4.4 Article

Perspectives on additives for polymers. 1. Aspects of stabilization

Journal

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY
Volume 27, Issue 1, Pages 5-27

Publisher

WILEY
DOI: 10.1002/vnl.21807

Keywords

additives; antagonism; antioxidants; degradation; degradation; melt flow index; metal deactivators; oxidation; phosphites; polyethylene; polymers; stabilization; synergism; thermal oxidation; yellowness index

Ask authors/readers for more resources

The field of additives in polymers has rapidly expanded with the discovery and developments over time. Additives like antioxidants, light stabilizers, processing aids, and flame retardants serve specific functions and interact with polymers to affect end use performance.
Since the earliest discovery and subsequent developments in the world of polymers associated problems and increasing applications have resulted in the rapidly expanding field of additives. In this context, the term additive is very generalized in that it encompasses many facets associated with ever growing needs. Of the most important are antioxidants (primary and secondary), light stabilizers, processing aids, metal deactivators, flame retardants, biocides, nucleating agents, antistatic compounds, fillers, dyes, pigments (nano, micro, and macro) to name but only a few each serving a particular function and not necessarily all at the same time in the one package. This article presents a general perspective on the type, mode of action, properties, uses, and problems (and circumvention) based on some of the more important key additives. The properties and behavior of many additives in this regard relates very much to the initial incorporation and formulation and in turn is often a major controlling factor in end use performance from a physical, esthetic, structural, mechanical, and chemical point of view. Indeed, with many polymers like PVC, for example, one enters a highly complex world of interactions which can in many cases destroy or even enhance the activity of functional processing additives. Some of these will be highlighted and hopefully the aim being here to enthuse the polymer and additive manufacturers and technologists in the processing laboratories to become more aware of potential issues and problems.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Applied

Perspectives on additives for polymers. Part 2. Aspects of photostabilization and role of fillers and pigments

Norman S. Allen, Michele Edge

Summary: This article discusses the importance of antioxidants, light stabilizers, processing aids, and fillers/pigments in polymer systems and their interactions. It emphasizes the synergism and antagonism in performances and color problems, with a special focus on PVC. The use of filled polymers leads to complex additive interactions, resulting in extreme outcomes.

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY (2021)

Article Chemistry, Applied

High-temperature stabilization of polypropylene using hindered phenol-thioester stabilizer combinations, Part 1: Optimization and efficacy via nondust blends

Norman S. Allen, Andrew P. Jones, Christopher M. Liauw, Michele Edge, Klaus Keck-Antoine, Joeng-Ho Yeo

Summary: The study found that a 20:80 phenol:thioester ratio provided the best long-term thermal stability (LTTS), with the reverse effect seen for processing stabilization (80:20), highlighting the antioxidant nature of the two stabilizers. Preblending the stabilizers to form a no-dust blend improved LTTS, indicating better additive dispersion and removal of volatile impurities. In high-temperature applications like under the bonnet of automobiles, minimizing stabilizer losses and maximizing synergy are important considerations for the long-term stabilization of polypropylene.

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY (2021)

Article Chemistry, Applied

High-temperature stabilization of polypropylene using hindered phenol-thioester stabilizer combinations, Part 2: Optimization and efficacy via encapsulation with silicate fillers

Norman S. Allen, Andrew P. Jones, Christopher M. Liauw, Michele Edge, Klaus Keck-Antoine, Joeng-Ho Yeo

Summary: The study found that a 20:80 phenol:thioester ratio provided the best long-term thermal stability for polypropylene, and further investigated the incorporation of high surface area inorganic substrates to limit stabilizer mobility and enhance stability. The results showed potential improvements in long-term stabilization of polypropylene and highlighted the importance of minimizing stabilizer losses and maximizing synergy in high-temperature applications.

