4.7 Article

A generic process modelling - LCA approach for UF membrane fabrication: Application to cellulose acetate membranes

Journal

JOURNAL OF MEMBRANE SCIENCE
Volume 618, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.memsci.2020.118594

Keywords

Process modelling; LCA; Membrane preparation; Ultrafiltration; Ecodesign

Funding

  1. Universite Federale de Toulouse (PRES)
  2. Region Occitanie/Pyrenees-Mediterranee, France

Ask authors/readers for more resources

The research aims to provide a decision-making tool for greener membrane fabrication through the application of generic process modelling-LCA approach. The parameterized model allows for material and energy flow analysis under different operating conditions. The study also identifies major contributions to environmental impacts and suggests improvement strategies for environmental mitigation.
The purpose of the research is to elaborate and implement a decision-making tool for greener membrane fabrication. The scientific novelty put forth in this study is the generic process modelling - LCA approach applied to the field. The resulting parameterized model allows to obtain material and energy flows as a function of operating conditions for ultrafiltration hollow fibers prepared by non-solvent induced phase separation. Its modular configuration allows for flexibility and adaptation to various membrane materials and industrial practices. Contributions of inputs on environmental impacts can be assessed, as well as the influence of operating conditions. Results for cellulose acetate membranes show major contributions of NMP (i.e. solvent) and glycerol (i.e. pre-conditioning liquid). Improvement strategies for environmental mitigation include acting on glycerolrelated operating conditions and are to be considered within the geographic context of membrane fabrication; further technical and economic feasibility studies would embed these strategies in a full eco-design approach. Such a methodology and results should be taken into account for the elaboration of green membranes whatever the application and coupled with the impact of membrane use and end-of-life.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Chemical

Catalytic membrane reactor for Suzuki-Miyaura C-C cross-coupling: Explanation for its high efficiency via modeling

Yingying Gu, Patrice Bacchin, Jean-Francois Lahitte, Jean-Christophe Remigy, Isabelle Favier, Montserrat Gomez, Douglas L. Gin, Richard D. Noble

AICHE JOURNAL (2017)

Article Engineering, Chemical

UV-cured polysulfone-based membranes: Effect of co-solvent addition and evaporation process on membrane morphology and SRNF performance

Veysi Altun, Jean-Christophe Remigy, Ivo F. J. Vankelecom

JOURNAL OF MEMBRANE SCIENCE (2017)

Article Engineering, Chemical

CO2 capture by aqueous ammonia with hollow fiber membrane contactors: Gas phase reactions and performance stability

Kevin Villeneuve, Denis Roizard, Jean-Christophe Remigy, Marcello Iacono, Sabine Rode

SEPARATION AND PURIFICATION TECHNOLOGY (2018)

Article Cell & Tissue Engineering

Tunable Microstructured Membranes in Organs-on-Chips to Monitor Transendothelial Hydraulic Resistance

Pritam Das, Andries D. van der Meer, Aisen Vivas, Yusuf B. Arik, Jean-Christophe Remigy, Jean-Francois Lahitte, Rob Gh Lammertink, Patrice Bacchin

TISSUE ENGINEERING PART A (2019)

Article Biophysics

Double porous poly (ε-caprolactone)/chitosan membrane scaffolds as niches for human mesenchymal stem cells

Pritam Das, Simona Salerno, Jean-Christophe Remigy, Jean-Francois Lahitte, Patrice Bacchin, Loredana De Bartolo

COLLOIDS AND SURFACES B-BIOINTERFACES (2019)

Article Materials Science, Biomaterials

Development of double porous poly (ε - caprolactone)/chitosan polymer as tissue engineering scaffold

Pritam Das, Jean-Christophe Remigy, Jean-Francois Lahitte, Andries D. van der Meer, Barbara Garmy-Susini, Clemence Coetsier, Sandrine Desclaux, Patrice Bacchin

MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS (2020)

Article Chemistry, Applied

Remarkable catalytic activity of polymeric membranes containing gel-trapped palladium nanoparticles for hydrogenation reactions

Melissa Lopez-Viveros, Isabelle Favier, Montserrat Gomez, Jean-Francois Lahitte, Jean-Christophe Remigy

Summary: Polymeric flat-sheet membranes and hollow fibers were prepared via UV photo-initiated polymerization of acrylic acid to efficiently immobilize palladium nanoparticles. The flat sheet membranes were more active than hollow fibers in hydrogenation reactions under mild conditions, achieving high conversions in short reaction times.

