Journal
DYES AND PIGMENTS
Volume 125, Issue -, Pages 100-105Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2015.10.014
Keywords
Benzothiadiazole; Third-order nonlinear absorption; Third-order nonlinear refraction; Donor-acceptor molecules; Carbazole; N,N-dimethylaniline
Funding
- National Natural Science Foundation of China [21290190, 21322301, 20803029, 51072064]
- NSFC-DFG joint fund [TRR 61]
- National Basic Research 973 Program of China [2011CB935800, 2012CB932900]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09020302]
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Three pi-conjugated donor-acceptor molecules containing either N,N-dimethylaniline or carbazole as the electron donor and 2,1,3-benzothiadiazole as the electron acceptor were synthesized through either Suzuki or Sonogashira cross-coupling reactions. Their X-ray crystal structural, optical, electrochemical properties were investigated. These compounds showed blue-shifted emission in the solid state compared with those in organic solvents. HOMO-LUMO gaps of these compounds estimated from cyclic voltammetry experiments correlated well with those obtained from theoretical calculation results. The nonlinear optical properties of the three D-A molecules were studied using the top-hat Z-scan technique with 21 ps laser pulses at 532 nm. The compound with N,N-dimethylaniline as the donor featuring a more planar configuration makes pi-electrons more delocalized, which exhibited large third-order nonlinear absorption and refraction effect. (C) 2015 Elsevier Ltd. All rights reserved.
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