Journal
ORGANIC LETTERS
Volume 22, Issue 24, Pages 9556-9561Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c03611
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Funding
- University of Tehran
- Kharazmi University
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We describe the development of a new method for construction of highly substituted indole scaffolds through the strategic utilizing of the metathesis of Ar-X sigma-bonds based on the dynamic nature of palladium-based oxidative addition/reductive elimination. A suitable and simple catalytic system has provided an appropriate platform for a productive ligand exchange and consecutive carbopalladation/C-H activation/amination of phosphine ligands with alkynes and aromatic/aliphatic amines for construction of structurally diverse indoles.
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