Article
Polymer Science
Elisa Guazzelli, Matteo Oliva, Carlo Pretti, Gianfranca Monni, Armand Fahs, Christine Bressy, Elisa Martinelli
Summary: Hydrolyzable block copolymers consisting of polyethylene glycol and poly(trialkylsilyl methacrylate-co-methyl methacrylate) were synthesized and their hydrolysis performance and erosion behavior in artificial seawater were studied. The results showed that the copolymer film surfaces could respond to the water environment and demonstrated antifouling behavior against diatoms.
Article
Construction & Building Technology
Po-Chien Hsiao, Chun-Yi Li
Summary: This study proposes a novel design of steel panel dampers (KSPD) which consists of a steel panel and two boundary columns connected by knife-plate details. Experimental results validate the feasibility of the KSPD design and demonstrate its stable energy dissipation and significant ductility. Design suggestions for the KSPD are summarized based on the experimental results and study findings.
JOURNAL OF BUILDING ENGINEERING
(2023)
Article
Chemistry, Physical
Maria del Prado Garrido, Ana Maria Borreguero, Francisco Javier Redondo, David Padilla, Manuel Carmona, Maria Jesus Ramos, Juan Francisco Rodriguez
Summary: In this study, St-MMA particles with PEGMA and/or GMA brushes were synthesized and found to effectively remove bilirubin by improving the BSA immobilization capacity and reducing processing time. Attachment of BSA to the particles reduced bilirubin concentration in plasma from levels that threaten patient survival to levels close to those of healthy individuals.
Article
Biochemistry & Molecular Biology
Ceren Cokca, Franz J. Hack, Daniel Costabel, Kira Herwig, Juliana Huelsmann, Patrick Then, Rainer Heintzmann, Dagmar Fischer, Kalina Peneva
Summary: This study describes the shielding of a high performing terpolymer using block copolymerization with various molecular weights of P(MEO(9)MA) and investigates its influence on cytotoxicity, pDNA binding, and transfection efficiency. The results show that higher molecular weight P(MEO(9)MA) blocks exhibit excellent biocompatibility and efficient transfection efficiency.
MACROMOLECULAR BIOSCIENCE
(2021)
Article
Chemistry, Analytical
Xiao-Lei Huo, Chen-Chen Zhu, Qing-Wen Zhou, Ning Bao
Summary: This paper aims to prepare disposable three-dimensional carbon electrodes using low-cost stainless steel wire mesh as templates, in order to improve their analytical performance. The results showed that the sensitivity and electrochemical response of the three-dimensional carbon electrodes were higher than those of the two-dimensional carbon electrodes, which could be attributed to the increased electrochemical effective area.
ANALYTICA CHIMICA ACTA
(2022)
Article
Polymer Science
Qian Li, Ruiqi Wang, Jun Lee, Joana S. Correia, Anna P. Constantinou, Jonathan Krell, Theoni K. Georgiou
Summary: A series of biocompatible thermoresponsive copolymers were synthesised using GTP from MEGMA and OEGMA. The copolymers displayed thermoresponsive behavior and self-assembly properties. Diblock copolymers with higher MEGMA content were able to form gels at low concentrations and showed a transition from spherical to wormlike micelles. Additionally, mixing the synthesised copolymers with Pluronic & REG; F127 broadened the gelation area and formed a stable gel within a desirable temperature range. Cell viability experiments confirmed the non-toxicity of the copolymers.
EUROPEAN POLYMER JOURNAL
(2023)
Article
Biochemistry & Molecular Biology
Nina Melnikova, Dmitry Orekhov, Alexander Simagin, Darina Malygina, Vitaly Korokin, Karina Kosmachova, Haider Al-Azzavi, Anna Solovyeva, Oleg Kazantsev
Summary: In this study, new copolymer conjugates were synthesized via RAFT polymerization and combined with CeO2 NPs to prepare biomimetic medical products with controlled antioxidant properties. The combination of copolymers and CeO2 NPs showed stronger effects in increasing enzyme activity and NADPH concentration compared to individual components.
Article
Chemistry, Multidisciplinary
Glendimar Molero, Cong Liu, Zewen Zhu, Qihui Chen, Suzanne R. Peterson, Pavan Kolluru, Hung-Jue Sue, Shuntaro Uenuma, Koichi Mayumi, Kohzo Ito
Summary: The fracture behavior of polyrotaxane (PR)-modified poly(methyl methacrylate) (PMMA) was investigated. By adding only 1 wt % of PR to the PMMA matrix, substantial improvement in fracture toughness was achieved while maintaining modulus and transparency. The interaction between PR and PMMA contributes to higher molecular mobility and enhanced molecular cooperativity, leading to the formation of massive crazing and improved fracture toughness.
