Journal
CATALYSIS LETTERS
Volume 151, Issue 10, Pages 3004-3010Publisher
SPRINGER
DOI: 10.1007/s10562-021-03547-2
Keywords
Pd/c; Tetrahydroxydiboron; H-2 evolution; Tandem reaction; Kinetic isotope effect
Categories
Funding
- National Natural Science Foundation of China [21805166]
- 111 Project [D20015]
- Engineering Research Center of Eco-environment in Three Gorges Reservoir Region, Ministry of Education, China Three Gorges University [KF2019-05]
- outstanding young and middle-aged science and technology innovation teams, Ministry of Education, Hubei province, China [T2020004]
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The production of hydrogen from non-fossil sources is a key research challenge. Recent studies have shown that aqueous solutions of tetrahydroxydiboron can serve as a hydrogen source, with commercial and inexpensive Pd/C as an efficient and recyclable catalyst for hydrogen evolution.
The production of H-2 from non-fossil sources is a key research challenge to contributing solving the forthcoming energy problem. Aqueous solutions of tetrahydroxydiboron have very recently appeared as a H-2 source, from which both hydrogen atoms are provided by water, in the presence of highly sophisticated nanocatalysts. Herein, commercial and cheap Pd/C is shown to be an efficient and recyclable catalyst for H-2 evolution upon tetrahydroxydiboron hydrolysis. Graphic
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