4.7 Article

Magnetoactive elastomer based on superparamagnetic nanoparticles with Curie point close to room temperature

Journal

MATERIALS & DESIGN
Volume 197, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2020.109281

Keywords

Magnetoactive elastomer; Superparamagnetic nanoparticles; Magneto-rheological effect; Magnetoelastic properties; Magnetization

Funding

  1. Thousand Talents Program for Foreign Experts program of China [WQ20162200339]
  2. NAS of Ukraine

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The research demonstrated that the magnetoelastic properties of magnetoactive elastomers (MAE) have critical features near room temperature, allowing for self-regulating magnetoelastic properties.
A magnetoactive elastomer (MAE) consisting of single-domain La0.6Ag0.2Mn1.2O3 nanoparticles with a Curie temperature close to room temperature (T-C = 308 K) in a silicone matrix has been prepared and comprehensively studied. It has been found that MAE particles are magnetized superparamagnetically with a low coercivity below 10 Oe at room temperature and above. The influence of magnetic anisotropy on the appearance of torque is justified. A coupling between magnetization and magnetoelasticity has also been established. The mechanisms of the appearance of magnetoelasticity, including the effect of MAE rearrangement and MAE compression by magnetized particles, have been revealed. It has been found that the magnetoelastic properties of MAE have critical features near T-C. The magnetoelastic properties of MAE disappear at T > T-C and are restored at T < T-C. This makes it possible to use MAE at room temperature as a smart material for devices with self-regulating magnetoelastic properties. (c) 2020 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

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