CATALYSIS TODAY (2021)

Article Engineering, Chemical

Critical backwash flux for high backwash efficiency: Case of ultrafiltration of bentonite suspensions

Thomas Vroman, Francois Beaume, Valentine Armanges, Emilie Gout, Jean-Christophe Remigy

Summary: Optimizing backwash conditions can reduce energy and water consumption. Critical backwash flux and inter cake-membrane pressure are key factors in efficient fouling removal, independent of membrane properties.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Environmental

Process-based LCA of ultrafiltration for drinking water production

Flavie Prezelus, Ligia Tiruta-Barna, Jean-Christophe Remigy, Christelle Guigui

Summary: In this study, a tool combining membrane filtration process modeling and life cycle analysis was developed to assess environmental impacts and applied in drinking water production. It was found that adjusting filtration cycle and flux can mitigate environmental impacts.

WATER RESEARCH (2021)

Article Green & Sustainable Science & Technology

Does substituting reprotoxic solvents during ultrafiltration membrane fabrication really mitigate environmental impacts? Focus on drinking water production

Flavie Prezelus, Jean-Christophe Remigy, Christelle Guigui, Ligia Tiruta-Barna

Summary: This research aims to fill knowledge gaps on the relevance of solvent substitution from a life cycle perspective and propose relevant operating conditions for process optimization and eco-design. Solvent substitution has little influence on environmental impacts, with environmental hotspots found in the operating stage.

JOURNAL OF CLEANER PRODUCTION (2022)

Article Multidisciplinary Sciences

Modeling equations and dataset of model parameters for ultrafiltration membrane fabrication

Flavie Prezelus, Ligia Tiruta-Barna, Christelle Guigui, Jean-Christophe Remigy

DATA IN BRIEF (2020)

Article Chemistry, Multidisciplinary

A metrics-based approach to preparing sustainable membranes: application to ultrafiltration

Flavie Prezelus, Dihia Chabni, Ligia Barna, Christelle Guigui, Jean-Christophe Remigy

GREEN CHEMISTRY (2019)

Proceedings Paper Green & Sustainable Science & Technology

Membrane Reactor Based on Hybrid Nanomaterials for Process Intensification of Catalytic Hydrogenation Reaction: an Example of Reduction of the Environmental Footprint of Chemical Synthesis from a Batch to a Continuous Flow Chemistry Process

Yingying Gu, Jean-Christophe Remigy, Isabelle Favier, Montserrat Gomez, Richard D. Noble, Jean-Franois Lahitte

INTERNATIONAL CONFERENCE ON NANOTECHNOLOGY BASED INNOVATIVE APPLICATIONS FOR THE ENVIRONMENT (2016)

Proceedings Paper Materials Science, Multidisciplinary

Hybrid catalytic membranes: tunable and versatile materials for fine chemistry applications

Yingying Gu, Clelia Emin, Jean-Christophe Remigy, Isabelle Favier, Montserrat Gomez, Richard D. Noble, Douglas L. Gin, Jorge Macanas, Berta Domenech, Jean-Francois Lahitte

MATERIALS TODAY-PROCEEDINGS (2016)

Article Engineering, Chemical

r-HGO/MXene composite membrane with enhanced permeability and rejection performance for water treatment

