Iron‐Catalyzed Tertiary Alkylation of Terminal Alkynes with 1,3‐Diesters via a Functionalized Alkyl Radical

Copper(II)-Mediated Ring Opening/Alkynylation of Tertiary Cyclopropanols by Using Nonmodified Terminal Alkynes

(2020) Bu-Qing Cheng et al.   ORGANIC LETTERS

Divergent C–H Oxidative Radical Functionalization of Olefins to Install Tertiary Alkyl Motifs Enabled by Copper Catalysis

(2019) Ming-Qing Tian et al.   ORGANIC LETTERS

Free Radical Addition of Nitrile, Ketone, and Ester to Alkyne and the Selectivity Discussion

(2019) Yingxia Xiao et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Selective Functionalization of C(sp3 )−H Bonds in Natural Products

(2018) Rashad R. Karimov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multi-Metal-Catalyzed Oxidative Radical Alkynylation with Terminal Alkynes: A New Strategy for C(sp3)–C(sp) Bond Formation

(2018) Shan Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Copper-Catalyzed Oxidative Coupling of α-Alkylated Styrenes with Tertiary Alkyl Radicals

(2018) Cong Wang et al.   ORGANIC LETTERS

Enantioselective Decarboxylative α-Alkynylation of β-Ketocarbonyls via a Catalytic α-Imino Radical Intermediate

(2017) Dehong Wang et al.   ORGANIC LETTERS

Copper-Catalyzed Functionalized Tertiary-Alkylative Sonogashira Type Couplings via Copper Acetylide at Room Temperature

(2017) Yu Yamane et al.   ACS Catalysis

Tandem Reactions Enable Trans- and Cis-Hydro-Tertiary-Alkylations Catalyzed by a Copper Salt

(2017) Kimiaki Nakamura et al.   ACS Catalysis

1,1-Disubstituted olefin synthesis via Ni-catalyzed Markovnikov hydroalkylation of alkynes with alkyl halides

(2016) Xiao-Yu Lu et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Free Coupling of Alkynes with α-Bromo Carbonyl Compounds: An Efficient Approach towards β,γ-Alkynoates and Allenoates

(2016) Wenbo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cu-Catalyzed Alkynylation of Unactivated C(sp3)–X Bonds with Terminal Alkynes through Directing Strategy

(2016) Fei-Xian Luo et al.   ORGANIC LETTERS

Metal-Free Markovnikov-Type Alkyne Hydration under Mild Conditions

(2016) Wenbo Liu et al.   ORGANIC LETTERS

Nickel-Catalyzed Oxidative Coupling of Unactivated C(sp3)–H Bonds in Aliphatic Amides with Terminal Alkynes

(2016) Fei-Xian Luo et al.   ORGANOMETALLICS

Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes

(2016) Shan Tang et al.   Nature Communications

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

(2015) Chao Liu et al.   CHEMICAL REVIEWS

Rhenium-Catalyzed anti-Markovnikov Addition Reaction of Methanetricarboxylates to Unactivated Terminal Acetylenes

(2015) Shunsuke Hori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Hydroalkylation of Terminal Alkynes

(2015) Mycah R. Uehling et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Z-Selective Olefin Synthesis via Iron-Catalyzed Reductive Coupling of Alkyl Halides with Terminal Arylalkynes

(2015) Chi Wai Cheung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iodine-Catalyzed Radical Oxidative Annulation for the Construction of Dihydrofurans and Indolizines

(2015) Shan Tang et al.   ORGANIC LETTERS

Empowering a transition-metal-free coupling between alkyne and alkyl iodide with light in water

(2015) Wenbo Liu et al.   Nature Communications

Nickel-Catalyzed Direct Alkylation of Terminal Alkynes at Room Temperature: A Hemilabile Pincer Ligand Enhances Catalytic Activity

(2015) Pablo M. Pérez García et al.   ACS Catalysis

Recent Advances of Transition-Metal Catalyzed Radical Oxidative Cross-Couplings

(2014) Chao Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Mechanistic Study of Silver-Mediated Furan Formation by Oxidative Coupling

(2014) János Daru et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient asymmetric synthesis of spiro-2(3H)-furanones via phase-transfer-catalyzed alkynylation

