4.7 Article

On the role of traps in the microstructural control of environmental hydrogen embrittlement of a 7xxx series aluminum alloy

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 855, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.157300

Keywords

Hydrogen trapping; Hydrogen embrittlement; Aluminum alloys; Dislocations; Intergranular fracture; Transgranular fracture

Funding

  1. JSPS, Japan KAKENHI [JP17H03406]
  2. Light Metal Educational Foundation, Inc.

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The study found that by controlling the distribution of soluble second phase particles, the hydrogen embrittlement resistance of the alloy can be improved, but an excessive increase in second phase particles can make the alloy more sensitive to hydrogen embrittlement.
The nature of hydrogen traps and hydrogen embrittlement (HE) behavior of a 7xxx series aluminum alloy with different microstructural characteristics were investigated. Hydrogen trapped by Al lattice, dislocations, soluble second phase particles, and vacancies. Hydrogen-induced intergranular fracture occurred in the specimen with high hydrogen trapping at dislocations, due to a large amount of weakly bounded hydrogen to dislocations. HE resistance was firstly obtained by controlling distribution of soluble second phase particles, resulting in a lower hydrogen content resides at dislocations. However, an excessive increase in second phase particles led to HE sensitivity of the alloy due to hydrogen-induced decohesion at the particles. (C) 2020 Elsevier B.V. All rights reserved.

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