4.7 Article

A caffeic acid sensor based on CuZnOx/MWCNTs composite modified electrode

Journal

MICROCHEMICAL JOURNAL
Volume 161, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.microc.2020.105786

Keywords

Electrochemical sensor; CuZnOx/MWCNTs; Caffeic acid; Electrochemical detection

Funding

  1. National Natural Science Foundation of China [21978026]

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CuZnOx/MWCNTs composite materials were successfully synthesized and used as an electrochemical sensor to detect the response of CA, showing good performance and stability. The sensor can be widely applied to detect CA content in coffee and white wine.
CuZnOx/Multi-walled carbon nanotubes (MWCNTs) were synthesized by coprecipitation method, which was used as electrochemical sensor to detect the response of caffeic acid (CA). The morphology and elemental composition of as-prepared materials were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS). Electrochemical performances of materials were investigated through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), and the content of CA was determined by differential pulse voltammetry (DPV). The CV results proved that the optimal CuZnOx/MWCNTs modified GCE had a lower limit of detection of 0.155 mu M (LOD = 3Sb/S) with a wide linear range of 1-100 mu M, good reproducibility, repeatability and stability for CA detection. The CuZnOx/MWCNTs sensor can be used to detect CA in coffee and white wine. The findings could contribute to the development of new high-performance sensors for monitoring diet and food safety.

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