeability and oil rejection, excellent antifouling performance, and stability under harsh conditions, providing a simple, robust, and cost-effective strategy for membrane modification.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Chemistry, Physical
Jian Xu, Atian Xie, Haotian Sun, Chengcai Li, Changguo Xue, Jiuyun Cui, Jianming Pan
Summary: In this study, a polyvinylidene difluoride composite membrane (PVDF@TA-Fe membrane) with superhydrophilicity was prepared through the repeated spraying of tannic acid (TA) and Fe3+. The TA-Fe(III)-complex network formed on the membrane significantly increased its hydrophilicity, and the membrane showed superhydrophilicity/underwater superoleophobicity. The PVDF@TA-Fe membrane exhibited high separation efficiencies (above 99%) and high fluxes (1189.1-2310.0 L m-2 h-1 bar -1) when used for oil/water emulsion separation. The membrane also demonstrated good antifouling performance and maintained excellent oil/water separation performance after more than 10 cycles. This study is of great importance for the large-scale preparation of superhydrophilic membranes and treatment of oily wastewater.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Physical
Shaolin Yang, Maohui Li, Guoli Fang, Min Xue, Youjun Lu
Summary: A novel flexible cement-sand coated cotton fabric (CS@CF) with superhydrophilicity and underwater superoleophobicity was successfully prepared through a simple fabrication process without the need for chemical reagents, complex reactions, etc. This material shows high efficiency and recyclability in separating various water/oil mixtures and oil in-water emulsions, making it suitable for practical applications in industrial oily wastewater and oil spill treatments.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Materials Science, Multidisciplinary
Yucong Yu, Xiaolong Shi, Lin Liu, Wenli Gong, Xiangdong Kong, Juming Yao
Summary: Inspired by the unique molecular structure of cellulose, this study successfully prepared cellulose aerogels with high strength, superhydrophilicity, and underwater superoleophobicity, exhibiting excellent performance in oil-water separation.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Chemistry, Physical
Wei Xiong, Ling Li, Fen Qiao, Junwu Chen, Zhi Chen, Xuedong Zhou, Kaiwen Hu, Xiujian Zhao, Yi Xie
Summary: This study successfully fabricated air superhydrophilic-superoleophobic SiO2 coating by modifying the SiO2 surface with both hydrophilic and oleophobic groups, and constructing porous and hierarchical structures. The coatings showed high-efficiency oil/water separation performance and long-term durability.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Physical
Mengnan Qu, Yajie Pang, Jiehui Li, Rong Wang, Zhanxia Luo, Dan He, Wenchao Sun, Lei Peng, Jinmei He
Summary: By modifying polyvinylidene fluoride membranes with synthesized polymers, a membrane with superhydrophilicity-underwater superoleophobicity was successfully fabricated, enabling efficient separation of various oil-in-water emulsions with stable separation efficiency.
SURFACE AND INTERFACE ANALYSIS
(2021)
Article
Chemistry, Physical
Mengnan Qu, Dan He, Zhanxia Luo, Rong Wang, Fan Shi, Yajie Pang, Wenchao Sun, Lei Peng, Jinmei He
Summary: In this study, superhydrophilicity/underwater superoleophobicity PVDF membrane and superhydrophilicity/underwater superoleophobicity polyester fiber were successfully prepared for the treatment of various water pollutants. The modified membranes showed good durability and stability, effectively separating oil-water mixtures and adsorbing organic dyes and heavy metal ions. Based on these advantages, this study provides a new idea for efficient adsorption and separation of pollutants.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Engineering, Chemical
Meng Zhu, Yucheng Liu, Mingyan Chen, Mohtada Sadrzadeh, Zhiheng Xu, Dong Gan, Zhi Huang, Lili Ma, Bing Yang, Ying Zhou
Summary: This study successfully prepared superhydrophilic and underwater superoleophobic stainless steel mesh for efficient oil-water separation and organic matter degradation. The fabricated meshes maintained excellent oil-water separation efficiency under extreme conditions, and could degrade dye pollutants under visible light, improving solar energy utilization. This research lays the foundation for preparing super wetting membranes for oil-water separation and organic matter degradation in actual complex oily wastewater.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Engineering, Chemical
Chao Yu, Jian Lu, Zhiqiang Hou, Zhongfei Ma, Xinyu Lin, Zeqing Dong, Wendong Xing, Yongsheng Yan, Yilin Wu
Summary: In this study, rubidium ion separation membranes were prepared using a delayed phase inversion method, taking advantage of the different polarities between ethanol and water. The membranes showed enhanced rebinding capacity and selectivity towards rubidium ions, as well as remarkable perm-selectivity and regeneration performance, demonstrating potential for rapid and effective separation of rubidium ions.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Environmental
Jian Lu, Yingying Qin, Chunxiang Li, Yilin Wu, Minjia Meng, Zeqing Dong, Chang Sun, Muning Chen, Yongsheng Yan
Summary: This work presents the development of irregular dot array nanocomposite bisphenol A (BPA)-molecularly imprinted membranes (BPA-MIMs) through a modification-by-imprinting strategy, with superior selectivity, rebinding capacity, and flux. The membranes show impressive permselectivity coefficients and stability, along with concentration-dependent and time-dependent cumulative selectivity, demonstrating the potential for membrane-based water treatment and specific separation.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Yingying Qin, Jian Lu, Fanying Meng, Xinyu Lin, Yonghai Feng, Yongsheng Yan, Minjia Meng
Summary: By utilizing the design of 2D/2D Schottky-Ohmic junction, composite photocatalysts with outstanding photocatalytic performance were successfully prepared, leading to significant H-2 production. This remarkable enhancement of photocatalytic performance provides a successful paradigm for future research.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Physical