Jiawei Hou, Shixuan Guo, Nigel Graham, Wenzheng Yu, Kening Sun, Ting Liu

Summary: A novel 2D composite membrane based on r-HGO and MXene materials was developed, demonstrating exceptional performance for water treatment in terms of permeability, pollutant rejection, and physical stability. The optimization of preparation conditions and material proportions can result in high water flux and efficient removal of pollutants.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Designing a multifunctional TFC membrane with improved permeability and anti-biofouling performance using zwitterionic, quaternary ammonium, and fluorinated materials

Rui Gao, Caihong Liu, Andreia F. Faria, Qiang He, Chun Yang, Jun Ma

Summary: A novel copolymer architecture has been developed to address biofouling concerns in thin-film composite (TFC) membranes by integrating anti-fouling, bactericidal, and fouling-release functions. The multifunctional membrane demonstrates promising anti-adhesive properties, self-cleaning ability, and high flux recovery rate.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Defect-free asymmetric Matrimid® gas separation membranes using dihydrolevoglucosenone (Cyrene™) as a greener polar aprotic solvent than traditional solvents

Alexander T. Bridge, Noah P. Wamble, Matthew S. Santoso, Joan F. Brennecke, Benny D. Freeman

Summary: This study demonstrates the reproducible preparation of high-flux defect-free asymmetric gas separation membranes using Cyrene(TM) as a majority dope formulation component. By adjusting the volume ratios of Cyrene(TM) and THF, as well as the concentrations of Matrimid(R) and the dry step time, optimal membrane performance is achieved.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Nanofiber composite ultrafiltration membrane functionalized with cross-linked β-cyclodextrin for steroid hormone micropollutant removal

Alessandra Imbrogno, Han Ya Lin, Babak Minofar, Andrea Iris Schaefer

Summary: In this study, a composite nanofiber membrane containing cross-linked beta-cyclodextrin-epichlorohydrin was prepared and evaluated for the removal of steroid hormones. The results showed that the membrane had high adsorption capacity and the ability to form a specific inclusion complex interaction with the hormones, indicating its potential application in hormone removal.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Modeling the flux of volatile fatty acid in a membrane distillation with the effect of pH

Bora Shin, Jaewon Shin, Yanuar Chandra Wirasembada, Ki Young Park, Jinwoo Cho

Summary: This study develops a mathematical model to estimate the initial flux of volatile fatty acids in the direct contact membrane distillation process. It identifies the parameters affecting the flux and their relationship with pH.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Plasma-engineered GQD-inorganic membranes with tunable interactions for ultrahigh-efficiency molecular separations

Yi-Jui Yeh, Jr Rong Liou, Wei Lin, Kuo-Lun Tung, Wei-Hung Chiang

Summary: This study demonstrates an effective plasma engineering method to create nitrogen-doped graphene quantum dot (NGQD)-inorganic nanocomposites for tunable molecular separation. The composite materials show high separation efficiency and controllable nanopore structures, making them potentially valuable for various applications.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Water vapor sorption and transport in carbon molecular sieve membranes

Horacio Lopez-Marques, Kristofer L. Gleason, Manuel Aguilar-Vega, Rita Sulub-Sulub, J. Ehren Eichler, Hyeonji Oh, C. Buddie Mullins, Benny D. Freeman, Manish Kumar

Summary: In this study, water transport properties in Carbon Molecular Sieve (CMS) membranes were investigated. It was found that membranes synthesized at different pyrolysis temperatures exhibited varying water permeabilities. Compared to other polymeric materials, CMS membranes showed high water permeability, indicating potential for dehydration applications.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Vinyl-addition polynorbornenes with glycerol and diethylene glycol moieties: Synthesis and structure-property study

Dmitry A. Alentiev, Roman Yu. Nikiforov, Marina A. Rudakova, Danil P. Zarezin, Maxim A. Topchiy, Andrey F. Asachenko, Nikolay A. Belov, Maxim Bermeshev

