4.6 Article

Plasmon and Plexciton Driven Interfacial Catalytic Reactions

Journal

CHEMICAL RECORD
Volume 21, Issue 4, Pages 797-819

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.202000171

Keywords

Plasmon-exciton coupling interaction; plexciton; Surface-enhanced Raman scattering spectroscopy; Surface catalytic reactions; Electrooptical Synergy

Funding

  1. National Natural Science Foundation of China [91436102, 11374353, 51971029]
  2. fundamental Research Funds for the Central Universities in China
  3. NSFC-BRICS STI Framework Program [51861145309]

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This paper focuses on the summary of catalytic reactions driven by surface plasmons and plexciton, demonstrating the promotion effect of coupling interaction in oxidation and reduction reactions. The coupling effect of plasmons and excitons successfully improves the efficiency of catalytic reactions. It also presents the research progress in electrooptical synergic plasmon-exciton co-driven surface catalytic reactions.
In this review, we focus on the summary of catalytic reaction driven by surface plasmons and plexciton, where the plexciton is the interaction between plasmon and exciton. We first review the reduction and oxidation reactions driven by plasmons, and analyze the role of plasmons in the two reactions. We then summarize the recent research on the surface catalytic reactions driven by plasmon-exciton coupling and discuss the promotion effect of coupling interaction in oxidation reaction and reduction reaction. The coupling effect of plasmons and excitons can successfully improve the efficiency of catalytic reactions. Finally, this paper demonstrates the research progress in the electrooptical synergic plasmon-exciton co-driven surface catalytic reactions.

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