Article
Engineering, Multidisciplinary
Norio Yamashita, Takashi Matsuno, Daisuke Maeda, Mayuko Kikuzuki, Hideo Yokota
Summary: This paper presents a fast and precise method for observing steel microstructures in 3D using cutting and on-site etching. The method combines precision cutting with automated 3D microscopy and on-site manual etching, resulting in high-quality 3D images of steel cross sections.
PRECISION ENGINEERING-JOURNAL OF THE INTERNATIONAL SOCIETIES FOR PRECISION ENGINEERING AND NANOTECHNOLOGY
(2022)
Article
Biochemistry & Molecular Biology
Dharavath Ravi, G. P. Rajalekshmy, M. R. Rekha, Roy Joseph
Summary: A new hydrogel system delivering ascorbic acid to wounds was developed using gellan-grafted poly (ethylene glycol) methacrylate. The hydrogel matrix allowed sustained release of ascorbic acid and showed improved wound closure in vitro. The study indicates that ascorbic acid has a favorable impact on wound healing and the GPMA matrix is a promising material for wound healing applications.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Materials Science, Multidisciplinary
Ricardo Santiago de Oliveira Gouvea, Maria Isabel Felisberti
Summary: Poly(sucrose methacrylate-co-acrylic acid) and poly(sucrose methacrylate-co-diethylene glycol methyl ether methacrylate) were synthesized via free radical polymerization, demonstrating temperature and pH responsiveness for hydrogel swelling. With increasing SMA molar fraction, the copolymer M-c also increases.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2021)
Article
Biochemistry & Molecular Biology
Ioanna Tzoumani, Amaia Soto Beobide, Zacharoula Iatridi, George A. Voyiatzis, Georgios Bokias, Joannis K. Kallitsis
Summary: This study reports the incorporation of GMA copolymers into waterborne polyurethanes (WPUs) and investigates their healing ability. Two types of copolymers were synthesized and successfully blended with WPUs to form homogeneous composites. Depending on the composition, the addition of different copolymers resulted in amorphous or semi-crystalline composite systems. Promising healing results were observed when water was used as a healing trigger.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Polymer Science
Birsen Somuncuoglu, Yu Lin Lee, Anna P. Constantinou, David L. M. Poussin, Theoni K. Georgiou
Summary: Well-defined amphiphilic diblock copolymers and statistical copolymers were synthesized and investigated as polymeric surfactants, with the molar mass and compositions affecting their final properties. Different hydrophilic monomers had varying effects on the solution properties of the copolymers. The emulsifying properties of block copolymers were influenced by the hydrophobic content and molecular weight, with differences observed between non-ionic and ionic polymeric macrosurfactants.
EUROPEAN POLYMER JOURNAL
(2021)
Article
Materials Science, Multidisciplinary
Kohei Sano, Koki Umemoto, Haruka Miura, Satoshi Ohno, Kyohei Iwata, Rin Kawakami, Masayuki Munekane, Toshihide Yamasaki, Daniel Citterio, Yuki Hiruta, Takahiro Mukai
Summary: Poly[oligo(ethylene glycol) methyl ether methacrylate] (POEGMA) was investigated as a potential drug carrier for tumor diagnosis. Different derivatives of POEGMA with varying molecular weights and side chain lengths were synthesized and labeled with radioisotopes or fluorescence dyes. The results showed that the POEGMA derivatives were efficiently taken up by tumor cells and exhibited high accumulation in tumor tissues. In vivo fluorescence imaging using optimized POEGMA derivatives confirmed their suitability as drug carriers for sensitive tumor diagnosis.
ACS APPLIED POLYMER MATERIALS
(2022)
Article
Polymer Science
D. M. Kamorin, A. S. Simagin, D. V. Orekhov, O. A. Kazantsev, E. A. Bolshakova, A. P. Sivokhin, M. V. Savinova, S. V. Orekhov
Summary: The synthesis and solution properties of thermoresponsive polymer molecular brushes based on five novel diblock macromonomers have been studied. The research showed the impact of synthesis conditions on the rate of radical solution polymerization, maximum conversions of macromonomers, and molecular weight characteristics of polymers. Furthermore, it demonstrated the influence of oligo(propylene glycol) block length on surface-active properties and aggregation behavior of the polymers.