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY (2021)

Article Chemistry, Applied

Research perspectives and further studies on catalyst effects on the stability of different polyethylenes during multiple extrusion: Inter-relationship of oxidation chemistry and antioxidant activity

Norman S. Allen, Christopher M. Liauw, Michele Edge, Eric Hoang, Eusebio Fontan

Summary: This study examined the degradation and stabilization of a variety of polyethylenes during multiple extrusions, revealing crosslinking reactions in HDPE and LLDPE initiated at unsaturated groups. Stabilizer packages effectively inhibited carbonyl growth, but did not prevent MFI changes due to crosslinking reactions, except for one LLDPE variant.

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY (2022)

Article Chemistry, Applied

A perspective on alloy effects between polymer additives in the development of nondust blends: A DSC and spectroscopic evaluation

Norman S. Allen, Michele Edge, Sajid Hussain

Summary: The study evaluated the optimal synergistic melt blending of 18 antioxidants and light stabilizers using differential scanning calorimetry (DSC) analysis. Only three systems showed true eutectic mixtures, but effective lower temperature melt blends were still possible up to 230 degrees C. The presence of strong eutectic behavior was often associated with specific interactions between additives, affecting the overall efficacy of the melt blends.

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY (2022)

Article Chemistry, Applied

Optimization of the ultraviolet-visible absorption properties of nano-particle TiO2: Influence of milling, surface area and surfactants on particle-size distribution, and stability of isocyanate/acrylic paints

Norman S. Allen, Michele Edge, Claire Hill, Julie Maltby Kerrod

Summary: The UV-Vis absorption properties of a range of nano-particle titanium dioxides can be optimized through different calcination and wet milling methodologies, with TiO2 particles with a crystallite size of 25 nm demonstrating the best properties. UV/visible absorption spectroscopy is sensitive to particle size and is a useful tool for assessing nano-TiO2 dispersions.

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY (2022)

Article Chemistry, Organic

Novel [60]fullerene polymers: Part 1: Synthesis and polymerisation processes through acrylation of N-methyl-o-hydroxy-2-phenyl fulleropyrrolidines and their monomers

Sajid Hussain, Norman S. Allen

Summary: This study describes the synthesis of functionalized C60 and novel fullerene polymers using pyrrolidine substitution. The addition of azomethine ylide was found to be a versatile method for the derivatization of [60]fullerene. Low molecular weight hydroxy fulleropyrrolidines were prepared through the cycloaddition of azomethine ylide to [60]fullerene using N-methyl glycine and benzaldehyde derivatives. The resulting fulleropyrrolidine monomer could be polymerized using benzoyl peroxide as an initiator.

TETRAHEDRON (2022)

Article Chemistry, Organic

Novel [60]fullerene polymers: Part 2: Synthesis and polymerisation processes through acrylation of N-(4-hydroxyphenyl)-o-hydroxy-2-phenyl fulleropyrrolidine derivatives and their monomers

Sajid Hussain, Norman S. Allen

Summary: This paper describes the synthesis of crosslinked and branched chain C60 polymers to increase the amount of C60 content and molecular weight in the polymer. The method involved the preparation of fulleropyrrolidines through a [3+2] cycloaddition reaction and the synthesis of various types of fullerene polymers using fulleropyrrolidine acrylic monomers. The study found that the cycloaddition process was a powerful tool for fullerene functionalization, resulting in stable cycloadducts. The addition of azomethine ylide provided a versatile method for the derivatization of [60] fullerene.

TETRAHEDRON (2022)

Article Chemistry, Applied

Effect of type of polymerization catalyst system on the degradation and stabilization of polyethylenes in the melt state-Part 4: Comparative antioxidant effectiveness on organoleptic extractables

Norman S. Allen, Karmele del Teso Sanchez, Michele Edge, Christopher M. Liauw, Sajid Hussain, Keith Hall

Summary: Different polymerization catalyst systems have a significant impact on the production of extractable thermo-oxidative degradation products during melt processing cycles. These products include volatile organoleptic components such as hydrocarbons, alcohols, aldehydes, ketones, and carboxylic acids. The identification of these components is important for quality modification and determining toxicity and leachability with food products.

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY (2023)

No Data Available