4.5 Article

Understanding the Effect of Nanosized NbC Precipitates on the Stress Corrosion Cracking of High-Strength Low-Alloy Steel in a Simulated Deep-Sea Environment

Journal

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
Volume 30, Issue 3, Pages 2159-2173

Publisher

SPRINGER
DOI: 10.1007/s11665-021-05532-7

Keywords

hydrogen; HSLA steel; nanosized NbC precipitates; SCC; simulated deep-sea environment

Funding

  1. National Key Research and Development Program of China [2016YFB0300604]
  2. National Natural Science Foundation of China [51971033, 51471033]
  3. National Materials Corrosion and Protection Data Center

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Nanosized NbC precipitates in a simulated deep-sea environment significantly decrease the electrochemical corrosion and SCC susceptibility of HSLA steel by increasing hydrogen traps and weakening the effect of hydrogen. The presence of nanosized NbC precipitates improves the SCC resistance of HSLA steel through hydrogen trapping and microstructural optimization effects, especially in environments with higher hydrogen concentration.
The effect of nanosized NbC precipitates on the stress corrosion cracking (SCC) of high-strength low-alloy (HSLA) steel in a simulated deep-sea environment was studied through electrochemical tests, hydrogen permeation tests and slow strain rate tension (SSRT) tests. The results show that in a simulated deep-sea environment, the presence of nanosized NbC precipitates significantly decreases electrochemical corrosion and SCC susceptibility. Nanosized NbC precipitates increased the amount of irreversible and reversible hydrogen traps, which pinned the hydrogen induced by the hydrogen evolution reaction, and weakened the effect of hydrogen on the AD and HE during SCC of HSLA steel. In addition, whether in deep- or shallow-sea environments, nanosized NbC precipitates improved the SCC resistance of HSLA steel by means of the hydrogen-trapping and microstructural optimization effect, but the microstructural optimization played a minor role. Once the steels were with higher hydrogen concentration, the hydrogen-trapping function of NbC precipitates increased, which resulted in larger SCC resistance improvement.

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