4.5 Article

Effects of Hydrothermal Temperature on the Photocatalytic Degradation Performance of Bismuth Oxide Formate

Journal

JOURNAL OF ELECTRONIC MATERIALS
Volume 50, Issue 4, Pages 2444-2453

Publisher

SPRINGER
DOI: 10.1007/s11664-021-08735-9

Keywords

BiOCOOH; photocatalytic; tetracycline; temperature

Funding

  1. Applied Basic Research Programs of Science and Technology Department of Sichuan Province [2018JY0115]
  2. Science and Technology Planning Project of Sichuan Province [2019YJ0345]
  3. innovation and Entrepreneurship Project of China West Normal University [cxcy2020188]
  4. Application Technology Research and Development Special Project of Nanchong, China [18YFZJ0035]

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The effects of hydrothermal temperature on the photocatalytic degradation performance of bismuth oxide formate were investigated, with the BiO-160 showing the highest degradation rate. The photocatalytic mechanisms revealed that center dot OH plays a major role in the degradation of tetracycline by bismuth oxide.
The effects of hydrothermal temperature on the photocatalytic degradation performance of bismuth oxide formate were investigated using Bi(NO3)(3)center dot 5H(2)O and N, N-dimethylformamide prepared by a simple hydrothermal process. Its structure and properties were analyzed by field emission scanning electron microscope, Fourier transform infrared spectroscopy, x-ray powder diffraction, and ultraviolet and visible absorption spectra. The photocatalytic degradation performance was evaluated in tetracycline solutions. Temperature has a great influence on the morphology of BiOCOOH, and reduces the width of the energy gap. The photocatalytic degradation rate of BiOCOOH prepared at 160 degrees C (BiO-160) with regard to tetracycline was 3.2 times that at 140 degrees C. Within 70 min, BiO-160 can almost completely degrade 10 mg/L of tetracycline in aqueous solution. Photocatalytic mechanisms showed that center dot OH plays a major role, while center dot O-2(-) plays a secondary role in the photocatalytic degradation of tetracycline by BiO-160.

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