Fanying Meng, Yingying Qin, Jian Lu, Xinyu Lin, Minjia Meng, Gang Sun, Yongsheng Yan
Summary: Optimizing light absorption and charge spatial separation is crucial for improving photocatalytic performance; The novel g-C3N4 nanotube@pDA/NiCo-LDH composite photocatalyst shows efficient hydrogen evolution activity and stability in experiments; The composite photocatalyst has potential applications in the field of energy conversion.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Nanoscience & Nanotechnology
Wendong Xing, Zhongfei Ma, Chong Wang, Jian Lu, Jia Gao, Chao Yu, Xinyu Lin, Chunxiang Li, Yilin Wu
Summary: This work developed novel atrazine molecularly imprinted nanofibrous membranes with a molecular organic framework-based viscid bead structure inspired by natural spider-webs for selective separation of atrazine. The membranes showed enhanced rebinding capacity and permselectivity towards atrazine, demonstrating strong potential for environmental pollutant separation.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Engineering, Environmental
Chao Yu, Jianping Song, Zhongfei Ma, Jian Lu, Wendong Xing, Minjia Meng, Jiangdong Dai, Yongsheng Yan, Yilin Wu
Summary: Janus imprinted membranes (JIM) fabricated through the connective method of phase inversion and dip-coating processes offer promising potential for selective adsorption and separation of pollutants, showing excellent rebinding performance and selectivity, as well as good regeneration capability.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Chemical
Muning Chen, Jian Lu, Jia Gao, Chao Yu, Wendong Xing, Jiangdong Dai, Minjia Meng, Yongsheng Yan, Yilin Wu
Summary: The Ribavirin-imprinted membranes (RBVMIMs) with self-cleaning, anti-fouling, and antibacterial properties achieved selective separation of RBV from industrial effluent. The use of two functional monomers in the membrane synthesis promoted selective recognition of RBV-imprinted sites, leading to satisfactory rebinding selectivity and permselectivity, indicating the potential of RBVMIMs in practical applications. The development strategies in this work not only guided selective separation of valuable constituents but also provided reference for the development of high-performance membranes.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Engineering, Chemical
Chao Yu, Jianping Song, Zhongfei Ma, Jian Lu, Wendong Xing, Minjia Meng, Jiangdong Dai, Yongsheng Yan, Yilin Wu
Summary: The new cadmium ion imprinted membranes with double-face asymmetric structure, prepared by loading MWCNTs on both surfaces, show enhanced loading capacity and stability, achieving promising selectivity for the selective removal of heavy metal ions in wastewater.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Wendong Xing, Zhongfei Ma, Chong Wang, Jian Lu, Jia Gao, Chao Yu, Xinyu Lin, Chunxiang Li, Yilin Wu
Summary: A multiple strengthening strategy was proposed for the preparation of MOFs based molecularly imprinted nanofiber membranes (MINMs), achieving desired adsorption capacity and permselectivity towards template molecules. The fabricated MINMs also displayed strong practicability in simulated real samples, showing tremendous potential for designing MIMs with enhanced selective separation performance using MOFs.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
J. Lu, Y. -Y. Qin, Y. -L. Wu, Z. Zhu, M. -N. Chen, Y. -S. Yan, C. -X. Li
Summary: This study proposes a highly specific, self-cleaning, and interfacial-stable molecularly imprinted membrane (MIM) composed of g-C3N4/Ag3PO4/PDA based on biomimetic self-polymerization of dopamine. The membrane exhibits superior antifouling performance, remarkable permselectivity, and high flux regeneration rate. The achievements in this work will promote the development of MIMs with high specificity, self-cleaning capability, and stability for specific and selective separation.
MATERIALS TODAY CHEMISTRY
(2022)
Article
Engineering, Environmental
Jia Gao, Li Yan, Yan Yan, Li Chen, Jian Lu, Wendong Xing, Chao Yu, Muning Chen, Minjia Meng, Yongsheng Yan, Yilin Wu
Summary: This article proposes a solvent-driven controllable molecularly imprinted membrane for switched selectivity and fast regenerability. This method has important potential applications in membrane separation in water treatment.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Chemical
Jian Lu, Bingang Xu
Summary: In recent years, molecularly imprinted membranes (MIMs) have gained significant attention for their superior selectivity in various applications. This study developed a bio-inspired MIM using the anchoring/imprinting strategy for the imprinting of Epigallocatechin gallate (EGCG), a representative catechin. The MIM demonstrated remarkable selectivity and efficient regeneration performance.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Engineering, Environmental
Xingguo Wang, Zhixiang Liu, Jian Lu, Honghui Teng, Hiroatsu Fukuda, Weidong Qin, Tong Wei, Yang Liu
Summary: This study proposes a thermally induced strategy for enhancing the selective separation of Ciprofloxacin using a polydopamine-embedded molecularly imprinted membrane (DEMIM). The resulting membrane shows improved interpenetrating-bicontinuous porous morphology and availability of imprinted sites, leading to superior separation performance. The approach of utilizing thiol-ene Click reaction for imprinting polymerization and the use of polyvinylidene fluoride (PVDF) with integrated 13-cyclodextrin (13-CD) are also highlighted. The results demonstrate the feasibility of using porous membrane-based sleeves for the regeneration of molecular imprinting.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Jia Gao, Li Chen, Yongsheng Yan, Jian Lu, Wendong Xing, Jiangdong Dai, Minjia Meng, Yilin Wu
Summary: The study successfully prepared dot-matrix-initiated molecularly imprinted nanocomposite membranes with an anti-oil fouling layer. These membranes exhibited remarkable adsorption capacity, specific recognition capacity, and permselectivity, making them applicable in chemical separation industry and biomedicine.
ENVIRONMENTAL SCIENCE-NANO
(2021)