4.6 Article

High performance porous MnO@C composite anode materials for lithium-ion batteries

Journal

ELECTROCHIMICA ACTA
Volume 188, Issue -, Pages 793-800

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.12.047

Keywords

MnO@C composite; Porous structure; Precipitation; Glucose; Lithium-ion batteries

Funding

  1. National Natural Science Foundation of China [21401017, 51125009]
  2. Fundamental Research Funds for the Central Universities [DUT13LK17]
  3. Scientific Research Fund of Liaoning Provincial Education Department [L2013030]
  4. Open Project of State Key Laboratory of Rare Earth Resources Utilization [RERU2013013]
  5. Hundred Talents Program of Chinese Academy of Sciences

Ask authors/readers for more resources

MnC2O4 precursor was prepared by a precipitation method, and then porous MnO@C composites were obtained by mixing MnC2O4 precursor with different amounts of glucose and sintering at different temperatures. The influences of carbon content and crystallinity on the electrochemical performance of MnO@C were investigated. Galvanostatic charge-discharge test results showed that the MnO@C sample 1.2,700 has the largest specific capacity among all samples, which can reach high specific discharge capacity of 1691 mAhg(-1) at the current density of 100 mAg(-1) after 200 cycles. Even at the high current density of 1600 mA g(-1), a remarkable discharge capacity of 630 mAhg(-1) can still be delivered, demonstrating a good rate capability. The excellent electrochemical performance can be ascribed to porous structure, good crystallinity and proper amount of carbon coating. This facile method can be applied to the large-scale synthesis of high performance transition metal oxide@carbon composite electrode materials. (C) 2015 Elsevier Ltd. All rights reserved.

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