Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 49, Pages 20680-20690Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c09056
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Funding
- MURI program of the Office of Naval Research [N00014-18-1-2624]
- Department of Energy, Laboratory Directed Research and Development program at SLAC National Accelerator Laboratory [DE-AC02-76SF00515]
- German National Academy of Sciences Leopoldina through the Leopoldina Fellowship Program [LPDS 2018-09]
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Azobenzene is one of the most ubiquitous photoswitches in photochemistry and a prototypical model for photoisomerizing systems. Despite this, its wavelength-dependent photochemistry has puzzled researchers for decades. Upon excitation to the higher energy pi pi* excited state instead of the dipole-forbidden n pi* state, the quantum yield of isomerization from trans- to cis-azobenzene is halved. The difficulties associated with unambiguously resolving this effect both experimentally and theoretically have contributed to lasting controversies regarding the photochemistry of azobenzene. Here, we systematically characterize the dynamic photoreaction pathways of azobenzene by performing first-principles simulations of the nonadiabatic dynamics following excitation to both the pi pi* and the n pi* states. We demonstrate that ground-state recovery is mediated by two distinct S-1 decay pathways: a reactive twisting pathway and an unreactive planar pathway. Increased preference for the unreactive pathway upon pi pi* excitation largely accounts for the wavelength-dependent behavior observed in azobenzene.
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