(2014) Xiangfei Wu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Mild and Phosphine-Free Iron-Catalyzed Cross-Coupling of Nonactivated Secondary Alkyl Halides with Alkynyl Grignard Reagents

(2014) Chi Wai Cheung et al.   ORGANIC LETTERS

Formal fluorine atom transfer radical addition: silver-catalyzed carbofluorination of unactivated alkenes with ketones in aqueous solution

(2014) Lin Zhu et al.   Organic Chemistry Frontiers

Nickel-Catalyzed Sonogashira Reactions of Non-activated Secondary Alkyl Bromides and Iodides

(2013) Jun Yi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-catalyzed oxidative coupling/cyclization of acrylamides with 1,3-dicarbonyl compounds

(2013) Hua Wang et al.   CHEMICAL COMMUNICATIONS

Palladium(0)-Catalyzed Alkynylation of C(sp3)–H Bonds

(2013) Jian He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems

(2012) Uta Wille   CHEMICAL REVIEWS

Electrophilic alkynylation: the dark side of acetylene chemistry

(2012) Jonathan P. Brand et al.   CHEMICAL SOCIETY REVIEWS

Zinc(II)-Catalyzed Redox Cross-Dehydrogenative Coupling of Propargylic Amines and Terminal Alkynes for Synthesis of N-Tethered 1,6-Enynes

(2012) Tsuyuka Sugiishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Oxidative C–H/C–H Functionalization: A Strategy To Construct Polysubstituted Furans

(2012) Chuan He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereoselective C(sp3)C(sp) Cross-Coupling Reactions between 1,3- and 1,4-Substituted Cyclohexylzinc Reagents and Bromoalkynes through Remote Stereocontrol

(2011) Tobias Thaler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Coupling of Nonactivated Alkyl Halides with Alkynyl Grignard Reagents: A Nickel Pincer Complex as the Catalyst

(2011) Oleg Vechorkin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning Chemoselectivity in Iron-Catalyzed Sonogashira-Type Reactions Using a Bisphosphine Ligand with Peripheral Steric Bulk: Selective Alkynylation of Nonactivated Alkyl Halides

(2011) Takuji Hatakeyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Direct Ethynylation of C(sp3)–H Bonds in Aliphatic Carboxylic Acid Derivatives

(2011) Yusuke Ano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Oxidative C−N Bond Formation for the Synthesis of Carbazoles: Comparison of Reactivity between the Copper-Catalyzed and Metal-Free Conditions

(2011) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-mediated cross dehydrogenative coupling (CDC) of terminal alkynes with benzylic ethers and alkanes

(2011) Shi-Kai Xiang et al.   Science China-Chemistry

Copper-Catalyzed Cross-Coupling of Alkyl and Aryl Grignard Reagents with Alkynyl Halides

(2010) Gérard Cahiez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Aerobic Oxidative Cross-Coupling Reactions of Terminal Alkynes with Alkylzinc Reagents

(2010) Mao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Secondary Alkyl Halides in Transition-Metal-Catalyzed Cross-Coupling Reactions

(2009) Alena Rudolph et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic compounds as synthons for 1,3-dicarbonyl derivatives

(2009) Gerhard Hilt et al.   CHEMICAL SOCIETY REVIEWS

Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides

(2009) Oleg Vechorkin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective C−H Bond Activation: Ligand and Solvent Free Iron-Catalyzed Oxidative C−C Cross-Coupling of Tertiary Amines with Terminal Alkynes. Reaction Scope and Mechanism

(2009) Chandra M. Rao Volla et al.   ORGANIC LETTERS

Copper/Diethyl Azodicarboxylate Mediated Regioselective Alkynylation of Unactivated Aliphatic Tertiary Methylamine with Terminal Alkyne

(2009) Xiaoliang Xu et al.   ORGANIC LETTERS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Efficient Oxidative Alkyne Homocoupling Catalyzed by a Monomeric Dicopper-Substituted Silicotungstate

(2008) Keigo Kamata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 2(3H)-Furanones via Electrophilic Cyclization

(2008) Ziwei W. Just et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Coupling of Tertiary Aliphatic Amines with Terminal Alkynes to Propargylamines via C−H Activation

(2008) Mingyu Niu et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Regioselective Dehydrohalogenation of Alkyl Halides with Dimethylphenylsilylmethylmagnesium Chloride

(2008) Tsuneyuki Kobayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY