4.2 Article

Lead removal from water using organic acrylic amine fiber (AAF) and inorganic-organic P-AAF, fixed bed filtration and surface-induced precipitation

Journal

JOURNAL OF ENVIRONMENTAL SCIENCES
Volume 101, Issue -, Pages 135-144

Publisher

SCIENCE PRESS
DOI: 10.1016/j.jes.2020.08.009

Keywords

Lead removal; Adsorption; Fixed bed filtration; Acrylic amine fiber; Inorganic-organic sorbent; Surface-induced precipitation

Funding

  1. Fundamental Research Funds for Central Public Welfare Scientific Research Institutes of China [2019-YSKY-009]
  2. Major Science and Technology Projects for Water Pollution Control and Treatment [2017ZX07004]

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Granular porous sorbents have been commonly used for heavy metals removal from water. In this study, an organic acrylic amine fiber (AAF) and phosphorus loading inorganic-organic AAF (P-AAF) were prepared and used for lead (Pb) removal from water. The study proposed a new strategy of inorganic-organic coupling technology for Pb removal, with P-AAF showing a better removal efficiency compared to AAF. This research contributes to our understanding of surface chemistry processes of Pb with P.
Granular porous sorbents were normally used for heavy metals removal from water. To search for the new commercial sorbent and treatment strategy, an organic acrylic amine fiber (AAF) and phosphorus loading inorganic-organic AAF (P-AAF) were prepared and used for lead (Pb) removal from water. A new strategy of inorganic-organic coupling technology was proposed for Pb removal, based on the hypothesis of surface-induced precipitation mechanism. The AAF showed a Pb adsorption capacity of 417 mg/g from the Langmuir fitting, while the column filtration technology was further applied to measure the adsorption edge and applications. Effects of different initial Pb concentrations, hydraulic retention time, and co-existing P were considered in the filtration experiments. The presence of 0.8 mg/L P in water significantly improved the Pb breakthrough point from 15,000 to 41,000 bed volumes of water spiked with 85 pg/L Pb, while the P-AAF fixed bed showed better removal of Pb than AAF SEM/EDX and XRD spectra were employed for determining the surface functional groups and the formation of surface-induced precipitation of pyromorphite (Pbs (PO4)(3)OH) on AAF. This study verified the application of AAF sorbent for Pb removal and the enhanced effect of coating P on AAF, thus improved our fundamental understanding and application of the surface chemistry process of Pb with P. (C) 2020 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

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