Journal
JOURNAL OF POWER SOURCES
Volume 478, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2020.229047
Keywords
Lithium ion battery; Gel polymer electrolyte; Nitrile co-solvents; Cell safety; High temperature
Funding
- Mitsui Chemicals [3550076500]
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Gel polymer electrolytes (GPEs) based on poly (vinylidene difluoride-co-hexafluoropropylene) (PVdF-HFP) containing propylene carbonate (PC), isobutyronitrile (IBN) and trimethyl acetonitrile (TMAN) solvent blend electrolytes were developed to enhance high temperature electrochemical performance and to improve safety of LiNi3/5Mn1/5Co1/5O2 (NMC622)parallel to graphite lithium ion battery (LIB) cells. These liquid electrolytes (LE) consist of lithium bis(trifluoro-methane)sulfonimide (LiTFSI) as conducting lithium salt and PC/nitrile (1:1, v/v) solvent blends. Ethylene sulfite (ES) and vinylene carbonate (VC) were used as solid electrolyte interphase (SEI) forming additives and contributing to an excellent cycling stability of electrolytes comprising nitrile solvents in NMC622 parallel to graphite cells. Electrochemical impedance spectroscopy (EIS), pulsed field gradient nuclear magnetic resonance spectroscopy (PFG NMR) and relative permittivity determination reveal remarkable ion conducting properties of IBN and TMAN solvents. Since their electrolytes are incompatible with lithium metal electrodes, their electrochemical stability window (ESW) was determined using lithiated lithium titanate (Li7Ti5O12) (LTO) as counter and reference electrodes and the obtained values were confirmed by quantum mechanical compu-tation. Differential scanning calorimetry (DSC) and accelerating rate calorimetry (ARC) confirmed significantly improved safety of IBN and TMAN containing electrolytes. Therefore, PVdF-HFP-based GPEs containing PC/nitrile solvent blends are a promising alternative to SOTA electrolyte for battery cycling at elevated temperature (60 degrees C) in NMC622 parallel to graphite cells.
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