Summary: A series of new norbornene-type monomers containing linear and branched substituents were synthesized, and robust thin membranes were prepared by vinyl-addition polymerization. Gas separation performance for the synthesized polymers was evaluated, and the structure of substituent side chains was found to significantly affect gas permeability and CO2 facilitated transport.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Hydrogel electrolyte membrane with regulated pore effect to stabilize zinc anode in aqueous zinc-ion batteries

Lei Yan, Qi Zhang, Ze Zhang, Gui-Jie Li, Yi Jin, Xin-Lin Zhang, Yan-Yun Sun

Summary: In this study, a continuous, stable and fast ion transport channel was established through in-situ guided cross-linking of zinc alginate hydrogels on a porous membrane, overcoming the negative pore effect and effectively inhibiting the dendrite growth of zinc anodes and interfacial side reactions.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Fabrication of an ultra-thin and ordered SPEEK proton exchange membrane by a Langmuir-Blodgett self-assembly process

Yuqing Zhang, Ailing Zhang, Huiyang He, Yuting Fan, Yongjiang Li, Song Wang, Sanxi Li

Summary: The Langmuir-Blodgett self-assembly process is used to create an ordered SPEEK membrane, which enhances the proton conductivity by three times compared to conventional solution casting method.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Estimating Gas Sorption In Polymeric Membranes From The Molecular Structure: A Machine Learning Based Group Contribution Method For The Non-Equilibrium Lattice Fluid Model (ML-GC-NELF)

Hasan Ismaeel, David Gibson, Eleonora Ricci, Maria Grazia De Angelis

Summary: In this study, a machine learning-based group contribution method (ML-GC) was developed to predict pure polymer parameters and successfully applied to predict gas solubility and gas solubility isotherms in glassy polymeric membranes. The model showed satisfactory performance on a small dataset, but has the potential to provide more accurate predictions for a wider range of polymers as more data becomes available.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Angular vibrations for fouling control during ultrafiltration of microalgae in a spiral wound module

Yi Ji, Yu Sun, Huilin Li, Qiang Fu, Yan Zhang

Summary: Previous studies have shown that vibration- or rotation-based techniques can effectively mitigate fouling during membrane filtration. However, it is difficult to incorporate these techniques with spiral wound modules (SWMs) widely used in water and wastewater treatment. This study developed a prototype membrane system to accommodate angular vibrations with a modified SWM, and experimental results showed that applying angular vibrations can effectively control algal fouling in an SWM with lower energy consumption compared to traditional methods.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Polyphenol-coated hollow fiber system for energy-efficient dehumidification in air-conditioning

Lakshmeesha Upadhayaya, Abaynesh Yihdego Gebreyohannes, Muhammad Wakil Shahzad, Usman T. Syed, Sandra L. Aristizabal, Radoslaw Gorecki, Suzana P. Nunes

Summary: Increasing temperatures worldwide pose a significant health risk, exacerbated by high humidity. Conventional air conditioners contribute heavily to carbon dioxide emissions, with dehumidification being a major factor. Membrane-based dehumidification system offers energy efficiency and non-toxic water vapor removal. This study demonstrates a membrane dehumidification system with polymeric hollow fibers coated with a green polyphenol coating, showing remarkable water vapor transport rate and selectivity. Long-term testing reveals minimal decline in vapor transport and a 4-5 times higher coefficient of performance (COP) compared to conventional dehumidifiers, making it a highly competitive, energy-saving device with reduced emissions and a smaller footprint.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

A facile method to fabricate anti-fouling nanofiltration membrane with aminated lignin

Zhengzhong Zhou, Xue Zhu, Yi Yuan, Shaoqiang Wang, Xiaoshan Meng, Taoli Huhe, Qian Wang

Summary: In this study, lignin, a biomass material, was chemically modified and utilized in the interfacial polymerization process to improve the performance of nanofiltration membranes. The modified membranes showed enhanced hydrophilicity and anti-fouling properties, and the optimization of membrane pore size increased permeability. The study also demonstrated the potential application of the membranes in biogas slurry valorization.

JOURNAL OF MEMBRANE SCIENCE (2024)